CIRCULAR ECONOMY FOR PLASTIC WASTE TO POLYETHYLENE AND LUBRICATING OIL VIA CRUDE AND ISOMERIZATION DEWAXING UNITS

    公开(公告)号:US20230048572A1

    公开(公告)日:2023-02-16

    申请号:US17964754

    申请日:2022-10-12

    Inventor: Hye-Kyung Timken

    Abstract: Provided is a continuous process for converting waste plastic into recycle for polyethylene polymerization. In one embodiment, the process comprises selecting waste plastics containing polyethylene and/or polypropylene and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. The naphtha/diesel fraction is passed to a crude unit distillation column in a refinery where a straight run naphtha (C5-C8) fraction or a propane/butane (C3-C4) fraction is recovered. The straight run naphtha fraction (C5-C8) or the propane/butane (C3-C4) fraction is passed to a steam cracker for ethylene production. The heavy fraction from the pyrolysis unit can also be passed to an isomerization dewaxing unit to produce a base oil.

    MULTISTAGE PROCESS WITH HYDROTHERMAL LIQUEFACTION

    公开(公告)号:US20230027439A1

    公开(公告)日:2023-01-26

    申请号:US17946194

    申请日:2022-09-16

    Abstract: The disclosure relates to a process for converting lignocellulosic feedstock (10) to renewable product (80), wherein the process comprises the following steps; treating (100) lignocellulosic feedstock (10) with aqueous solution (20) to obtain a mixture (30); heating (110) the mixture (30) of step (a) to a temperature between 290 and 340° C., under a pressure from 90 to 120 bar, to obtain a first product mix (40); separating aqueous phase (53) and oil phase (50), and optionally gas (51) and solids (52), of the first product mix (40) of step (b); and heating (130) the oil phase (50) of step (c) and solvent (60). The heating (130) is optionally followed by fractionation (200) to obtain a light fraction (90) and a heavy fraction (91) and optionally a bottom residue fraction (92) and/or a gaseous fraction.

    Hydrothermic liquefaction outputs and fractions thereof

    公开(公告)号:US11518702B2

    公开(公告)日:2022-12-06

    申请号:US16979639

    申请日:2019-03-13

    Abstract: Commercially beneficial carbon-containing fractions can be recovered from hydrothermal liquefaction reactions in various types of processors. Feedstock slurry from waste solids is placed into a pressurized processor where it is maintained at temperature and pressure for a predetermined period. On discharge from the processor the processed discharge is separated into liquid and solid fractions. Gaseous fractions including carbon dioxide can also be removed or off-taken from the processor. New molecular structures are created in this reaction, resulting in fractions including biogas, biofuels, biosolids and biocrude. Silica, phosphates, potash and low concentration nitrogen based fertilizer, along with carbonaceous material can also be recovered.

    MULTI-STEP PROCESS FOR CONVERSION OF WASTE PLASTICS TO HYDROCARBON LIQUIDS

    公开(公告)号:US20220259502A1

    公开(公告)日:2022-08-18

    申请号:US17668937

    申请日:2022-02-10

    Applicant: Barry Liss

    Inventor: Barry Liss

    Abstract: A method for thermally converting plastics and biomass, and especially non-recyclable waste plastic and or biomass, to primarily liquid phase hydrocarbons is a three step process comprised of hydrothermal treatment, steam cracking and coking. Plastic or plastic and biomass feedstocks are reduced in particle size to inch minus or smaller and suspended in a liquid slurry. The slurry is pumped to high pressure and heated to a temperature high enough to initiate de-polymerization. The resulting partially de-polymerized slurry is sent to a multi-phase separation system via a pressure reduction valve and thereafter subjected to steam cracking to further reduce the average molecular weight of the hydrocarbon components. The resulting gas phase hydrocarbon mixture is quenched, and naphtha, middle distillate, and heavy oils are condensed out. The residual heavy oil phase is further reduced in pressure and sent to a coker from which additional liquid hydrocarbon product is recovered.

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