公开(公告)号：US06555053B1

公开(公告)日：2003-04-29

申请号：US09460867

申请日：1999-12-14

申请人： Kohei Aoyagi

发明人： Kohei Aoyagi

IPC分类号： A61L200

CPC分类号： A61L2/24 ,  A61L2/20 ,  A61L2/26 ,  A61L9/015 ,  A61L9/02 ,  A61L9/03 ,  C01B11/022 ,  F24F2003/1667 ,  Y10S204/903 ,  Y10S204/904

摘要： According to the present invention, provided are a method whereby a sterilization/deodorization gas is supplied by irradiating a stabilized chlorine dioxide gel or liquid with ultraviolet radiation, and a sterilization/deodorization gas supply apparatus which comprises: a chemical container used to hold a chemical gel or liquid which is used for sterilization and deodorization, and as an insecticide or an insectifuge; an ultraviolet radiation unit for projecting ultraviolet radiation onto the chemical and for generating a dispersed gas; and a gas discharge unit for extracting from the chemical container gas elements that are to be dispersed by the ultraviolet radiation unit. With this arrangement, a chlorine dioxide gas that can effectively perform sterilization and deodorization can be easily and safely stored, handled and supplemented by employing the chemical reactive propagative effects of ultraviolet radiation.

摘要翻译： 根据本发明，提供一种通过用紫外线照射稳定的二氧化氯凝胶或液体来提供灭菌/除臭气体的方法，以及灭菌/除臭气体供给装置，其包括：用于容纳化学物质的化学容器 用于灭菌和除臭的凝胶或液体，以及作为杀虫剂或杀虫剂; 用于将紫外线辐射投射到化学品上并用于产生分散气体的紫外线辐射单元; 以及气体排出单元，用于从化学容器中提取要由紫外线辐射单元分散的气体元素。 通过这种布置，可以通过使用紫外线辐射的化学反应性传播效应，可以容易且安全地存储，处理和补充能够有效地进行灭菌和除臭的二氧化氯气体。

公开(公告)号：US4623437A

公开(公告)日：1986-11-18

申请号：US398338

申请日：1982-07-15

申请人： Mario Visca ,  Carlo Scotti

发明人： Mario Visca ,  Carlo Scotti

IPC分类号： C07C9/04 ,  B01J19/12 ,  B01J21/06 ,  B01J23/20 ,  B01J23/26 ,  B01J23/34 ,  B01J23/40 ,  B01J23/46 ,  B01J27/04 ,  B01J27/057 ,  B01J27/14 ,  C01B3/04 ,  C01B3/22 ,  C07B61/00 ,  C07C1/00 ,  C07C1/207 ,  C07C27/00 ,  C07C29/15 ,  C07C29/158 ,  C07C31/04 ,  C07C67/00 ,  B01J27/02 ,  B01J27/188

CPC分类号： B01J21/063 ,  B01J23/20 ,  B01J23/46 ,  B01J27/04 ,  C01B3/042 ,  Y02E60/364 ,  Y10S204/903

摘要： New catalysts for photo-assisted (i.e. promoted by light) oxidation-reduction (redox) reactions are disclosed. These catalysts consist of colloidal particles of a semiconductor, containing on their surface a reduction catalyst and an oxidation catalyst. In a first class of catalysts, the semiconductor has a difference of energy between valence band and conduction band such as to allow the hole-electron separation by absorption of visible light. This semiconductor is selected, in the case of the photo-decomposition of water, from the group consisting of TiO.sub.2 doped with Mn, Cr, or Cr and Nb; CdS doped with In or Ga; SrTiO.sub.3 doped with Cr or Mn; gallium phosphide; and cadmium sulphoselenide. In the case of the other photo-decomposition reactions, the semiconductor is selected from the group consisting of the above-mentioned compounds and CdS.In a second class of catalysts, the semiconductor has a difference of energy between valence band and conduction band such as not to permit the hole-electron separation by absorption of visible light. This semiconductor is selected, in the case of the photo-decomposition of water, from the group consisting of SrTiO.sub.3 and Nb.sub.2 O.sub.5. In the case of the other photo-decompositon reactions, the semiconductor is selected from the group consisting of the above-mentioned compounds and TiO.sub.2 doped with Nb.

摘要翻译： 公开了用于光辅助（即通过光促进）氧化还原（氧化还原）反应的新催化剂。 这些催化剂由半导体的胶体颗粒组成，在其表面上含有还原催化剂和氧化催化剂。 在第一类催化剂中，半导体具有价带和导带之间的能量差，例如通过吸收可见光而允许空穴 - 电子分离。 在由Mn，Cr或Cr和Nb掺杂的TiO 2组成的组中，在水分解光的情况下选择该半导体; 掺杂In或Ga的CdS; 掺杂Cr或Mn的SrTiO3; 磷化镓; 和硫镉硒。 在其他光分解反应的情况下，半导体选自上述化合物和CdS。 在第二类催化剂中，半导体具有价带和导带之间的能量差，例如不允许通过吸收可见光而进行空穴 - 电子分离。 在水分解的情况下，由SrTiO 3和Nb 2 O 5组成的组中选择该半导体。 在其它光分解反应的情况下，半导体选自上述化合物和掺杂有Nb的TiO 2。

公开(公告)号：US4602988A

公开(公告)日：1986-07-29

申请号：US743546

申请日：1985-06-11

申请人： John H. Kolts

发明人： John H. Kolts

IPC分类号： B01J19/12 ,  C01B3/04

CPC分类号： B01J19/127 ,  C01B3/04 ,  Y02E60/364 ,  Y02P20/134 ,  Y10S204/903

摘要： H.sub.2 is produced from H.sub.2 S dissolved in an alkaline aqueous medium by irradiating the alkaline aqueous solution of H.sub.2 S using light in the visible range in the presence of a catalytic amount of a compound chosen from the group of ZnO, ZnO-RuO.sub.2, ZnS, ZnSe and CuGaS.sub.2.

摘要翻译： 通过在催化量的选自ZnO，ZnO-RuO 2，ZnS，ZnSe的化合物的存在下，在可见光范围内照射硫酸的碱性水溶液，在溶解于碱性水性介质中的H 2 S中生成H 2， CuGaS2。

公开(公告)号：US3853729A

公开(公告)日：1974-12-10

申请号：US38233473

申请日：1973-07-25

申请人： AQUITAINE PETROLE

发明人： LUCAS G

IPC分类号： B01J19/12 ,  B01J1/10 ,  B01J1/14

CPC分类号： B01J19/123 ,  Y10S204/903

摘要： A process for photo-oximating cycloalkanes by means of a gaseous nitrosating agent, in which the agent is fed into a radiation zone, without any cycloalkane present, the activated radicals are transferred immediately to an adjoining reaction zone containing the cycloalkane, and the oxime is produced in this reaction zone and drawn off. The radiation zone is separated from reaction zone by a perforated or gas-permeable partition, such as an electroformed grid made from a corrosion-resistant metal or alloy. Pressure is maintained in the radiation zone by means of a gas vehicle carrying the gaseous nitrosating agent, ensuring immediate transfer of the activated radicals and preventing any of the liquid phase in the radiation zone from leaking in.

摘要翻译： 通过气态亚硝化剂使环烷烃光肟化的方法，其中将试剂送入辐射区，而不存在任何环烷烃，活化的基团立即转移到含有环烷烃的相邻反应区，肟为 在该反应区产生并抽出。

公开(公告)号：US3717561A

公开(公告)日：1973-02-20

申请号：US3717561D

申请日：1971-03-15

申请人： TEXACO INC

发明人： HOLST E ,  RIGDON O ,  EDWARDS R

IPC分类号： B01J19/12 ,  B01J1/10

CPC分类号： B01J19/122 ,  Y10S204/903

摘要： A process for producing normal paraffin oximes and, in particular, normal paraffin oximes having from 10 to 13 carbon atoms wherein a C10 to C13 normal paraffin is photochemically reacted with a gaseous nitrosating agent where the photolytic reaction is conducted under the influence of a sodium arc lamp producing light in the wavelength of about 380 millimicrons to about 760 millimicrons and preferably where the principal emission spectra is from about 550 to 650 millimicrons.

摘要翻译： 一种生产正链烷烃肟的方法，特别是具有10至13个碳原子的正链烷烃肟，其中C10至C13正链烷烃与气态亚硝化剂进行光化学反应，其中光解反应在钠弧 产生波长为约380毫微子至约760毫微子的光，优选主要发射光谱为约550至650毫微子。

公开(公告)号：US3658671A

公开(公告)日：1972-04-25

申请号：US3658671D

申请日：1969-09-18

申请人： LION FAT OIL CO LTD

发明人： NAGAYAMA MASUZO ,  KAWANA TERUNOSUKE

IPC分类号： B01J19/12 ,  C07C303/14 ,  B01J1/10

CPC分类号： C07C303/14 ,  B01J19/123 ,  Y10S204/903 ,  C07C309/04

摘要： A method of sulfoxidation of paraffin which comprises the steps of imparting actinic ray energy, to paraffin which contains not more than 5 weight percent of the reaction product of sulfoxidation and/or oxygen, and which contains sulfur dioxide gas dissolved therein, and subsequently blowing oxygen and sulfur dioxide gas into the thus processed paraffin.

摘要翻译： 一种对石蜡进行磺氧化的方法，包括以下步骤：将含有不超过5重量％的亚砜化和/或氧的反应产物，并含有二氧化硫气体溶解在其中的石蜡，然后吹入氧气，给予光化射线能量 和二氧化硫气体进入如此处理的石蜡。

公开(公告)号：US3635807A

公开(公告)日：1972-01-18

申请号：US3635807D

申请日：1969-01-13

申请人： MOBIL OIL CORP

发明人： GUARINO JOHN P ,  WILLIAMS ROBERT H

IPC分类号： A61L9/12 ,  B01J1/10 ,  C07C81/06

CPC分类号： C07C249/06 ,  A61L9/12 ,  Y10S204/903 ,  Y10S204/911 ,  Y10S204/912 ,  C07C251/44

摘要： Cycloaliphatic ketoximes are produced in good yields by means of a photochemical reaction between a cycloaliphatic compound and an alkyl nitrite in the presence of an alkyl alcohol and ammonia.

摘要翻译： 在烷基醇和氨存在下，通过脂环族化合物和亚硝酸烷基酯之间的光化学反应，以良好的产率制备环脂族酮肟。

公开(公告)号：US3616359A

公开(公告)日：1971-10-26

申请号：US3616359D

申请日：1968-08-20

申请人： THIOKOL CHEMICAL CORP

发明人： PAUSTIAN JOHN E ,  BURWASSER HERMAN

IPC分类号： B01J1/10

CPC分类号： C07C201/00 ,  Y10S204/903

摘要： A process has been provided for preparing perhalo nitroso alkanes from a halocarbon compound of the formula RCX2H wherein X is fluorine, chlorine, or bromine and R is a halogen or a perhalo radical and wherein the halogens substituents are fluorine, chlorine, or bromine. The process is carried out by reacting the halocarbon with nitrosyl chloride in a vapor phase at a pressure of one atmosphere or less and at a temperature from 160* C. and lower while irradiating the reaction mixture with radiant energy at the characteristic wavelength displayed by nitrosyl chloride.

公开(公告)号：US3418228A

公开(公告)日：1968-12-24

申请号：US52357566

申请日：1966-01-28

申请人： DU PONT

发明人： LEE BARTLETT PHILIP

CPC分类号： C07C255/45 ,  Y10S204/903 ,  Y10S204/905 ,  Y10S204/907 ,  Y10S204/909

公开(公告)号：US3392095A

公开(公告)日：1968-07-09

申请号：US49906765

申请日：1965-10-20

申请人： GULF RASEARCH & DEV COMPANY

发明人： DIMOND HAROLD L ,  PASCARELLA VINCENT J ,  WHITAKER ARTHUR C

IPC分类号： C07B45/02 ,  C07C303/16

CPC分类号： C07C303/16 ,  C07B45/02 ,  Y10S204/903 ,  Y10S204/914