摘要:
Disclosed is a process for the synthesis of fluorinated olefins, and in particularly preferred embodiments tetrafluorinated olefins having F on an unsaturated, non-terminal carbon, such as 2,3,3,3-tetrafluoropropene. The preferred processes of the present invention in accordance with one embodiment generally comprise: (a) reacting a compound of formula (I) X1X2 (I) with a compound of formula (II) CX1X2X3CX1═CX1X2 (II) to produce a reaction product comprising a compound of formula (III) CF3CHX1CH2X2 (III), and (b) exposing said compound of formula (III) to reaction conditions effective to convert said compound of formula (III) to a compound of formula (IV) CF3CZ=CH2 (IV) wherein X1, X2, and X3 are each independently selected from the group consisting of hydrogen, chlorine, bromine, fluorine and iodine, provided that X1 and X2 in formula (I) are not both hydrogen and Z is Cl, I, Br, or F.
摘要:
Disclosed are processes for the production of fluorinated olefins, preferably adapted to commercialization of CF3CF═CH2 (1234yf). In certain preferred embodiments the processes comprise first exposing a compound of Formula (IA) C(X)2═CClC(X)3 (IA) where each X is independently F, Cl or H, preferably CCl2═CClCH2Cl, to one or more sets of reaction conditions, but preferably a substantially single set of reaction conditions, effective to produce at least one chlorofluoropropane, preferably in accordance with Formula (IB): CF3CClXC(X)3 Formula (IB) where each X′ is independently F, Cl or H, and then exposing the compound of Formula (IB) to one or more sets of reaction conditions, but preferably a substantially single set of reaction conditions, effective to produce a compound of Formula (II) CF3CF═CHZ (II) where Z is H, F, Cl, I or Br.
摘要:
A vending apparatus for containing and releasing generally box-shaped or flat articles is disclosed. The articles are vertically stacked in a pre-packaged cartridge that removably mounts on top of a fixed housing. The main housing collects coins to account for purchases of each product independently, which is released by a rotating cam after the turning of a knob. A securable door allows limited access to the coin collecting box.
摘要:
A device for implantation in a host having a material at an interface between the host and the device, said material having a conformation which results in growth of vascular structures by the host close to the interface.
摘要:
A motorcycle stand including a pivotable rotating support surface that may be positioned beneath the frame of the motorcycle. Positioning the stand near the rear of the frame elevates the rear wheel from the ground, and positioning the stand near the front of the frame elevates the front wheel off the ground.The rolling support surface is preferably coated with a layer of urethane to protect the surface of the frame from scratches or other damage that could result from coming into contact with the motorcycle stand. The support surface is a roller assembly the ends of which are attached to supports that rest on the ground. Preferably, these supports each have two feet, resulting in four support points resting on the ground for a stable foundation.
摘要:
This invention provides tobacco expansion processes and apparatus that can be employed for expanding tobacco at rapid throughput rates employing high pressure tobacco impregnation conditions. The processes and apparatus of the invention are particularly useful in tobacco expansion processes employing cycle times of less than 20-30 seconds; the use of preheated, prepressurized expansion agent such as propane; preheating of tobacco batches; and/or compression of tobacco within a high pressure impregnation zone for greatly improving use of available space in a high pressure impregnation vessel.
摘要:
Method for providing caloric nutrition via liquid emulsions, to a patient with dysfunctional visceral organ comprising parenterally administering to the patient a lipid emulsion containing from about 10% to 50% by weight of long chain triglycerides and the remaining lipid being medium chain triglycerides.
摘要:
A hand held voltage sensor in which a low impedance test lamp mode or a high impedance voltage test mode is selectable via a thumb accessed slide switch. In the high impedance mode, three light emitting elements provide indication of the value of voltage potential between a probe conductor and an associated ground conductor being above, below or pulsing above an adjustable threshold level.
摘要:
This specification discloses testing vehicle primary ignition systems by taking the integral of the primary spark plug firing voltage versus time over a time period when the spark should occur. To determine when an integration output should be evaluated, a phase locked loop circuit is used to predict the occurrence of an ignition firing pulse. To compensate for changes in engine speed and yet disregard extraneous spark plug firings, the phase locked loop circuit contains two loop filters having different response times which are automatically selected to minimize response to erroneous or missing spark plug firings and maximize response to actual engine RPM changes.