Method for preparing fluorine compounds
    51.
    发明授权
    Method for preparing fluorine compounds 有权
    氟化合物的制备方法

    公开(公告)号:US08779217B2

    公开(公告)日:2014-07-15

    申请号:US13382574

    申请日:2010-05-21

    CPC classification number: C07C17/25 C07C17/354 C07C21/18 C07C19/08

    Abstract: The invention relates to a method for preparing fluoropropenes of formula (I) CF3CF═CHR, where R is a hydrogen or a fluorine atom from at least one compound of formula (Ia) CF3CF═CFR, where R has the same meaning as in formula (I), said method including the following steps: (i) hydrogenating at least one compound of formula (Ia) in an adiabatic reactor in the presence of a catalyst with a superstoichiometric amount of hydrogen so as to produce a hydrofluoropropane; (ii) partially condensing the flow from the adiabatic reactor of step (i) so as to produce a gaseous phase fraction, including unreacted hydrogen and a portion of the formed hydrofluoropropane, which is recirculated to step (i), and a liquid phase fraction including the residue of the hydrofluoropropane; (iii) dehydrofluorinating hydrofluoropropane from the liquid fraction of step (ii) using potassium hydroxide in an aqueous reaction medium contained in an agitated reactor so as to produce the fluoropropene of formula (I); and (iv) purifying the fluoropropene obtained in step (iii).

    Abstract translation: 本发明涉及一种制备式(I)CF 3 CF = CHR的氟丙烯的方法,其中R是至少一种式(Ia)CF 3 CF = CFR的化合物的氢或氟原子,其中R的定义与式 (I),所述方法包括以下步骤:(i)在具有超化学计量的氢的催化剂存在下,在绝热反应器中氢化至少一种式(Ia)化合物以产生氢氟丙烷; (ii)部分地冷凝来自步骤(i)的绝热反应器的流,以便产生气相馏分,包括未反应的氢气和一部分所形成的氢氟丙烷,其循环至步骤(i),以及液相馏分 包括氢氟丙烷的残留物; (iii)使用氢氧化钾在搅拌反应器中的含水反应介质中,从步骤(ii)的液体馏分中脱氢氟化氢氟丙烷,以制备式(I)的氟丙烯; 和(iv)纯化步骤(iii)中获得的氟丙烯。

    Process for the preparation of fluorinated compounds
    56.
    发明授权
    Process for the preparation of fluorinated compounds 有权
    氟化合物的制备方法

    公开(公告)号:US08389779B2

    公开(公告)日:2013-03-05

    申请号:US12842737

    申请日:2010-07-23

    CPC classification number: C07C21/18 C07C17/25 C07C17/354 C07C17/383 C07C19/08

    Abstract: A subject-matter of the invention is a process for the preparation of 2,3,3,3-tetrafluoro-1-propene comprising the following stages: (i) hydrogenation of hexafluoropropylene to give 1,1,1,2,3,3-hexafluoropropane; (ii) dehydrofluorination of the 1,1,1,2,3,3-hexafluoropropane obtained in the preceding stage to give 1,2,3,3,3-pentafluoro-1-propene; (iii) hydrogenation of the 1,2,3,3,3-pentafluoro-1-propene obtained in the preceding stage to give 1,1,1,2,3-pentafluoropropane; (iv) purification of the 1,1,1,2,3-pentafluoropropane obtained in the preceding stage; and (v) dehydrofluorination of the 1,1,1,2,3-pentafluoropropane obtained in the preceding stage to give 2,3,3,3-tetrafluoro-1-propene; and (vi) purification of the 2,3,3,3-tetrafluoro-1-propene of the preceding stage.

    Abstract translation: 本发明的主题是制备2,3,3,3-四氟-1-丙烯的方法,包括以下步骤:(i)六氟丙烯的氢化,得到1,1,1,2,3, 3-六氟丙烷; (ii)前段得到的1,1,1,2,3,3-六氟丙烷的脱氟化氢,得到1,2,3,3,3-五氟-1-丙烯; (iii)在前一阶段获得的1,2,3,3,3-五氟-1-丙烯的氢化,得到1,1,1,2,3-五氟丙烷; (iv)前一阶段获得的1,1,1,2,3-五氟丙烷的纯化; 和(v)前一阶段获得的1,1,1,2,3-五氟丙烷的脱氟化氢,得到2,3,3,3-四氟-1-丙烯; 和(vi)前一阶段的2,3,3,3-四氟-1-丙烯的纯化。

    DRIVING MECHANISM FOR WATCH MOVEMENT
    57.
    发明申请
    DRIVING MECHANISM FOR WATCH MOVEMENT 审中-公开
    用于手表运动的驱动机构

    公开(公告)号:US20120120775A1

    公开(公告)日:2012-05-17

    申请号:US13291540

    申请日:2011-11-08

    CPC classification number: G04B1/12 G04B1/145

    Abstract: Driving mechanism for watch movement having: a barrel mounted on an arbor so as to be capable of turning around an axis of the arbor when the driving mechanism is wound up. A mainspring unit has a first and second spring coiled up inside the barrel in superimposed fashion and coaxial one relative to the other. The first and second springs are coupled at one of their extremities to the barrel and to the arbor, respectively. The unit has a plate mounted coaxially between the two springs, and mounted rotatively on the axis. The first and second springs are coupled at their other extremity to the centre and to the periphery of the plate, respectively, so that the two springs simultaneously wind up around the axis when the driving mechanism is wound up.

    Abstract translation: 手表机芯的驱动机构具有:安装在心轴上的筒体,以便当驱动机构被卷起时能够围绕心轴的轴线转动。 主发条单元具有第一和第二弹簧,其以叠加的方式在筒内卷起,并且相对于另一个共轴。 第一和第二弹簧分别在其一端连接到枪管和心轴。 该单元具有同轴地安装在两个弹簧之间的板,并且可旋转地安装在轴上。 第一和第二弹簧在其另一端分别联接到板的中心和周边,使得当驱动机构被卷绕时,两个弹簧同时卷绕在轴上。

    DOUBLE FLOW HEAT EXCHANGER DEVICE
    58.
    发明申请
    DOUBLE FLOW HEAT EXCHANGER DEVICE 审中-公开
    双流热交换器装置

    公开(公告)号:US20110132583A1

    公开(公告)日:2011-06-09

    申请号:US12994555

    申请日:2009-05-27

    CPC classification number: F24F12/006 Y02B30/563

    Abstract: The invention relates to a device (1) enabling the exchange of heat between a first fluid (2) and a second fluid (3) flowing counter current through the device, comprising: an outer casing (4) sealed against the two fluids, having a long shape that extends between first (7) and second (9) ends; a wall (5) enabling heat exchange between the fluids, housed inside the outer casing; a first inlet (6) for the first fluid (2), formed at the first end (7) of the outer casing; a second inlet (8) for the second fluid (3), formed at the second end (9) of the outer casing (4) opposite the first end (7), the aforementioned exchange wall (5) extending between the first (6) and second (8) fluid inlets; a first outlet (10) for extracting the first fluid (2) from the outer casing (4), formed in the area at the first end (7); a second outlet (11) for extracting the second fluid (3) from the outer casing (4), formed in the area at the second end (9); a first pipe (12) enabling the flow of the first fluid (2) inside the outer casing (4); and a second pipe (13) enabling the flow of the second fluid (3) inside the outer casing (4), such that (i) the second outlet (11) and the first inlet (6) and (ii) the first outlet (10) and the second inlet (8) are separated respectively by a distance equal to or greater than the length (□) of the exchange wall. The invention also relates to the different uses of the device.

    Abstract translation: 本发明涉及一种能够在第一流体(2)和流过逆流装置的第二流体(3)之间进行热交换的装置(1),包括:密封在两个流体上的外壳(4),具有 在第一(7)和第二(9)端之间延伸的长形状; 壁(5),其能够容纳在所述外壳内的所述流体之间的热交换; 用于第一流体(2)的第一入口(6),形成在外壳的第一端(7)处; 形成在与第一端(7)相对的外壳(4)的第二端(9)处的第二流体(3)的第二入口(8),上述交换壁(5)在第一(6) )和第二(8)个流体入口; 第一出口(10),用于从所述外壳(4)提取所述第一流体(2),形成在所述第一端(7)的区域中; 第二出口(11),用于从所述外壳(4)中提取所述第二流体(3),形成在所述第二端(9)的区域中; 能够使第一流体(2)流入外壳(4)内部的第一管(12); 以及能够使第二流体(3)在外壳(4)内流动的第二管(13),使得(i)第二出口(11)和第一入口(6)和(ii)第一出口 (10)和第二入口(8)分别分开等于或大于交换壁的长度(□)的距离。 本发明还涉及该装置的不同用途。

    Building material and method of making and installing the same
    60.
    发明授权
    Building material and method of making and installing the same 有权
    建筑材料及其制造和安装方法

    公开(公告)号:US07600356B2

    公开(公告)日:2009-10-13

    申请号:US10849279

    申请日:2004-05-19

    Abstract: The building material, in one embodiment, has a jointing system that is uniquely configured to cover the frame of a structure. This building material, in one embodiment, is a building board with a conforming flange that is embossed onto the board and adapted to engage or mate with an end of an adjacent board. In another embodiment, the building material is an engineered panel joint comprised of a building board and a flexible or hinged article attached to the back surface of the building board. The article is preferably attached to the building board by an adhesive and extends beyond the edge and away from the building board for receiving a fastener to fix the building board to the structure. The fastener is preferably a nail. Components of the building material are preferably attached to the frame of the structure through the use of a single row of nails while maintaining or enhancing the shear strength performance of the building board system.

    Abstract translation: 在一个实施例中,建筑材料具有唯一地构造成覆盖结构的框架的接合系统。 在一个实施例中,该建筑材料是建筑板,该建筑板具有凸起并且适于与相邻板的端部接合或配合的符合凸缘。 在另一个实施例中,建筑材料是由建筑板和连接到建筑板的后表面的柔性或铰接物品组成的工程板接合件。 该制品优选通过粘合剂附接到建筑板上并且延伸超过边缘并远离建筑板,用于接收紧固件以将建筑板固定到结构上。 紧固件优选是钉子。 建筑材料的部件优选通过使用单排钉子而附接到结构的框架,同时保持或增强建筑板系统的剪切强度性能。

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