Method for producing oxymethylene copolymer

    公开(公告)号:US10954332B2

    公开(公告)日:2021-03-23

    申请号:US16764479

    申请日:2019-07-16

    IPC分类号: C08G2/10

    摘要: A method for producing an oxymethylene copolymer which gives molded articles that are inhibited from emitting formaldehyde and can be reduced in yellowness is provided. In producing an oxymethylene copolymer, an effective polymerization initiator amount is regulated to a value within a given range, the amount being calculated from the amount of perchloric acid or a derivative thereof contained in the polymerization initiator and the amount of triethanolamine contained in all the monomers comprising trioxane and comonomers, which are starting materials for the copolymer.

    Initiator
    48.
    发明授权
    Initiator 有权
    发起人

    公开(公告)号:US09163120B2

    公开(公告)日:2015-10-20

    申请号:US14246536

    申请日:2014-04-07

    申请人: Ticona GmbH

    CPC分类号: C08G75/24 C08G2/06 C08G2/10

    摘要: An initiator for cationic polymerization comprises a salt of a protic acid as well as a protic add. The molar ratio of protic acid to salt is in the range from 1:0.01 to 1:2000. The initiator is used for example for cationic homo- or copolymerization of trioxane, and permits stable and flexible operation of the polymerization.

    摘要翻译: 用于阳离子聚合的引发剂包括质子酸的盐以及质子添加剂。 质子酸与盐的摩尔比在1:0.01至1:2000的范围内。 引发剂用于例如三恶烷的阳离子均聚或共聚,并且允许聚合的稳定和灵活的操作。

    Process for producing polyacetal copolymer
    50.
    发明授权
    Process for producing polyacetal copolymer 失效
    生产聚缩醛共聚物的方法

    公开(公告)号:US5886139A

    公开(公告)日:1999-03-23

    申请号:US835932

    申请日:1997-04-11

    CPC分类号: C08G2/24 C08G2/06

    摘要: To economically produce a polyacetal copolymer excellent in properties including thermal stability by copolymerizing trioxane as the main monomer through simple steps, a polyacetal copolymer is produced by copolymerizing trioxane as the main monomer using a nonvolatile protonic acid catalyst as a polymerization catalyst until the conversion reaches at least 60% (based on all monomers), and then vaporizing unreacted monomers to separate, remove, and recover the same from the polymerization system to thereby reduce the residual monomer content of the polymerization system to 5% by weight or lower.

    摘要翻译: 为了通过简单的步骤经济地制备具有热稳定性优异的聚缩醛共聚物,通过使用不挥发性质子酸催化剂作为聚合催化剂将三恶烷作为主要单体进行共聚,直到转化率达到 至少60%(基于所有单体),然后蒸发未反应的单体以从聚合体系中分离,除去和回收它们,从而将聚合体系的残余单体含量降低至5重量%以下。