公开(公告)号：US20090183982A1

公开(公告)日：2009-07-23

申请号：US12354403

申请日：2009-01-15

Applicant: Hideko Inoue ,  Hiroko Nomura

Inventor： Hideko Inoue ,  Hiroko Nomura

IPC: B01J19/12

CPC classification number: C07D241/12

Abstract: A novel synthesis method of a triarylpyrazine derivative, in particular, a manufacturing method by which a triarylpyrazine derivative, in specific, a 2,3,5-triarylpyrazine derivative in which an aryl group at a 5-position includes a substituent having an electron-withdrawing property can be synthesized with high yield as compared to a conventional method is provided. By using a synthesis method in which a mixture including a 1-aryl-2-(methylsulfinyl)ethanone derivative, meso-1,2-diarylethylenediamine, and a dehydrogenation agent is irradiated with a microwave to be reacted, the above object is achieved.

Abstract translation: 三芳基吡嗪衍生物的新颖合成方法，特别是三芳基吡嗪衍生物，特别是其中5位的芳基含有具有电子发射性的取代基的2,3,5-三芳基吡嗪衍生物的制造方法， 与常规方法相比，可以以高产率合成取出性质。 通过使用其中包含1-芳基-2-（甲基亚磺酰基）乙酮衍生物，内消旋-1,2-二芳基乙二胺和脱氢剂的混合物被微波照射以进行反应的合成方法，实现了上述目的。

公开(公告)号：US20090015143A1

公开(公告)日：2009-01-15

申请号：US11908010

申请日：2006-03-14

Applicant: Hideko Inoue ,  Satoko Shitagaki ,  Satoshi Seo ,  Nobuharu Ohsawa

Inventor： Hideko Inoue ,  Satoko Shitagaki ,  Satoshi Seo ,  Nobuharu Ohsawa

IPC: H01J1/63 ,  C07F15/00

CPC classification number: H01L51/0085 ,  C07F15/0033 ,  C09K11/06 ,  C09K2211/1044 ,  C09K2211/185 ,  H01L51/0079 ,  H01L51/5016 ,  H05B33/14

Abstract: It is an object of the present invention to provide an organometallic complex which can increase recombination efficiency of electrons and holes. One aspect of the present invention is an organometallic complex having a structure represented by a general formula (1), wherein each of R1 and R2 is any of a halogen group, a —CF3 group, a cyano group, and an alkoxycarbonyl group, each of R3 and R4 is any of hydrogen and an alkyl group having 1 to 4 carbon atoms, and M is an element that belongs to Group 9 or 10 of the periodic table.

Abstract translation: 本发明的目的是提供一种能提高电子和空穴的复合效率的有机金属络合物。 本发明的一个方面是具有由通式（1）表示的结构的有机金属配合物，其中R 1和R 2各自为卤素基，-CF 3基，氰基和烷氧基羰基中的任一个，各自为 R 3和R 4是氢和具有1至4个碳原子的烷基中的任何一个，M是属于周期表第9或10族的元素。

公开(公告)号：US20080312437A1

公开(公告)日：2008-12-18

申请号：US12132143

申请日：2008-06-03

Applicant: Hideko Inoue ,  Satoshi Seo ,  Nobuharu Ohsawa

Inventor： Hideko Inoue ,  Satoshi Seo ,  Nobuharu Ohsawa

IPC: C07F15/00

CPC classification number: C09K11/06 ,  C07F15/0033

Abstract: According to the present invention, a wider variation of organometallic complexes that can emit phosphorescence can be provided by applying, as a ligand, an organic compound from which a variety of derivatives can be easily synthesized. In particular, an organometallic complex having a sharp emission spectrum is provided. Further, an organometallic complex having high emission efficiency is provided. An organometallic complex represented by the general formula (G1) is provided. In the formula, Ar represents an aryl group, R represents an alkoxy group having 1 to 4 carbon atoms, and R1 and R2 individually represent either hydrogen or an alkyl group having 1 to 4 carbon atoms.

Abstract translation: 根据本发明，可以通过应用可以容易地合成各种衍生物的有机化合物作为配体，提供可发射磷光的有机金属配合物的更广泛的变化。 特别地，提供具有尖锐发射光谱的有机金属络合物。 此外，提供了发光效率高的有机金属络合物。 提供由通式（G1）表示的有机金属络合物。 式中，Ar表示芳基，R表示碳原子数1〜4的烷氧基，R 1和R 2分别表示氢或碳原子数1〜4的烷基。

公开(公告)号：US20080231177A1

公开(公告)日：2008-09-25

申请号：US12048516

申请日：2008-03-14

Applicant: Ryoji Nomura ,  Satoshi Seo ,  Nobuharu Ohsawa ,  Tsunenori Suzuki ,  Sachiko Kawakami ,  Harue Osaka ,  Hideko Inoue

Inventor： Ryoji Nomura ,  Satoshi Seo ,  Nobuharu Ohsawa ,  Tsunenori Suzuki ,  Sachiko Kawakami ,  Harue Osaka ,  Hideko Inoue

IPC: H01J1/63

CPC classification number: H05B33/14 ,  C09K11/06 ,  C09K2211/1011 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/185 ,  H01L27/3211 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/0072 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/5012 ,  H01L51/5016 ,  H01L2251/552 ,  H05B33/18 ,  H05B33/20

Abstract: The present invention provides light-emitting devices having excellent characteristics and electronic devices having excellent characteristics, having such light-emitting devices. Specifically, the present invention provides a light-emitting device includes a first light-emitting element, a second light-emitting element, and a third light-emitting element which emit light having different color from each other. The first light-emitting element includes a first anode; a first cathode; and a first light-emitting layer and a second light-emitting layer between the first anode and the first cathode, wherein the first light-emitting layer includes a first high light-emitting substance and a first organic compound, and the second light-emitting layer includes the first high light-emitting substance and a second organic compound, wherein the first light-emitting layer is in contact with the first anode side of the second light-emitting layer, and wherein the first organic compound is an organic compound having a hole-transporting property and the second organic compound is an organic compound having an electron-transporting property. The second light-emitting element includes a second anode; a second cathode; and a third light-emitting layer and a layer for controlling carrier transfer between the second anode and the second cathode, wherein the third light-emitting layer includes a second high light-transmitting substance, wherein the layer for controlling carrier transfer includes a third organic compound and a fourth organic compound, and is provided between the third light-emitting layer and the second cathode, wherein the third organic compound is an organic compound having an electron-transporting property and the fourth organic compound is an organic compound having an electron-trapping property; and wherein the third organic compound is included more than the fourth organic compound in the layer for controlling carrier transfer. The third light-emitting element includes a third anode; a third cathode; and a fourth light-emitting layer, wherein the fourth light-emitting layer includes a fifth organic compound, a sixth organic compound, and a third high light-emitting substance, wherein the fifth organic compound is an organic compound having a hole-transporting property, and the sixth organic compound is an organic compound having an electron-transporting property, and wherein the third high light-emitting substance is a substance which emits phosphorescence.

公开(公告)号：US07413816B2

公开(公告)日：2008-08-19

申请号：US10736679

申请日：2003-12-17

Applicant: Hideko Inoue ,  Satoshi Seo ,  Atsushi Tokuda ,  Ryoji Nomura

Inventor： Hideko Inoue ,  Satoshi Seo ,  Atsushi Tokuda ,  Ryoji Nomura

IPC: H01L51/54 ,  C09K11/06

CPC classification number: C07C251/24 ,  C07F15/0033 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/185 ,  Y10S428/917

Abstract: A white or whitish luminescent material for phosphorescence is provided by synthesizing an organometallic complex that is able to convert a triplet excited state into light emission. In particular, a white electroluminescent device that has a high luminous efficiency and can be manufactured easily is provided by using the organometallic complex to manufacture a white or whitish electroluminescent device. The electroluminescent device is used to provide a light-emitting device with low power consumption. A fluorescent and phosphorescent material represented by a general formula (2) is synthesized. Since this material can emit both components of fluorescence and phosphorescence in the region of visible light, white or whitish luminescence can be achieved, which is applied to an electroluminescent device or a light-emitting device

Abstract translation: 通过合成能够将三线态激发态转化为发光的有机金属络合物，提供了用于磷光的白色或发白的发光材料。 特别地，通过使用有机金属络合物制造白色或发白的电致发光器件，提供了具有高发光效率并且可容易地制造的白色电致发光器件。 电致发光器件用于提供具有低功耗的发光器件。 合成由通式（2）表示的荧光和磷光材料。 由于这种材料可以在可见光区域中发射荧光和磷光的两个成分，所以可以实现白色或白色的发光，其被施加到电致发光器件或发光器件

公开(公告)号：US20080122350A1

公开(公告)日：2008-05-29

申请号：US11984357

申请日：2007-11-16

Applicant: Junichiro Sakata ,  Hideko Inoue ,  Satoshi Seo ,  Nobuharu Ohsawa

Inventor： Junichiro Sakata ,  Hideko Inoue ,  Satoshi Seo ,  Nobuharu Ohsawa

IPC: H01L27/28 ,  B05D5/12

CPC classification number: H01L51/5203 ,  H01L51/006 ,  H01L51/0067 ,  H01L51/008 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/0087 ,  H01L51/009 ,  H01L51/5012

Abstract: A light-emitting element is provided which has a light-emitting layer between a first electrode and a second electrode, where the light-emitting layer has a first layer and a second layer; the first layer contains a first organic compound and a third organic compound; the second layer contains a second organic compound and the third organic compound; the first layer is provided to be in contact with the second layer on the first electrode side; the first organic compound is an organic compound with an electron transporting property; the second organic compound is an organic compound with a hole transporting property; the third organic compound has an electron trapping property; and light emission from the third organic compound can be obtained when voltage is applied to the first electrode and the second electrode so that the potential of the first electrode is higher than that of the second electrode.

Abstract translation: 提供一种在第一电极和第二电极之间具有发光层的发光元件，其中发光层具有第一层和第二层; 第一层包含第一有机化合物和第三有机化合物; 第二层包含第二有机化合物和第三有机化合物; 第一层设置成与第一电极侧的第二层接触; 第一有机化合物是具有电子传输性质的有机化合物; 第二有机化合物是具有空穴传输性的有机化合物; 第三有机化合物具有电子捕获性; 并且当对第一电极和第二电极施加电压使得第一电极的电位高于第二电极的电位时，可以获得来自第三有机化合物的发光。

公开(公告)号：US20070241667A1

公开(公告)日：2007-10-18

申请号：US10590703

申请日：2005-05-17

Applicant: Nobuharu Ohsawa ,  Hiroko Abe ,  Hideko Inoue ,  Satoko Shitagaki ,  Satoshi Seo

Inventor： Nobuharu Ohsawa ,  Hiroko Abe ,  Hideko Inoue ,  Satoko Shitagaki ,  Satoshi Seo

IPC: H05B33/14 ,  C07D241/36

CPC classification number: C09K11/06 ,  C09K2211/1044 ,  C09K2211/185 ,  H01L27/3244 ,  H01L51/0061 ,  H01L51/0072 ,  H01L51/0085 ,  H01L51/5016 ,  H01L51/5278 ,  H05B33/14 ,  Y10S428/917

Abstract: It is an object of the present invention to obtain an organometallic complex that is capable of converting an excited triplet state into luminescence, a light-emitting element that can be driven for a long time, is high in luminous efficiency, and has a favorable long lifetime, and a light-emitting device using the light-emitting element. The present invention provides a light-emitting element that has a pair of electrodes (an anode and a cathode) and a light-emitting layer between a pair of electrodes, where the light-emitting layer includes an organometallic complex represented by the following general formula (5) and one of a compound that has a larger energy gap than the organometallic complex and a compound that has a larger ionization potential and a smaller electron affinity than the organometallic complex, and provides a light-emitting device using the light-emitting device.

Abstract translation: 本发明的目的是获得能够将激发的三线态转化为发光的有机金属络合物，长时间驱动的发光元件的发光效率高，并且具有良好的长 寿命和使用发光元件的发光器件。 本发明提供一种在一对电极之间具有一对电极（阳极和阴极）和发光层的发光元件，其中发光层包括由以下通式表示的有机金属络合物 （5）和具有比有机金属络合物更大的能隙的化合物和具有比有机金属络合物更大的电离电位和更小的电子亲和性的化合物之一，并且提供使用该发光器件的发光器件 。

公开(公告)号：US07252895B2

公开(公告)日：2007-08-07

申请号：US11342424

申请日：2006-01-30

Applicant: Satoshi Seo ,  Hideko Inoue ,  Atsushi Tokuda ,  Ryoji Nomura

Inventor： Satoshi Seo ,  Hideko Inoue ,  Atsushi Tokuda ,  Ryoji Nomura

IPC: H01L51/54

CPC classification number: C09K11/06 ,  C07C49/92 ,  C07D207/16 ,  C07F15/0033 ,  C07F15/0086 ,  C09K2211/1007 ,  C09K2211/1022 ,  C09K2211/1092 ,  C09K2211/1458 ,  C09K2211/1466 ,  C09K2211/185 ,  Y10S428/917

Abstract: The present invention is directed to a novel phosphorescent compound formed by synthesizing an orthometallated complex by using easily-synthesized ligands. The invention is further directed to an electroluminescent device having high luminous efficiency by using the phosphorescent compound. Moreover, the invention is also directed to a light-emitting device operating at a low voltage by using the electroluminescent device. According to the present invention, a phosphorescent compound represented by general formula [formula 1] is synthesized. Further, an electroluminescent device containing the phosphorescent compound is formed. In order to generate phosphorescent emission more efficiently, a heavy metal is preferably used as a central metal from the perspective of heavy atom effects. Therefore, one feature of the present invention is that the central metal M in the below general formula [formula 1] is iridium or platinum

Abstract translation: 本发明涉及通过使用容易合成的配体合成邻位金属络合物形成的新型磷光化合物。 本发明还涉及通过使用磷光化合物具有高发光效率的电致发光器件。 此外，本发明还涉及通过使用电致发光器件在低电压下工作的发光器件。 根据本发明，合成由通式[式1]表示的磷光化合物。 此外，形成含有磷光化合物的电致发光器件。 为了更有效地产生磷光发射，从重原子效应的观点出发，优选使用重金属作为中心金属。 因此，本发明的一个特征是下述通式[式1]中的中心金属M是铱或铂

公开(公告)号：US20060128974A1

公开(公告)日：2006-06-15

申请号：US11342424

申请日：2006-01-30

Applicant: Satoshi Seo ,  Hideko Inoue ,  Atsushi Tokuda ,  Ryoji Nomura

Inventor： Satoshi Seo ,  Hideko Inoue ,  Atsushi Tokuda ,  Ryoji Nomura

IPC: C07D333/04 ,  C09K11/06 ,  H01L51/54 ,  H05B33/14

CPC classification number: C09K11/06 ,  C07C49/92 ,  C07D207/16 ,  C07F15/0033 ,  C07F15/0086 ,  C09K2211/1007 ,  C09K2211/1022 ,  C09K2211/1092 ,  C09K2211/1458 ,  C09K2211/1466 ,  C09K2211/185 ,  Y10S428/917

Abstract: The present invention is directed to a novel phosphorescent compound formed by synthesizing an orthometallated complex by using easily-synthesized ligands. The invention is further directed to an electroluminescent device having high luminous efficiency by using the phosphorescent compound. Moreover, the invention is also directed to a light-emitting device operating at a low voltage by using the electroluminescent device. According to the present invention, a phosphorescent compound represented by general formula [formula 1] is synthesized. Further, an electroluminescent device containing the phosphorescent compound is formed. In order to generate phosphorescent emission more efficiently, a heavy metal is preferably used as a central metal from the perspective of heavy atom effects. Therefore, one feature of the present invention is that the central metal M in the below general formula [formula 1] is iridium or platinum.

Abstract translation: 本发明涉及通过使用容易合成的配体合成邻位金属络合物形成的新型磷光化合物。 本发明还涉及通过使用磷光化合物具有高发光效率的电致发光器件。 此外，本发明还涉及通过使用电致发光器件在低电压下工作的发光器件。 根据本发明，合成由通式[式1]表示的磷光化合物。 此外，形成含有磷光化合物的电致发光器件。 为了更有效地产生磷光发射，从重原子效应的观点出发，优选使用重金属作为中心金属。 因此，本发明的一个特征是下述通式[式1]中的中心金属M是铱或铂。

公开(公告)号：US20050112400A1

公开(公告)日：2005-05-26

申请号：US10719808

申请日：2003-11-21

Applicant: Satoshi Seo ,  Hideko Inoue ,  Atsushi Tokuda ,  Ryoji Nomura

Inventor： Satoshi Seo ,  Hideko Inoue ,  Atsushi Tokuda ,  Ryoji Nomura

IPC: C07C49/92 ,  C07C251/24 ,  C07D207/16 ,  C07F15/00 ,  C09K11/06 ,  H05B33/14 ,  C07D333/02

CPC classification number: C09K11/06 ,  C07C49/92 ,  C07D207/16 ,  C07F15/0033 ,  C07F15/0086 ,  C09K2211/1007 ,  C09K2211/1022 ,  C09K2211/1092 ,  C09K2211/1458 ,  C09K2211/1466 ,  C09K2211/185 ,  Y10S428/917

Abstract: (Object) The present invention provides a novel phosphorescent compound by synthesizing an orthometallated complex by using easy-synthesized ligands. Further, the invention provides an electroluminescent device having high luminous efficiency by using the phosphorescent compound. Moreover, the invention provides a light-emitting device operating at a low voltage by using the electroluminescent device. (Solution Method) According to the invention, a phosphorescent compound represented by general formula [formula 1] is synthesized. Further, an electroluminescent device containing the phosphorescent compound is formed. In order to generate phosphorescent emission further efficiently, a heavy metal is preferably used as a central metal from the perspective of heavy atom effects. Therefore, one feature of the present invention is that the central metal M in the foregoing general formula [formula 1] is iridium or platinum.

Abstract translation: （对象）本发明通过使用容易合成的配体合成邻位金属配合物来提供新的磷光化合物。 此外，本发明通过使用磷光化合物提供具有高发光效率的电致发光器件。 此外，本发明提供了通过使用电致发光器件在低电压下工作的发光器件。 （溶液法）根据本发明，合成由通式[式1]表示的磷光化合物。 此外，形成含有磷光化合物的电致发光器件。 为了进一步有效地生成磷光发射，从重原子效应的角度来看，优选使用重金属作为中心金属。 因此，本发明的一个特征是上述通式[式1]中的中心金属M是铱或铂。