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51.发明授权
公开(公告)号：US4190652A
公开(公告)日：1980-02-26
申请号：US885234
申请日：1978-03-10
申请人： Wolfgang Hofer , Fritz Maurer , Hans-Jochem Riebel , Rolf Schroder , Bernhard Homeyer , Ingeborg Hammann , Wilhelm Stendel
发明人： Wolfgang Hofer , Fritz Maurer , Hans-Jochem Riebel , Rolf Schroder , Bernhard Homeyer , Ingeborg Hammann , Wilhelm Stendel
CPC分类号： C07F9/4084 , A01N57/22 , C07F9/425
摘要： O-Phenyl-thionothiolalkanephosphonic acid esters of the formula ##STR1## wherein R is alkyl, halogenoalkyl, alkenyl or alkynyl,R.sup.1 is alkyl, andR.sup.2, R.sup.3 and R.sup.4 each independently is hydrogen, halogen, cyano, alkyl, alkylthio, alkylsulphonyl, alkoxy, nitro, carbalkoxy or phenyl,which possess arthropodicidal and nematicidal properties.
摘要翻译： 其中R是烷基，卤代烷基，烯基或炔基，R 1是烷基，R 2，R 3和R 4各自独立地是氢，卤素，氰基，烷基，烷硫基，烷基磺酰基，烷氧基 ，硝基，烷氧基或苯基，具有节肢杀虫和杀线虫性质。
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52.发明授权O-alkyl-O-[4-alkylpyrimidin(2)yl]-(thiono)-(thiol) phosphoric (phosphonic) acid esters and insecticidal, acaricidal and nematocidal compositions containing them 失效O-烷基-O-（4-烷基吡啶（2）YL） - （噻二唑） - （硫醇）磷酸
公开(公告)号：US4113860A
公开(公告)日：1978-09-12
申请号：US645128
申请日：1975-12-29
申请人： Fritz Maurer , Hans-Jochem Riebel , Bernhard Homeyer , Wolfgang Behrenz , Ingeborg Hammann , Wilhelm Stendel
发明人： Fritz Maurer , Hans-Jochem Riebel , Bernhard Homeyer , Wolfgang Behrenz , Ingeborg Hammann , Wilhelm Stendel
IPC分类号： A01N57/16 , A01N57/08 , A01N57/24 , A01N57/32 , A01P5/00 , A01P7/02 , A01P7/04 , C07D239/34 , C07D239/36 , C07D239/38 , C07D239/52 , C07D239/56 , C07F9/6512 , A01N9/36 , C07F9/65
CPC分类号： C07D239/36 , A01N57/08 , C07D239/34 , C07D239/38 , C07D239/52 , C07D239/56 , C07F9/65125
摘要： O-Alkyl-O-[4-alkylpyrimidin(2)yl]-(thiono)-(thiol) phosphoric (phosphonic) acid esters of the formula ##STR1## in which R is alkyl with 1 to 9 carbon atoms,R.sub.1 is alkyl, alkoxy or alkylmercapto each with 1 to 6 carbon atoms, or phenyl,R.sub.2 is alkyl with 1 to 6 carbon atoms,R.sub.3 is hydrogen or halogen,R.sub.4 is halogen, thiocyanato or alkoxy, alkylmercapto or alkoxycarbonyl with 1 to 4 carbon atoms in each radical, andX is oxygen or sulfur, which possess insecticidal, acaricidal and nematocidal properties.
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53.发明授权O-Alkyl-O-(1-carbalkoxy-2-tert.-pentyryl-vinyl)-(thiono) (thiol) phosphoric (phosphonic) acid esters, ester-amides and method of combatting insects 失效O-烷基-O-（1-烷氧基-2-叔戊酰基 - 乙烯基） - （硫醇）（硫醇）磷酸（膦酸）酯，酯酰胺和防治昆虫的方法
公开(公告)号：US4078057A
公开(公告)日：1978-03-07
申请号：US729931
申请日：1976-10-06
申请人： Fritz Maurer , Hans-Jochem Riebel , Bernhard Homeyer , Wolfgang Behrenz , Ingeborg Hammann , Wilhelm Stendel
发明人： Fritz Maurer , Hans-Jochem Riebel , Bernhard Homeyer , Wolfgang Behrenz , Ingeborg Hammann , Wilhelm Stendel
IPC分类号： A01N57/02 , A01N57/12 , C07F9/113 , C07F9/173 , C07F9/24 , C07F9/38 , C07F9/40 , A01N9/36 , C07F9/165
CPC分类号： C07F9/173 , C07F9/113 , C07F9/2412 , C07F9/4078
摘要： O-Alkyl-O-(1-carbalkoxy-2-tert.-pentyryl-vinyl)-(thiono) (thiol) phosphoric (phosphonic) acid esters and esteramides of the formula ##STR1## in which R and R.sub.2 each independently is alkyl with 1 to 6 carbon atoms,R.sub.1 is phenyl, or alkyl, alkoxy, alkylthio or alkylamino each with 1 to 6 carbon atoms, andX is oxygen or sulfur,Which possess insecticidal and acaricidal properties.
摘要翻译： O-（1-烷氧基-2-叔戊酰基 - 乙烯基） - （硫醇）（硫醇）（膦酸）酸酯和下式的酯酰胺
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54.发明授权O-alkyl-0-[1-(3-nitrophenyl)-2-carbalkoxy-vinyl ]-thiono(thiol)-phosphoric (phosphonic) acid esters 失效O-烷基-O- {8-（3-硝基苯基）-2-羧酸烷氧基 - 乙烯基{9-硫杂（硫醇） - 磷酸（膦酸）酯
公开(公告)号：US4041158A
公开(公告)日：1977-08-09
申请号：US630856
申请日：1975-11-11
CPC分类号： C07F9/173 , A01N57/06 , C07F9/4078
摘要： O-Alkyl-O-[1-(3-nitrophenyl)-2-carbalkoxy-vinyl]-thiono(thiol)-phosphoric (phosphonic) acid esters of the formula ##STR1## in which R is alkyl, alkoxy or alkylthio, each with 1 to 6 carbon atoms, or phenyl, andR.sub.1 and R.sub.2 each independently is alkyl with 1 to 6 carbon atoms,Which possess insecticidal properties.
摘要翻译： 式（I）的化合物的O-烷基-O- [1-（3-硝基苯基）-2-烃氧基 - 乙烯基] - 硫代（硫醇） - 磷酸（膦酸）酯其中R是烷基，烷氧基或 烷硫基，各自具有1至6个碳原子，或苯基，并且R 1和R 2各自独立地为具有1至6个碳原子的烷基，具有无定形的杀虫剂性质。
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55.发明授权O-ethyl-S-n-propyl-O-[pyridaz-(6)-on-(3)-yl]-thionothiolphosphoric acid esters 失效O-乙基-S-N-丙基-O-（吡咯并 - （6）-ON-（3）-Y） - 十二烷基磷酸酯
公开(公告)号：US4013657A
公开(公告)日：1977-03-22
申请号：US498288
申请日：1974-08-16
申请人： Wolfgang Hofer , Fritz Maurer , Hans-Jochem Riebel , Lothar Rohe , Ingeborg Hammann , Wilhelm Stendel
发明人： Wolfgang Hofer , Fritz Maurer , Hans-Jochem Riebel , Lothar Rohe , Ingeborg Hammann , Wilhelm Stendel
IPC分类号： A01N57/16 , A01P7/02 , A01P7/04 , C07F9/6509 , C07F9/40
CPC分类号： A01N57/16 , C07F9/650929
摘要： O-ethyl-S-n-propyl-O-[pyridaz-(6)-on-(3)-yl]-thionothiolphosphoric acid esters of the formula ##SPC1##In whichR.sup.1 is hydrogen, alkyl, substituted alkyl, alkenyl, alkynyl, aryl, substituted aryl, a five- or six-membered heterocyclic radical, or a five- or six-membered heterocyclic radical bonded to the nitrogen via a methyl group, andR.sup.2 and R.sup.3 each independently is hydrogen or alkyl, or together are (CH).sub.4 forming a fused benzene ring with the adjoining carbon atomsWhich possess insecticidal and acaricidal properties.
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56.发明授权O,S-Dialkyl-O-(2-cyanophenyl)-thionothiolphosphoric acid esters and insecticidal and acaricidal compositions and method 失效O，S-二烷基-O-（2-氰基苯基） - 硫代硫代磷酸酯和杀虫和杀螨组合物和方法
公开(公告)号：US3966920A
公开(公告)日：1976-06-29
申请号：US529660
申请日：1974-12-04
摘要： O,S-Dialkyl-O-(2-cyanophenyl)-thionothiolphosphoric acid esters of the formula ##EQU1## in which R and R' each independently is alkyl with 1 to 6 carbon atoms, andR" is hydrogen or bromine,Which possess insecticidal and acaricidal properties.
摘要翻译： O，S-二烷基-O-（2-氰基苯基） - 硫代硫代磷酸酯，其中R和R'各自独立地是具有1至6个碳原子的烷基，R“是 氢或溴，具有无毒的杀虫剂和杀虫剂性质。
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57.发明授权N,N-dimethyl-N'-[O-phenyl-(thiono)-alkane-phosphonyl]-formamidines 失效N，N-二甲基-N' - （邻苯基 - （噻喃基） - 烷基 - 膦酰基） - 甲酰胺
公开(公告)号：US4000268A
公开(公告)日：1976-12-28
申请号：US570938
申请日：1975-04-22
CPC分类号： C07F9/4449 , C07F9/4465
摘要： N,N-Dimethyl-N'-[O-phenyl-(thiono)-alkane-phosphonyl]-formamidines of the formula ##STR1## in which R is alkyl with 1 to 4 carbon atoms, andX is oxygen or sulfur,Which possess insecticidal, acaricidal, nematocidal and fungicidal properties.
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公开(公告)号：US4596880A
公开(公告)日：1986-06-24
申请号：US548123
申请日：1983-11-02
IPC分类号： A01N37/34 , A01N37/38 , A01N43/30 , A01N43/32 , A01N53/00 , A01N53/02 , A01N53/06 , C07C33/22 , C07C41/00 , C07C41/18 , C07C41/22 , C07C41/26 , C07C43/225 , C07C43/23 , C07C43/257 , C07C43/29 , C07C67/00 , C07C69/73 , C07C69/743 , C07C69/747 , C07C253/00 , C07C255/33 , C07C255/37 , C07C255/38 , C07C255/39 , C07C255/50 , C07C255/53 , C07C255/54 , C07C313/00 , C07C319/20 , C07C321/28 , C07C323/19 , C07C323/62 , C07D317/46 , C07D319/16 , C07D319/20 , C07D321/10 , C07D319/14
CPC分类号： C07C255/00 , A01N37/34 , A01N37/38 , A01N43/30 , A01N43/32 , A01N53/00 , C07C323/00 , C07C41/22 , C07C41/26 , C07C69/743 , C07D317/46 , C07D319/20 , C07C2101/02
摘要： Benzyl esters of the formula ##STR1## in which n is 1,2,3,4, or 5,R.sup.2 is hydrogen, C.sub.1-4 -alkyl, cyano or ethynyl,R.sup.3 is the radical of a carboxylic acid customary in pyrethroids or pyrethroid-like compounds, andat least one R.sup.1 is fluoroalkoxy or fluoroalkylmercapto, or two together are fluoromethylene- or fluoroethylene-dioxy, and the others, if present, are hydrogen or various radicals,which possess arthropodicidal properties. Various alcohols, amines, aldehydes, halides, and the like, corresponding to the alcohol moieties of the esters are also synthesized.
摘要翻译： 式中，n为1,2,3,4或5，R2为氢，C1-4烷基，氰基或乙炔基的式为“IMAGE”的苄酯，R3为拟除虫菊酯或拟除虫菊酯中常用的羧酸基团 并且至少一个R 1是氟代烷氧基或氟烷基巯基，或两个是氟亚甲基或氟代亚乙基二氧基，其它的如果存在的话是具有节肢动物特性的氢或各种基团。 也合成对应于酯的醇部分的各种醇，胺，醛，卤化物等。
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公开(公告)号：US4438275A
公开(公告)日：1984-03-20
申请号：US288440
申请日：1981-07-30
IPC分类号： A01N37/34 , A01N37/38 , A01N43/30 , A01N43/32 , A01N53/00 , A01N53/02 , A01N53/06 , C07C33/22 , C07C41/00 , C07C41/18 , C07C41/22 , C07C41/26 , C07C43/225 , C07C43/23 , C07C43/257 , C07C43/29 , C07C67/00 , C07C69/73 , C07C69/743 , C07C69/747 , C07C253/00 , C07C255/33 , C07C255/37 , C07C255/38 , C07C255/39 , C07C255/50 , C07C255/53 , C07C255/54 , C07C313/00 , C07C319/20 , C07C321/28 , C07C323/19 , C07C323/62 , C07D317/46 , C07D319/16 , C07D319/20 , C07D321/10 , C07D317/44
CPC分类号： C07C255/00 , A01N37/34 , A01N37/38 , A01N43/30 , A01N43/32 , A01N53/00 , C07C323/00 , C07C41/22 , C07C41/26 , C07C69/743 , C07D317/46 , C07D319/20 , C07C2101/02
摘要： Benzyl esters of the formula ##STR1## in which n is 1,2,3,4, or 5,R.sup.2 is hydrogen, C.sub.1-4 -alkyl, cyano or ethynyl,R.sup.3 is radical of a carboxylic acid customary in pyrethroids or pyrethroid-like compounds, andat least one R.sup.1 is fluoroalkoxy or fluoroalkylmercapto, or two together are fluoromethylene- or fluoroethylene-dioxy, and the others, if present, are hydrogen or various radicals,which possess arthropodicidal properties. Various alcohols, amines, aldehydes, halides, and the like, corresponding to the alcohol moieties of the esters are also synthesized.
摘要翻译： 式为“IMAGE”的苄基酯，其中n为1,2,3,4或5，R2为氢，C1-4烷基，氰基或乙炔基，R3为拟除虫菊酯或拟除虫菊酯衍生物中常用的羧酸基团， 并且至少一个R 1是氟代烷氧基或氟烷基巯基，或两个是氟亚甲基或氟代亚乙基二氧基，而其它的（如果存在的话）是具有节肢动物特性的氢或各种基团。 也合成对应于酯的醇部分的各种醇，胺，醛，卤化物等。
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公开(公告)号：US4348323A
公开(公告)日：1982-09-07
申请号：US226289
申请日：1981-01-19
申请人： Rainer Fuchs , Erich Klauke , Ingeborg Hammann , Bernhard Homeyer , Wolfgang Behrenz , Wilhelm St-Noel , Reinhard Lantzsch , Albrecht Harhold
发明人： Rainer Fuchs , Erich Klauke , Ingeborg Hammann , Bernhard Homeyer , Wolfgang Behrenz , Wilhelm St-Noel , Reinhard Lantzsch , Albrecht Harhold
IPC分类号： A01N37/00 , A01N37/10 , A01N37/38 , A01N43/24 , A01N43/30 , A01N43/32 , A01N47/02 , A01N53/00 , C07C59/64 , C07C69/612 , C07C255/53 , C07D317/46 , C07D319/20
CPC分类号： C07C255/00 , A01N37/10 , A01N37/38 , A01N43/30 , A01N43/32 , A01N47/02 , A01N53/00 , C07C323/00 , C07C59/64 , C07D317/46 , C07D319/20
摘要： Fluorine-containing phenylacetic acid esters of the formula ##STR1## in which R represents the radical of an alcohol customary in the case of pyrethroids,R.sup.1 represents C.sub.2-4 -alkyl, C.sub.2-4 -alkenyl or cyclopropyl,X represents H, halogen, alkyl, alkoxy, OCHF.sub.2, SCHF.sub.2, SCClF.sub.2 or SCF.sub.3 andX.sup.1 can vary widely or form a fused ring with X, the overall compound necessarily containing a fluorine atom, which compounds possess arthropodicidal properties. Intermediates therefor and an overall synthesis from an alcohol of the formula ROH and a toluene of the formula ##STR2## are also shown.
摘要翻译： 式（I）的含氟苯乙酸酯其中R表示在拟除虫菊酯类中常用的醇的基团，R 1表示C 2-4烷基，C 2-4链烯基或环丙基，X表示H ，卤素，烷基，烷氧基，OCHF 2，SCHF 2，SCClF 2或SCF 3和X 1可以广泛变化或与X形成稠环，所述化合物必须含有氟原子，该化合物具有节肢动物学特性。 还示出了其中间体和来自式ROH的醇和式“IMAGE”的甲苯的总体合成。
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