公开(公告)号：US07009074B2

公开(公告)日：2006-03-07

申请号：US10901643

申请日：2004-07-28

Applicant: Mark Zerella ,  Sudip Mukhopadhyay ,  Alexis T. Bell ,  John Glenn Sunley ,  Sander Gaemers ,  Philip Howard ,  Brian Ellis ,  Andrew Richard Lucy

Inventor： Mark Zerella ,  Sudip Mukhopadhyay ,  Alexis T. Bell ,  John Glenn Sunley ,  Sander Gaemers ,  Philip Howard ,  Brian Ellis ,  Andrew Richard Lucy

IPC: C07C51/14

CPC classification number: C07C51/305 ,  C07C53/08

Abstract: Acetic acid is produced by oxidation of methane with an oxygen-containing gas in the presence of an acid selected from concentrated sulfuric acid and fuming sulfuric acid, a palladium-containing catalyst and a promoter, preferably a copper or iron salt. The addition of a promoter and O2 to a system that includes a palladium-containing catalyst such as PdCl2 increases the rate of acetic acid formation from methane by more than an order of magnitude as compared with prior art and, in addition, inhibits the precipitation of Pd black.

Abstract translation: 在选自浓硫酸和发烟硫酸的酸，含钯催化剂和促进剂，优选铜或铁盐的存在下，用含氧气体氧化甲酸来生产乙酸。 将促进剂和O 2加入到包含含钯催化剂如PdCl 2 N的体系中增加了甲烷形成乙酸的速率超过一个量级 与现有技术相比，并且还抑制了Pd黑的沉淀。

公开(公告)号：US06476261B2

公开(公告)日：2002-11-05

申请号：US09964848

申请日：2001-09-28

Applicant: Brian Ellis ,  Mark Stephen Roberts

Inventor： Brian Ellis ,  Mark Stephen Roberts

IPC: C07B5300

CPC classification number: B01J23/686 ,  B01J23/002 ,  B01J23/6525 ,  B01J23/8877 ,  B01J27/199 ,  B01J2523/00 ,  C07C5/48 ,  C07C51/215 ,  C07C51/25 ,  C07C67/04 ,  C07C67/05 ,  Y02P20/125 ,  Y02P20/52 ,  Y02P20/582 ,  C07C11/04 ,  C07C53/08 ,  C07C69/14 ,  C07C69/01 ,  B01J2523/19 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/68 ,  B01J2523/824 ,  B01J2523/18 ,  B01J2523/17 ,  B01J2523/51 ,  C07C69/15

Abstract: A process for the oxidation of a C2 to C4 alkane to produce the corresponding alkene and carboxylic acid which process comprises contacting in an oxidation reaction zone, said alkane, molecular oxygen-containing gas, and optionally, at least one of the corresponding alkene and water, in the presence of at least two catalysts each active, with different selectivities, for the oxidation of the alkane to the corresponding alkene and carboxylic acid, to produce a product stream comprising said alkene, carboxylic acid and water, and in which process the molar ratio of alkene to carboxylic acid produced in said oxidation reaction zone is adjusted or maintained at a pre-determined value by controlling the relative proportions of the at least two catalysts in said oxidation reaction zone. Such an oxidation process may be used in an integrated process, such as for the manufacture of ethyl acetate or vinyl acetate.

Abstract translation: 用于氧化C 2至C 4烷烃以产生相应的烯烃和羧酸的方法，该方法包括在氧化反应区，所述烷烃，含分子氧的气体和任选的至少一个相应的烯烃和水 在至少两种具有不同选择性的活性物质的催化剂的存在下，将烷烃氧化成相应的烯烃和羧酸，以产生包含所述烯烃，羧酸和水的产物流，并且其中摩尔 通过控制所述氧化反应区中的至少两种催化剂的相对比例，将所述氧化反应区中产生的烯烃与羧酸的比例调节或维持在预定值。 这种氧化方法可以用于一体化方法，例如用于制造乙酸乙酯或乙酸乙烯酯。

公开(公告)号：US5994602A

公开(公告)日：1999-11-30

申请号：US902006

申请日：1997-07-29

Applicant: Ala'a K Abdul-Sada ,  Martin Philip Atkins ,  Brian Ellis ,  Philip Kenneth Gordon Hodgson ,  Mark Louis Michael Morgan ,  Kenneth Richard Seddon

Inventor： Ala'a K Abdul-Sada ,  Martin Philip Atkins ,  Brian Ellis ,  Philip Kenneth Gordon Hodgson ,  Mark Louis Michael Morgan ,  Kenneth Richard Seddon

IPC: B01J31/26 ,  C07C2/54 ,  C07C2/68 ,  C07C15/02 ,  C07C2/66 ,  C07C2/70

CPC classification number: C07C2/68 ,  C07C2527/126 ,  C07C2531/02 ,  C07C2531/12 ,  C07C2531/14 ,  C07C2531/26

Abstract: This invention relates to a process for the alkylation of aromatics by reacting an aromatic hydrocarbon with an olefin in the presence of an ionic liquid comprising (a) a compound of the formula R.sub.n MX.sub.3-n wherein R is a C1-C6 alkyl radical, M is aluminium or gallium, X is a halogen atom and n is 0, 1 or 2 and, (b) a hydrocarbyl substituted imidazolium halide or a hydrocarbyl substituted pyridinium halide wherein at least one of the said hydrocarbyl substituents in the imidazolium halide is an alkyl group having 1-18 carbon atoms. The process allows ready separation of reaction products from the ionic liquid and improves selectivity to alkylated products.

Abstract translation: PCT No.PCT / GB95 / 00254 Sec。 371 1995年9月5日第 102（e）1995年9月5日PCT 1995年2月9日提交PCT公布。 WO95 / 21806 PCT公开号 日期：1995年8月17日本发明涉及一种通过在离子液体存在下使芳族烃与烯烃反应来烷基化芳族化合物的方法，该离子液体包含（a）式RnMX3-n的化合物，其中R是C1-C6 烷基，M是铝或镓，X是卤素原子，n是0,1或2，和（b）烃基取代的咪唑鎓卤化物或烃基取代的吡啶鎓卤化物，其中咪唑鎓中的至少一个烃基取代基 卤化物是具有1-18个碳原子的烷基。 该方法允许反应产物从离子液体中快速分离并提高对烷基化产物的选择性。