Abstract:
A lithographic printing plate precursor includes an image-recording layer and a support, and the image-recording layer contains: (A) at least one compound selected from compounds represented by the following formulae (1) and (2); and (B) an infrared absorbing agent: wherein R1 and R2 each represents Ra—SO3—, Ra—CO2— or Ra—OCO2—, Ra represents a monovalent organic group, R3 to R12 each represents a hydrogen atom or a monovalent substituent, or adjacent two of R3 to R12 may be combined with each other to form a ring, X1, Y1 and Z1 and X2, Y2 and Z2 each represents an atomic group necessary to form a thiazole ring, an oxazole ring, an imidazole ring, a triazole ring or a 3H-indole ring, provided that one nitrogen atom of the imidazole ring is connected to a hydrogen atom or a monovalent organic group.
Abstract:
To provide a coloring photosensitive composition and a lithographic printing plate precursor, ensuring that coloring stability after exposure by infrared laser exposure is good and high coloring is obtained even when exposed after the elapse of time.These can be a coloring photosensitive composition containing a microgel encapsulating (A) a polymer having a glass transition temperature of 50° C. or more, (B) a photoinitiator, and (C) an infrared absorbing dye, and a lithographic printing plate precursor having an image-recording layer containing the composition.
Abstract:
A processing method of a lithographic printing plate precursor includes: exposing imagewise a lithographic printing plate precursor comprising a support on a surface of which at least one of: a hydrophilizing treatment; and an undercoat layer has been provided and an image-recording layer, to cure an exposed area of the image-recording layer; and undergoing developing processing with an aqueous solution having pH of from 2 to 10, wherein the aqueous solution comprises an amphoteric surfactant and an anionic surfactant selected from an anionic surfactant having an aliphatic chain and a total number of carbon atoms included in the aliphatic chain of 6 or more and an anionic surfactant having an aromatic ring and a total number of carbon atoms of 12 or more, and a content of the anionic surfactant is from 0.1 to 3.3% by weight of the aqueous solution.
Abstract:
A plate making method of a lithographic printing plate precursor includes: exposing imagewise a lithographic printing plate precursor including a support and an image-forming layer and containing (A) a compound generating an acid with light or heat, (B) an aromatic hydrocarbon compound or heterocyclic compound substituted with a functional group containing a nitrogen atom and (C) an aromatic aldehyde protected with an acid-decomposable group; and removing an unexposed area of the image-forming layer of the lithographic printing plate precursor by supplying at least one of dampening water and ink on a cylinder of a printing machine.
Abstract:
A lithographic printing plate precursor is provided that includes, above a support, a photosensitive layer including (i) a binder polymer, (ii) an ethylenically unsaturated compound, and (iii) a polymerization initiator, the ethylenically unsaturated compound (ii) including a compound represented by Formula (1) below. (In Formula (1), L denotes an (m+n)-valent linking group, the Ds independently denote a group selected from the group consisting of groups represented by Formulae (A) to (D) below, the Rs independently denote a monovalent substituent, m denotes an integer of 1 to 20, and n denotes an integer of 2 to 20.) (In Formulae (A) to (D), X, Y, and Z independently denote an oxygen atom, a sulfur atom, or NR17, R4 to R14 and R17 independently denote a hydrogen atom or a monovalent substituent, R15 denotes a hydrogen atom or a methyl group, R16 denotes a monovalent substituent, and k denotes an integer of 0 to 4.) There is also provided a process for producing a lithographic printing plate, including an exposure step of imagewise exposing the lithographic printing plate precursor and a development step of removing the photosensitive layer of a non-exposed portion in the presence of a developer having buffering capacity.
Abstract:
Both positive-working and negative-working imageable element can have a radiation-sensitive imageable layer that has at least one pigment colorant that does not change color when heated, and at least one dye that can change color when heated. The dye is soluble in the solvent or mixture of solvents used to coat the radiation-sensitive imageable layer on a substrate and the pigment colorant is not. This combination of pigment colorant and dye provide excellent image contrast after imaging, development, and postbaking. The pigment colorant and the dye independently have a maximum absorption of from about 480 to about 700 nm.
Abstract:
A lithographic printing plate precursor includes a support and an image-recording layer containing a star polymer, a radical polymerizable compound and a radical polymerization initiator, the star polymer is a star polymer in which a polymer chain is branched from a central skeleton via a sulfide bond and the polymer chain contains an acid group and a crosslinkable group in a side chain of the polymer chain.
Abstract:
The invention is directed to a negative lithographic printing plate precursor including a support and an image-recording layer, wherein a layer containing a star polymer is provided between the support and the image-recording layer, and the star polymer is preferably a polymer in which from 3 to 10 polymer chains are branched from a central skeleton.
Abstract:
Lithographic printing plates can be prepared and made ready for lithographic printing without wet development or processing. A positive-working lithographic printing plate precursor is exposed to ablating infrared radiation of an energy of at least 1 J/cm2 to form a lithographic printing plate ready for lithographic printing. The positive-working lithographic printing plate precursor has a hydrophilic aluminum substrate, and on the substrate, a crosslinked hydrophilic inner layer, and an oleophilic surface layer that is chemically bonded to the crosslinked hydrophilic inner layer. An intermediate layer provided between the crosslinked hydrophilic inner and oleophilic surface layers. Either this intermediate or the oleophilic surface layer, or both, generally includes an infrared radiation absorbing compound.
Abstract translation:可以制备平版印刷版并准备进行平版印刷,而无需湿法显影或加工。 将正性平版印刷版原版暴露于至少1J / cm 2的能量的消融红外辐射,以形成准备用于平版印刷的平版印刷版。 正性平版印刷版原版具有亲水性的铝基材,在基材上具有交联的亲水性内层和与交联的亲水性内层化学键合的亲油性表面层。 提供在交联的亲水内亲和亲油表面层之间的中间层。 该中间体或亲油性表面层或两者都通常包括红外辐射吸收化合物。
Abstract:
The present invention provides a lithographic printing plate precursor which exhibits satisfactory ink cleanup and restart toning characteristics during printing.Disclosed is a lithographic printing plate precursor comprising a substrate having thereon in order an interlayer containing a copolymer comprising K units and L units, and an image-forming layer, wherein said K unit is derived from a monomer of the formula I: wherein R1 represents a hydrogen atom, a C1-22 linear, branched or cyclic alkyl group, a C1-22 linear, branched or cyclic, substituted alkyl group, a C6-24 aryl group or substituted aryl group, wherein the substituent is selected from a C1-4alkyl group, an aryl group, a halogen atom, a keto group, an ester group, an alkoxy group, or a cyano group; Y represent a single bond, or a C1-22 linear, branched or cyclic alkylene; or CH2═CHPO(OH)2; and said L unit is derived from a monomer of the formula II: CH2═CRCONH2 (II) wherein R is H or CH3, and said K units are present from more than 3% and less than 40% and said L units are present from more than 60% and less than 97% in the copolymer.