Abstract:
A method for producing acrylic fiber includes preparing a spinning solution including an acrylic copolymer, dimethyl sulfoxide, water, and a polyphosphate; and subjecting the spinning solution to wet spinning, wherein the acrylic copolymer includes acrylonitrile in an amount of 20 to 85 mass %, vinyl chloride in an amount of 14.5 to 79.5 mass %, and a sulfonic acid group-containing monomer in an amount of 0.5 to 10 mass % with respect to a total mass of the acrylic copolymer.
Abstract:
An arc resistant acrylic fiber includes an acrylic polymer. The arc resistant acrylic fiber also includes an infrared absorber in an amount of 1 wt % to 30 wt % with respect to a total weight of the acrylic polymer.
Abstract:
Provided is a flame-retardant fabric comprising (A) from 16 to 45 parts by weight of a halogen-containing fiber containing from 11 to 67% by weight of a halogen chemically bound to a polymer and from 4 to 30% by weight of an Sb compound not chemically bound to a polymer, (B) from 10 to 36 parts by weight of a polyvinyl alcohol fiber, and (C) from 60 to 40 parts by weight of a polyester fiber, which are compounded to total 100 parts by weight. The flame-retardant fabric of the present invention has an excellent heat resistance, an excellent processability and a high flame retardance. This fabric can improve the feeling after high-temperature processing such as transfer printing and further widen the range of application of a polyester fiber product.
Abstract:
A doll having hair comprising synthetic fiber consisting essentially of an acrylonitrile polymer comprising 30 to 80% by weight of an acrylonitrile and 70 to 20% by weight of at least one of a vinyl chloride and a vinylidene chloride. The fiber hair of the invention have the excellent flame resistance, the natural touch, the natural and quiet luster, the excellent curl retention and the excellent bulkiness.
Abstract:
The present invention relates to acrylic fibers each having a Y-type cross section which consist of an acrylic polymer constituted of at least 50% by weight of acrylonitrile, characterized in that the Y-type cross section is constructed substantially of three rectangles and when the thickness values of the middle part, innermost part, and outermost part of each component rectangle are represented by d.sub.0, d.sub.1, and d.sub.2, respectively, the ratios of d.sub.1 /d.sub.0 and d.sub.2 /d.sub.0 are each in the range of 0.95 to 1.05, and a process for producing the same comprising discharging an organic solvent solution which contains an acrylic polymer constituted of at least 50% by weight of acrylonitrile, dissolved at a concentration of 22 to 30% by weight, and has a viscosity of 200 to 500 poises, through spinneret holes each having a Y-type cross section constructed substantially of three rectangles, into a coagulating liuqid composed of an organic solvent and water at a spinning draft of 1.1 to 1.8, and subjecting the thus spun filaments to washing and stretching. The acrylic fibers of the present invention have excellent bulkiness and softness to the touch.
Abstract:
A process for preparing fibers from acrylonitrile polymer via melt spinning is disclosed wherein a slurry of polymer, water and surfactant are evaporated to form a single phase homogeneous melt of less than about 25 weight percent water and in the range from about 12 to 20 percent.
Abstract:
Textile fibers having reduced inflammability and high luster, constituted copolymers of acrylonitrile, vinylidene chloride and a significantly homopolymerizable sulphonic comonomer are described. Significantly homopolymerizable comonomers are defined as monomers which homopolymerize with a conversion above 30.degree.-40.degree. under standard conditions set forth in the specification. A preferred class of such comonomers are the derivatives of acrylamidoalkanesulphonic acids, e.g. 2-acrylamido-2-methylpropane-sodium sulphonate. The fibers are spun from spinning dopes containing said copolymers in solution in organic solvent miscible with water and less than 4% of water. Said spinning dopes can be obtained by preparing a binary copolymer of acrylonitrile and the sulphonic monomer, in solution in the solvent, mixing the solution with a solution of acrylonitrile and vinylidene monomers in the same solvent, and subjecting the mixture to copolymerization. The copolymers finally obtained contain 50-85% of acrylonitrile, 13.5-46.5% of vinylidene chloride, and 1.5-3.5% of the sulphonic comonomer, the percentages being by weight.
Abstract:
The invention relates to modacryl filaments and fibers made from copolymers insoluble in acetone of acrylonitrile and from 20 to 45 weight % of vinylidene chloride, containing from 0 to 1.5 weight % of unsaturated organic sulfonic acids or the salts thereof, and from 0 to 10 weight % of further copolymerizable compounds, which copolymers have a K value according to Fikentscher of more than about 95 and a process for the manufacture thereof. These modacryl filaments and fibers are especially distinguished by their permanent brilliance and permanent transparence; these properties are maintained even on contact with water having a temperature above 80.degree. C.
Abstract:
A thermoplastic modacrylic resin suitable for producing modacrylic fiber excellent in strength and/or melt spinning stability is provided. The thermoplastic modacrylic resin includes a copolymer. The copolymer includes a polymer (A) that includes a modacrylic resin containing constituent unit 1 derived from acrylonitrile (a1) and constituent unit 2 derived from an ethylenically unsaturated monomer (a2) other than the acrylonitrile (a1), and a polymer (B) that contains constituent unit 3 derived from acrylonitrile (b1). The polymer (B) has first and second terminals and is bound to the polymer (A) at the second terminal. The polymer (B) has 30 mol % or more to less than 70 mol % of all constituent unit 3 in a terminal region that contains the first terminal and contains one-half of all constituent units in the polymer (B). The constituent unit 3 content is 3 to 50 mol % relative to all constituent units in the polymer (B).
Abstract:
A task is to provide a cloth which is advantageous in that the cloth has extremely excellent flame retardancy, and further has excellent washing shrinkage resistance and excellent hand as well as excellent antistatic properties, preferably in that the whole of the cloth can be uniformly dyed, and a fiber product, and the task is achieved by obtaining a cloth using a spun yarn which comprises a meta-type wholly aromatic polyamide fiber, a modacrylic fiber, and a conductive fiber.