公开(公告)号：US5516493A

公开(公告)日：1996-05-14

申请号：US964082

申请日：1992-10-20

Applicant: Maxwell G. Bell ,  Stephen J. Smith ,  David T. Pratt ,  Matthew P. Sharpe ,  Dale C. Cable

Inventor： Maxwell G. Bell ,  Stephen J. Smith ,  David T. Pratt ,  Matthew P. Sharpe ,  Dale C. Cable

IPC: C01B13/11 ,  C02F1/78

CPC classification number: C01B13/11 ,  C01B2201/14 ,  C01B2201/22 ,  C01B2201/34 ,  C01B2201/64 ,  C01B2201/66 ,  C02F1/78 ,  Y10S422/907

Abstract: The present invention relates to a tubular ozone generator which uses a novel electrode structure wherein a wound electrode has a solid insulator between the turns of the windings.

Abstract translation: PCT No.PCT / AU92 / 00061 Sec。 371日期：1993年1月29日 102（e）日期1993年1月29日PCT提交1992年2月21日PCT公布。 WO92 / 14677 PCT出版物 本发明涉及一种管状臭氧发生器，其使用新颖的电极结构，其中绕组电极在绕组匝之间具有固体绝缘体。

公开(公告)号：US5316639A

公开(公告)日：1994-05-31

申请号：US989480

申请日：1992-12-07

Applicant: Sachiko Okazaki ,  Masuhiro Kogoma ,  Masahiro Hirakawa

Inventor： Sachiko Okazaki ,  Masuhiro Kogoma ,  Masahiro Hirakawa

IPC: C01B13/11 ,  C23C16/34 ,  C23C16/40 ,  C23C14/00

CPC classification number: C01B13/11 ,  C23C16/345 ,  C23C16/402 ,  C01B2201/12 ,  C01B2201/14 ,  C01B2201/34

Abstract: This invention concerns a SiO.sub.2, SiN.sub.x protection film formed by a CVD or PVD gas phase glowing method capable of preventing melting of the matrix ingredients at the surface of a dielectric material in electric discharge of an ozone generator and it relates to a dielectric material used for an ozone generator capable of overcoming the problems for the abrasion of electrode and dielectric material or melting of ions or molecules of during electric discharge, as well as a method of forming a protection film therefor based on the finding that an SiO.sub.2 film or SiN.sub.x film can be formed easily on a surface of a predetermined electric material or, further, on a surface of electrode by processing a specific reaction gas, for example, comprising a crude gas such as SiH.sub.4, SiCl.sub.4, N.sub.2, NH.sub.3 or TEOS or further incorporated with an inert gas or like by means of an atmospheric CVD process such as CVD or heat CVD and, in particular, on the finding that the protection film can be disposed directly to the surface of the dielectric material and the electrode in an ozone generator after the completion of assembling.

Abstract translation: 本发明涉及通过CVD或PVD气相发光法形成的SiO 2，SiN x保护膜，其能够防止在臭氧发生器的放电中电介质材料的表面处的基体成分熔化，并且涉及用于 能够克服电极和介电材料的磨损或放电期间的离子或分子熔化的问题的臭氧发生器，以及形成保护膜的方法基于SiO 2膜或SiN x膜可以 可以容易地形成在预定电材料的表面上，或者通过加工特定的反应气体，例如包含诸如SiH 4，SiCl 4，N 2，NH 3或TEOS的粗气体，或进一步与 惰性气体或类似物，通过诸如CVD或热CVD的大气CVD工艺，并且特别地，基于保护膜可以直接设置在sur 在组装完成后的臭氧发生器中的电介质材料和电极的表面。

公开(公告)号：US5254317A

公开(公告)日：1993-10-19

申请号：US669939

申请日：1991-03-15

Applicant: Melchior Fischer ,  Paul Kostinger

Inventor： Melchior Fischer ,  Paul Kostinger

IPC: C01B13/11 ,  B01J19/12

CPC classification number: C01B13/11 ,  C01B2201/14 ,  C01B2201/32 ,  C01B2201/34

Abstract: In an ozone generator, spring elements (5) of metal pointing transversely to the longitudinal direction of the tube are provided for spacing the dielectric (3) from the metallic outer electrode (1). These spring elements are either bonded directly to the dielectric (3) and are stuck onto a tape-shaped carrier which is attached to the dielectric (3) and at their free ends rest against the inside wall of the outer electrode (1). In this manner, the discharge gap is only minimally constricted and the assembly of the inner tubes (2a, 2b) is simplified.

Abstract translation: 在臭氧发生器中，提供横向于管的纵向方向的金属弹簧元件（5），用于将电介质（3）与金属外电极（1）间隔开。 这些弹簧元件或者直接结合到电介质（3）上，并且被粘贴到附着到电介质（3）上并且其自由端靠在外电极（1）的内壁上的带状载体上。 以这种方式，放电间隙仅被最小限度地缩小并且内管（2a，2b）的组装被简化。

公开(公告)号：US5147614A

公开(公告)日：1992-09-15

申请号：US515440

申请日：1990-04-27

Applicant: Richard H. Conrad

Inventor： Richard H. Conrad

IPC: C01B13/11

CPC classification number: C01B13/11 ,  C01B2201/14 ,  C01B2201/34 ,  C01B2201/74

Abstract: A self-contained and self-supporting cell for generating ozone by corona discharge which consists basically of two open-ended straight tubes. An inner metal tube serves as a first electrode and is cooled by a fluid flowing through its core. An outer glass or ceramic tube concentrically surrounds and is shorter than the inner tube, carries a second electrode on its outer surface, and is cooled by a flow of fluid across its outer surface. The inner metal tube serves as a supporting column on which all other components are mounted and aligned. It carries a collar near each of its ends, and across each collar are clamped outer end-pieces carrying coolant seals and fittings, the inner side of the clamp assembly comprising flat aligning plates. Short cylinders of non-conductive inert material, bearing seals on each face and dry gas inlet/ozone outlet ports, fit concentrically around the inner tube and are clamped between the surfaces of clamping-plates. The ends of the dielectric tube fit inside sealing rings in the inner faces of the short cylinders. The invention also includes an extension coupling which allows the mounting of two or more dielectric tubes in series on a single metal tube.

Abstract translation: 用于通过电晕放电产生臭氧的独立和自支撑电池，其基本上由两个开放式直管组成。 内金属管用作第一电极，并且被流过其芯的流体冷却。 外部玻璃或陶瓷管同心地围绕并短于内管，在其外表面上承载第二电极，并且通过其流体流过其外表面而被冷却。 内金属管用作支撑柱，其上安装和对准所有其它部件。 它在其每个端部附近带有一个轴环，并且穿过每个轴环夹紧着承载冷却剂密封件和配件的外部端部件，夹具组件的内侧包括平的对准板。 不导电惰性材料的短圆柱体，每个表面上的轴承密封件和干燥气体入口/臭氧出口端口均匀地配合在内管周围并夹紧在夹紧板的表面之间。 电介质管的端部装配在短气缸内表面的密封环内。 本发明还包括延伸耦合，其允许将两个或更多个电介质管串联安装在单个金属管上。

公开(公告)号：US4963331A

公开(公告)日：1990-10-16

申请号：US485175

申请日：1990-02-26

Applicant: Kenneth W. Mouw

Inventor： Kenneth W. Mouw

IPC: C01B13/11

CPC classification number: C01B13/11 ,  C01B2201/14 ,  C01B2201/22 ,  C01B2201/24 ,  C01B2201/32

Abstract: A sealed glass tube having an electrical conductor therein arranged when combined with a high voltage and an encircling perforated metal member on the tube to produce ozone. The tube has an electrically conducting cap fitted on and integrally secured to one end thereof, and an externally threaded adapter is mounted on the cap for quick attachment to and detachment from an ozone generator manifold. The conductor has a projecting end secured to an outer end wall of the cap, and such wall in turn has a lug attached thereto providing quick attachment to a source of high voltage.

Abstract translation: 一个密封的玻璃管，其内部布置有电导体，与管上的高电压和环绕穿孔的金属构件组合以产生臭氧。 该管具有安装在其一端并一体地固定到其一端的导电帽，并且外螺纹适配器安装在帽上，用于快速附接到臭氧发生器歧管和从臭氧发生器歧管脱离。 导体具有固定到盖的外端壁的突出端，并且这样的壁依次具有连接到其上的凸耳，从而提供与高电压源的快速连接。

公开(公告)号：US4461744A

公开(公告)日：1984-07-24

申请号：US331751

申请日：1981-12-17

Applicant: Peter Erni ,  Ulrich Kogelschatz ,  Sigfrid Strassler ,  Hans-Jurg Wiesmann

Inventor： Peter Erni ,  Ulrich Kogelschatz ,  Sigfrid Strassler ,  Hans-Jurg Wiesmann

IPC: C01B13/11 ,  B01J19/12

CPC classification number: C01B13/115 ,  C01B13/11 ,  C01B2201/14 ,  C01B2201/22

Abstract: An ozone-generating element is disclosed which has a tube ozonizer (1), consisting essentially of an outer metal tube (3) forming one electrode, and of a glass tube (4) which is located coaxially therein and is spaced from it and the inner surface of which is provided with an electrically conductive layer (5) serving as the other electrode. Ozone is formed by pulse discharges with a passive, plate-like spark gap (12) with a defined response voltage serving as a switching element. The tube ozonizer (1) is fed by a low-frequency current source (7) via a high-voltage transformer (9), to the secondary winding (10) of which a storage capacitor (11) is connected. A series of embodiments is proposed, and in these part or all the constructional elements of the critical pulse circuit form a constructional unit with, or integrated into, the tube ozonizer (1). In this way, it is possible to produce pulse circuits of extremely low inductance which lead to up to a doubling of the total efficiency of ozone generation. By means of the highest integration stage which is considered especially advantageous, it becomes possible to convert conventional ozone generators fed with alternating current to pulse operation, without having to carry out expensive conversion and adaptation work, especially in terms of circuitry.

Abstract translation: 公开了一种臭氧发生元件，其具有管臭氧发生器（1），其基本上由形成一个电极的外部金属管（3）和与其同轴并且与其间隔开的玻璃管（4）和 其内表面设置有用作另一电极的导电层（5）。 臭氧由具有限定的响应电压作为开关元件的无源板状火花隙（12）的脉冲放电形成。 管式臭氧发生器（1）通过高压变压器（9）由低频电流源（7）馈送到连接有存储电容器（11）的次级绕组（10）。 提出了一系列实施例，并且在关键脉冲电路的这些部分或全部结构元件形成与管臭氧发生器（1）一体的结构单元。 以这种方式，可以产生极低电感的脉冲电路，导致臭氧产生的总效率增加一倍。 通过被认为是特别有利的最高积分级，可以将传统的用交流电馈送的臭氧发生器转换为脉冲操作，而不必执行昂贵的转换和适配工作，特别是在电路方面。

公开(公告)号：US4159971A

公开(公告)日：1979-07-03

申请号：US764219

申请日：1977-01-31

Applicant: Arthur Gneupel

Inventor： Arthur Gneupel

IPC: C01B13/11 ,  H01T23/00

CPC classification number: C01B13/11 ,  H01T23/00 ,  C01B2201/14 ,  C01B2201/22 ,  C01B2201/24 ,  C01B2201/32 ,  C01B2201/34

Abstract: A substantially tubular-shaped ozone generator embodying an inner electrode, a coaxial outer electrode surrounding the inner electrode and a tube member formed of dielectric material arranged between the inner electrode and the outer electrode. Within the tube member formed of dielectric material there is arranged a substantially cylindrical core provided at its outer surface with one or a number of substantially helically-shaped grooves extending in the axial direction of the core and forming a throughpass channel for the medium to be ozonized and the ozone which is generated.

Abstract translation: 一个体积为管状的臭氧发生器，其包括内部电极，围绕内部电极的同轴外部电极和由内部电极和外部电极之间布置的电介质材料形成的管件。 在由电介质材料形成的管构件中，布置有基本上圆柱形的芯，其在其外表面处设置有沿芯的轴向方向延伸的一个或多个基本上为螺旋状的凹槽，并形成用于介质被臭化的通道 和产生的臭氧。

公开(公告)号：US3865733A

公开(公告)日：1975-02-11

申请号：US43772974

申请日：1974-01-30

Applicant: TAYLOR LELAND THOMAS

Inventor： TAYLOR LELAND THOMAS

IPC: C01B13/11 ,  C01B13/12

CPC classification number: C01B13/11 ,  C01B2201/14 ,  C01B2201/22

Abstract: Apparatus for the production of ozone is disclosed. The apparatus comprises two or more electrically conductive wires each encased in an insulating material being brought into contact with each other. The principal advantage of the apparatus of the present invention is its durability.

Abstract translation: 公开了用于生产臭氧的设备。 该装置包括两个或多个导电线，每个导电线都被封装在彼此接触的绝缘材料中。 本发明的装置的主要优点是其耐久性。

公开(公告)号：US3833492A

公开(公告)日：1974-09-03

申请号：US34373173

申请日：1973-03-22

Applicant: POLLUTION CONTROL IND INC

Inventor： BOLLYKY L

IPC: C01B13/11 ,  C01B13/10 ,  C01B13/12

CPC classification number: C01B13/11 ,  C01B2201/14 ,  C01B2201/32 ,  C01B2201/62 ,  C01B2201/74 ,  C01B2201/76

Abstract: An ozone generator module of the electric discharge field type is provided having at least one cell comprising an assembly of three concentric tubular members, the inner and outer tubular members being electrodes separated by a tubular dielectric member spaced from one of the electrodes a distance sufficient to define a high density electric discharge zone between them, the cell or cells being disposed within a liquid container. Surprisingly good results are obtained by employing a combination of three method steps; - limiting variation in the cross sectional dimension of the field to within a very small range of tolerance; controlling the temperature of the electrodes; and limiting the density of the field by regulating the voltage across the field and the frequency employed.

Abstract translation: 提供了一种放电场型的臭氧发生器模块，其具有至少一个电池，该电池包括三个同心管状部件的组件，内部和外部管状部件是由与电极之一间隔开的管状介电部件隔开的电极， 在它们之间限定高密度放电区，细胞或细胞设置在液体容器内。 通过采用三个方法步骤的组合获得令人惊奇的良好结果; - 将场的横截面尺寸的变化限制在非常小的公差范围内; 控制电极的温度; 并通过调节场上的电压和使用的频率来限制场的密度。

公开(公告)号：US3551321A

公开(公告)日：1970-12-29

申请号：US3551321D

申请日：1968-05-22

Applicant: EAUX ET DE L OZONE CIE DES

Inventor： GUILLERD JEAN ,  TRAVERS FERNAND

IPC: C01B13/11 ,  C01B13/12

CPC classification number: C01B13/11 ,  C01B2201/14 ,  C01B2201/76