摘要:
Polyoxymethylenes are obtained by first irradiating trioxane and/or tetraoxane with ionizing radiation, then contacting the irradiated trioxane and/or tetraoxane with nonirradiated trioxane and/or tetraoxane, and then maintaining the resulted mixture under the polymerizing condition to thereby effect polymerization of the whole system including the nonirradiated trioxane and/or tetraoxane by the action of active species formed in the irradiated trioxane and/or tetraoxane to give polyoxymethylenes readily with a minimum dosage required for such irradiation.
摘要:
A method for producing an oxymethylene copolymer which gives molded articles that are inhibited from emitting formaldehyde and can be reduced in yellowness is provided. In producing an oxymethylene copolymer, an effective polymerization initiator amount is regulated to a value within a given range, the amount being calculated from the amount of perchloric acid or a derivative thereof contained in the polymerization initiator and the amount of triethanolamine contained in all the monomers comprising trioxane and comonomers, which are starting materials for the copolymer.
摘要:
A polyoxymethylene resin molded article comprising 100 parts by mass of a polyoxymethylene resin (A) and 0.1 to 5 parts by mass of a sliding agent (B), wherein four or more dispersion domains of the sliding agent (B) are present in a region of 1000 nm in depth from a surface of the molded article and 12000 nm in width, and the dispersion domain has an average minor diameter of 300 nm or less, and an average major diameter of 600 nm or more and 5000 nm or less.
摘要:
Potentially degradable isohexide based compounds and their polymers, derived from renewable resources, are described. Degradable isohexide-based monomers and polymers obtained from renewable resources are also described. Finally, processes for synthesizing such degradable polymers via copolymerization of the isohexide-based monomers and long chain diols are disclosed.
摘要:
A production method for a polyacetal copolymer that makes deactivation of a catalyst simple and efficient and that achieves a high polymerization yield and high quality using equipment that does not require a cleaning step and a process that involves a simple operation technique. The production method for a polyacetal copolymer uses trioxane as a main monomer and a cyclic ether and/or a cyclic formal having at least one carbon-carbon bond as a comonomer. In the production method, a predetermined heteropoly acid is used as a polymerization catalyst to perform copolymerization, a predetermined salt is added to the reaction product, melt kneading processing is performed, and the polymerization catalyst is deactivated.
摘要:
An initiator for cationic polymerization comprises a salt of a protic acid as well as a protic add. The molar ratio of protic acid to salt is in the range from 1:0.01 to 1:2000. The initiator is used for example for cationic homo- or copolymerization of trioxane, and permits stable and flexible operation of the polymerization.
摘要:
Compositions that can be polymerized and/or crosslinked into coatings by cationic and/or radical irradiation contain at least one photoinitiator and at least one compound having at least one isocyanate function.
摘要:
To economically produce a polyacetal copolymer excellent in properties including thermal stability by copolymerizing trioxane as the main monomer through simple steps, a polyacetal copolymer is produced by copolymerizing trioxane as the main monomer using a nonvolatile protonic acid catalyst as a polymerization catalyst until the conversion reaches at least 60% (based on all monomers), and then vaporizing unreacted monomers to separate, remove, and recover the same from the polymerization system to thereby reduce the residual monomer content of the polymerization system to 5% by weight or lower.