Abstract:
The present invention relates to stabilized supports stable at temperatures above 800null C., and method of preparing such supports, which includes adding a rare earth metal to an aluminum-containing precursor prior to calcining. The present invention can be more specifically seen as a support, process and catalyst wherein the stabilized alumina catalyst support comprises a rare earth aluminate with a molar ratio of aluminum to rare earth metal greater than 5:1 and, optionally, an aluminum oxide. More particularly, the invention relates to the use of catalysts comprising rhodium, ruthenium, iridium, or combinations thereof, loaded onto said stabilized supports for the synthesis gas production via partial oxidation of light hydrocarbons, and further relates to gas-to-liquids conversion processes.
Abstract:
A process is disclosed for producing hydrocarbons. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons. In accordance with this invention, the catalyst used in the process includes at least a Fischer-Tropsch metal selected from Groups 8, 9, and 10 of the periodic table and combinations thereof. The catalyst also includes a fluorided clay support material. The fluorided clay is preferably a fluorided bentonite.
Abstract:
A system and/or process for removing water from an alkylation catalyst mixture of an alkylation process is disclosed. The process includes passing an alkylation reaction zone effluent to a settler for separation into a hydrocarbon phase and a catalyst mixture phase; passing at least a portion of the hydrocarbon phase, as a settler effluent stream containing alkylate, water, HF and volatility reducing additive, to a first separator; removing and condensing a first overhead stream from the first separator thereby forming an HF/water stream; passing the HF/water stream to a second separator for separation into a modified HF stream containing HF and volatility reducing additive and into an HF/water azeotrope stream containing HF and water; using the modified HF stream as a part of the alkylation catalyst mixture and; removing water from the system by removing the HF/water azeotrope stream from the second separator.
Abstract:
Implementations described and claimed herein provide systems and methods for breaking cement within an annulus of a wellbore. In one implementation, an annulus cement breaking system includes a cement compression tool operable to be disposed within an inner bore of a casing having a longitudinal length. The casing is disposed within a wellbore formed in a subterranean formation having a cement layer disposed within an annulus formed between the casing and the subterranean formation. One or more actuation elements are coupled with the cement compression tool, and the one or more actuation elements are operable to engage the inner bore. The one or more actuation elements are transitionable between an unactuated state and an actuated stated. The actuated state operable to engage the inner bore of the casing, thereby radially expanding the casing and compressing the cement layer.
Abstract:
A perf wash cement (“P/W/C”) abandonment job is conducted in an offshore oil or gas well annulus (2), in particular the washing or cementing operation using a rotating head (6, 8) with nozzles (7, 9) dispensing wash fluid or cement at pressure. Certain values of parameters of a washing or cementing job have been found surprisingly to affect the quality of the job, or the degree to which they affect the quality of the job has been unexpected. These include rotation rate of the tool, the direction of translational movement of the tool, and the volume flow rate and pressure per nozzle of cement or wash fluid (and hence nozzle size).
Abstract:
Water hammer is oscillatory pressure behavior in a wellbore resulting from the inertial effect of flowing fluid being subjected to an abrupt change in velocity. It is commonly observed at the end of large-scale hydraulic fracturing treatments after fluid injection is rapidly terminated. Factors affecting treatment-related water hammer behavior are disclosed and field studies are introduced correlating water hammer characteristics to fracture intensity and well productivity.
Abstract:
A technique for abandonment of a hydrocarbon well injects cement into the annulus through apertures (5) in the casing (3). The apertures (5) are pre-formed in the casing before the casing is installed at the start of life of the well, and are also fitted with a closure sleeve (6). The apertures (5) remain closed for the lifetime of the well. The closure sleeve (6) is designed to remain operational over the 20-30 year lifetime of the well. When the time comes to plug and abandon the well, a tool (9) is passed down the well on drill pipe (10) to open the apertures (5) by moving the sleeve (6). Wash fluid and then cement are injected from the tool (9) through the apertures (5) to wash and then plug the annulus behind the casing (3).
Abstract:
The invention relates to a method of conducting a perf wash cement (“P/W/C”) abandonment job in an offshore oil or gas well annulus, in particular the washing or cementing operation using a rotating head with nozzles dispensing wash fluid or cement at pressure. A new design of bottom hole assembly is proposed in which the cementing tool has a relatively large diameter in order to optimize pressure whilst the wash tool has a relatively small diameter. The wash process, for a number of reasons, appears to be less sensitive to tool diameter and making the wash tool smaller reduces the overall risk of stuck pipe.
Abstract:
Methods and systems for liquefying natural gas using environmentally-friendly low combustibility refrigerants are provided. Methods of liquefaction include cooling a fluid in an LNG facility via indirect heat exchange with an environmentally-friendly low combustibility refrigerants that are propane, ethane and methane mixed with small amounts of fluorinated olefin, but still within close proximity to the boiling points of the pure refrigerants such that the mixed refrigerants can still be used in an optimized cascade process.
Abstract:
Implementations described and claimed herein provide systems and methods for processing liquefied natural gas (LNG). In one implementation, a feed gas is received and partially condensed into a two-phase stream by expanding the feed gas. A liquid containing fouling components is removed from the two-phase stream. A vapor generated from the two-phase stream is compressed into a compressed feed gas. The compressed feed gas is directed into a feed chiller heat exchanger. The compressed feed gas is free of the fouling components.