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    Polymer compositions
    3.
    发明授权
    Polymer compositions 失效
    聚合物组合物

    公开(公告)号：US08481640B2

    公开(公告)日：2013-07-09

    申请号：US12597788

    申请日：2008-04-30

    申请人： Helen L. Gough ,  Iain A. MacKinnon ,  Sarah O'Hare ,  Geraldine Durand

    发明人： Helen L. Gough ,  Iain A. MacKinnon ,  Sarah O'Hare ,  Geraldine Durand

    IPC分类号： C08L83/05

    CPC分类号： C08G77/46 ,  C08K5/54 ,  C08L83/04 ,  C08L83/12 ,  C08L2666/44 ,  C08L83/00

    摘要： The invention relates to a water-insoluble hydrophilic polymer network comprising polyorganosiloxane polyoxyalkylene block copolymer moieties characterized that they are linked to each other through an organosilicon cross-linking moiety, provided that the cross-linking moiety forming the links between polyorganosiloxane polyoxyalkylene block copolymer moieties result from an addition reaction between cross-linking sites present on the polyorganosiloxane polyoxyalkylene block copolymer moieties prior to formation of the hydrophilic polymer network, selected from silicon-bonded hydrogen atoms and aliphatically unsaturated groups, and reactive groups present on the cross-linking moiety prior to formation of the hydrophilic polymer network. Also disclosed is a process for making the polymer network, and a curable composition able to be reacted into such polymer network.

    摘要翻译： 本发明涉及包含聚有机硅氧烷聚氧化烯嵌段共聚物部分的水不溶性亲水性聚合物网络，其特征在于它们通过有机硅交联部分彼此连接，条件是形成聚有机硅氧烷聚氧化烯嵌段共聚物部分之间的连接的交联部分导致 在形成亲水性聚合物网络之前，存在于聚有机硅氧烷聚氧化烯嵌段共聚物部分上的交联位点之间的加成反应，选自与硅键合的氢原子和脂族不饱和基团，以及存在于交联部分之前的反应性基团 形成亲水性聚合物网络。 还公开了制备聚合物网络的方法，以及可固化的组合物能够反应成这样的聚合物网络。

    Polymer and polymer compositions
    4.
    发明授权
    Polymer and polymer compositions 有权
    聚合物和聚合物组合物

    公开(公告)号：US08592545B2

    公开(公告)日：2013-11-26

    申请号：US12597783

    申请日：2008-04-30

    申请人： Iain A. Mackinnon ,  Sarah O'Hare ,  Francois De Buyl ,  Geraldine Durand

    发明人： Iain A. Mackinnon ,  Sarah O'Hare ,  Francois De Buyl ,  Geraldine Durand

    IPC分类号： C08G77/18

    CPC分类号： C08G77/46 ,  C08K5/54 ,  C08L83/04 ,  C08L83/12 ,  C08L2666/44 ,  C08L83/00

    摘要： A polyorganosiloxane polyoxyalkylene block copolymer having one or more polyorganosiloxane blocks and one or more polyoxyalkylene blocks linked to each other via divalent radicals which comprises at least two silicon-bonded alkoxy groups, preferably of the form PS (A PO)m (A PS)n, wherein PO is a polyoxyalkylene block, PS represents a polyorganosiloxane block, A is a divalent radical, m and n have independently a value of at least 1, comprising at least one alkoxy-substituted siloxane unit of the formula (R′)q(OR)—SiO3−q/2 ′, wherein R represents an alkyl group having 1 to 4 carbon atoms and each R′ represents an alkyl group having 1 to 6 carbon atoms, a phenyl group, or an alkoxy group of the formula —OR and q has a value of 0, 1 or 2, provided at least two silicon-bonded groups OR are present in the block copolymer. Also provided is a curable composition of the above which may comprise a condensation catalyst and a hydrophilic polymer network made from curing the composition in the presence of moisture, which exhibit interesting reversible hydrophilic properties.

    摘要翻译： 一种具有一个或多个聚有机硅氧烷嵌段和一个或多个聚氧亚烷基嵌段的聚有机硅氧烷聚氧化烯嵌段共聚物，其通过二价基团彼此连接，该二价基团包含至少两个与硅键合的烷氧基，优选形式为PS（A PO）m（A PS）n 其中PO是聚氧化烯嵌段，PS表示聚有机硅氧烷嵌段，A是二价基团，m和n独立地为至少为1的值，包含至少一个式（R'）q（R'）q的烷氧基取代的硅氧烷单元， OR）-SiO 3-q / 2'，其中R表示具有1至4个碳原子的烷基，并且每个R'表示具有1至6个碳原子的烷基，苯基或式-OR的烷氧基 并且q具有0,1或2的值，只要至少两个硅键合基团或存在于嵌段共聚物中。 还提供了上述可固化组合物，其可以包含缩合催化剂和通过在水分存在下固化组合物制成的亲水性聚合物网络，其显示出有趣的可逆亲水性质。

    CONDENSATION REACTION CURABLE SILICONE ORGANIC BLOCK COPOLYMER COMPOSITION CONTAINING A PHOSPHONATE CATALYST AND METHODS FOR THE PREPARATION AND USE OF THE COMPOSITION
    5.
    发明申请
    CONDENSATION REACTION CURABLE SILICONE ORGANIC BLOCK COPOLYMER COMPOSITION CONTAINING A PHOSPHONATE CATALYST AND METHODS FOR THE PREPARATION AND USE OF THE COMPOSITION 审中-公开
    含有磷酸酯催化剂的凝结反应可固化有机硅嵌段共聚物组合物及其组合物的制备和使用方法

    公开(公告)号：US20140024774A1

    公开(公告)日：2014-01-23

    申请号：US14007734

    申请日：2012-03-12

    申请人： Simon Cook ,  Geraldine Durand ,  Thomas Easton ,  Sarah O'Hare ,  Avril Surgenor ,  Richard Taylor

    发明人： Simon Cook ,  Geraldine Durand ,  Thomas Easton ,  Sarah O'Hare ,  Avril Surgenor ,  Richard Taylor

    IPC分类号： C08G77/46 ,  C09D183/12 ,  C08K5/5419

    CPC分类号： C08K5/5419 ,  C08G77/12 ,  C08G77/18 ,  C08G77/20 ,  C08G77/46 ,  C08K5/0025 ,  C08K5/524 ,  C08K5/5317 ,  C08K5/5425 ,  C08L83/12 ,  C09D183/12

    摘要： A condensation reaction curable composition comprises a new catalyst, Dow Corning® 4-6085, and a polyorganosiloxane polyoxyalkylene block copolymer having one or more polyorganosiloxane blocks and one or more polyoxyalkylene blocks linked to each other via divalent radicals which comprises at least two silicon-bonded alkoxy groups, preferably of the form PS-(A-PO)m-(A-PS)n, wherein PO is a polyoxyalkylene block, PS represents a polyorganosiloxane block, A is a divalent radical, subscripts m and n have independently a value of at least 1, comprising at least one alkoxy-substituted siloxane unit of the formula (R′)q(OR)—SiO3-q/2, wherein R represents an alkyl group having 1 to 4 carbon atoms and each R′ represents an alkyl group having 1 to 6 carbon atoms, a phenyl group, or an alkoxy group of the formula —OR and subscript q has a value of 0, 1 or 2, provided at least two silicon-bonded groups OR are present in the block copolymer.

    摘要翻译： 缩合反应固化的组合物包含新的催化剂，Dow Corning 4-6085和具有一个或多个聚有机硅氧烷嵌段和一个或多个聚氧化烯嵌段的聚有机硅氧烷聚氧化烯嵌段共聚物，该聚有机硅氧烷嵌段通过二价基团彼此连接，该二价基团包含至少两个硅键合 烷氧基，优选形式为PS-（A-PO）m-（A-PS）n，其中PO是聚氧化烯嵌段，PS表示聚有机硅氧烷嵌段，A是二价基团，下标m和n独立地为 至少一个，包含至少一个式（R'）q（OR）-SiO 3-q / 2的烷氧基取代的硅氧烷单元，其中R表示具有1至4个碳原子的烷基，并且每个R'表示 具有1至6个碳原子的烷基，苯基或式-OR和下标q的烷氧基具有0,1或2的值，只要至少两个硅键合基团或存在于嵌段共聚物中 。

    Polymer Compositions
    8.
    发明申请
    Polymer Compositions 失效
    聚合物组合物

    公开(公告)号：US20100168325A1

    公开(公告)日：2010-07-01

    申请号：US12597788

    申请日：2008-04-30

    申请人： Helen L. Gough ,  Iain A. Mackinnon ,  Sarah O'Hare ,  Geraldine Durand

    发明人： Helen L. Gough ,  Iain A. Mackinnon ,  Sarah O'Hare ,  Geraldine Durand

    IPC分类号： C08L83/05

    CPC分类号： C08G77/46 ,  C08K5/54 ,  C08L83/04 ,  C08L83/12 ,  C08L2666/44 ,  C08L83/00

    摘要： The invention relates to a water-insoluble hydrophilic polymer network comprising polyorganosiloxane polyoxyalkylene block copolymer moieties characterised that they are linked to each other through an organosilicon cross-linking moiety, provided that the cross-linking moiety forming the links between polyorganosiloxane polyoxyalkylene block copolymer moieties result from an addition reaction between cross-linking sites present on the polyorganosiloxane polyoxyalkylene block copolymer moieties prior to formation of the hydrophilic polymer network, selected from silicon-bonded hydrogen atoms and aliphatically unsaturated groups, and reactive groups present on the cross-linking moiety prior to formation of the hydrophilic polymer network. Also disclosed is a process for making the polymer network, and a curable composition able to be reacted into such polymer network.

    摘要翻译： 本发明涉及包含聚有机硅氧烷聚氧化烯嵌段共聚物部分的水不溶性亲水性聚合物网络，其特征在于它们通过有机硅交联部分彼此连接，条件是形成聚有机硅氧烷聚氧化烯嵌段共聚物部分之间的连接的交联部分导致 在形成亲水性聚合物网络之前，存在于聚有机硅氧烷聚氧化烯嵌段共聚物部分上的交联位点之间的加成反应，选自与硅键合的氢原子和脂族不饱和基团，以及存在于交联部分之前的反应性基团 形成亲水性聚合物网络。 还公开了制备聚合物网络的方法，以及可固化的组合物能够反应成这样的聚合物网络。

    Polymer And Polymer Compositions
    9.
    发明申请
    Polymer And Polymer Compositions 有权
    聚合物和聚合物组合物

    公开(公告)号：US20100168309A1

    公开(公告)日：2010-07-01

    申请号：US12597783

    申请日：2008-04-30

    申请人： Iain A. Mackinnon ,  Sarah O'Hare ,  Francois De Buyl ,  Geraldine Durand

    发明人： Iain A. Mackinnon ,  Sarah O'Hare ,  Francois De Buyl ,  Geraldine Durand

    IPC分类号： C08L83/04 ,  C08K3/30 ,  C08K3/26 ,  C08K3/36 ,  C08K3/34

    CPC分类号： C08G77/46 ,  C08K5/54 ,  C08L83/04 ,  C08L83/12 ,  C08L2666/44 ,  C08L83/00

    摘要： A polyorganosiloxane polyoxyalkylene block copolymer having one or more polyorganosiloxane blocks and one or more polyoxyalkylene blocks linked to each other via divalent radicals which comprises at least two silicon-bonded alkoxy groups, cc preferably of the form PS (A PO)m(A PS)n, wherein PO is a polyoxyalkylene block, PS represents a polyorganosiloxane block, A is a divalent radical, m and n have independently a value of at least 1, comprising at least one alkoxy-substituted siloxane unit of the formula (R′)q(OR)—SiO3-q/2, wherein R represents an alkyl group having 1 to 4 carbon atoms and each R′ represents an alkyl group having 1 to 6 carbon atoms, a phenyl group, or an alkoxy group of the formula —OR and q has a value of 0, 1 or 2, provided at least two silicon-bonded groups OR are present in the block copolymer. Also provided is a curable composition of the above which may comprise a condensation catalyst and a hydrophilic polymer network made from curing the composition in the presence of moisture, which exhibit interesting reversible hydrophilic properties.

    摘要翻译： 一种具有一个或多个聚有机硅氧烷嵌段和一个或多个聚氧化烯嵌段的聚有机硅氧烷聚氧化烯嵌段共聚物，其通过包含至少两个与硅键合的烷氧基，优选形式为PS（A PO）m（A PS） n，其中PO是聚氧化烯嵌段，PS表示聚有机硅氧烷嵌段，A是二价基团，m和n独立地为至少为1的值，包含至少一个式（R'）q的烷氧基取代的硅氧烷单元 （OR）-SiO 3-q / 2，其中R表示具有1至4个碳原子的烷基，并且每个R'表示具有1至6个碳原子的烷基，苯基或式-OR的烷氧基 并且q具有0,1或2的值，只要至少两个硅键合基团或存在于嵌段共聚物中。 还提供了上述可固化组合物，其可以包含缩合催化剂和通过在水分存在下固化组合物制成的亲水性聚合物网络，其显示出有趣的可逆亲水性质。