公开(公告)号：US08507621B2

公开(公告)日：2013-08-13

申请号：US13663528

申请日：2012-10-30

Applicant: Chevron Phillips Chemical Company LP

Inventor： Kumundini C. Jayaratne ,  Michael D. Jensen ,  Qing Yang

IPC: C08F4/64 ,  C08F4/76 ,  C08F4/52

CPC classification number: B01J31/2295 ,  B01J31/143 ,  B01J2531/0263 ,  B01J2531/48 ,  B01J2531/49 ,  C08F4/65912 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/00 ,  C08F210/16 ,  Y10S526/941 ,  Y10S526/943 ,  C08F4/65904 ,  C08F210/14 ,  C08F2500/05 ,  C08F2500/07 ,  C08F2500/12

Abstract: Catalyst compositions comprising a first metallocene compound, a second metallocene compound, an activator-support, and an organoaluminum compound are provided. An improved method for preparing cyclopentadienyl complexes used to produce polyolefins is also provided.

Abstract translation: 提供了包含第一茂金属化合物，第二茂金属化合物，活化剂 - 载体和有机铝化合物的催化剂组合物。 还提供了用于制备用于制备聚烯烃的环戊二烯基络合物的改进方法。

公开(公告)号：US08450436B2

公开(公告)日：2013-05-28

申请号：US13681443

申请日：2012-11-20

Applicant: Chevron Phillips Chemical Company LP

Inventor： Albert P. Masino ,  Rex E. Murray ,  Qing Yang ,  Steve J. Secora ,  Kumudini C. Jayaratne ,  William B. Beaulieu ,  Errun Ding ,  Gary L. Glass ,  Alan L. Solenberger ,  Ted H. Cymbaluk

IPC: C08F4/642 ,  C08F4/643 ,  C08F4/6592 ,  B01J31/22

CPC classification number: C08F4/642 ,  C08F4/12 ,  C08F4/52 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F4/76 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F2500/01 ,  C08F2500/12 ,  C08F2500/08 ,  C08F210/14

Abstract: The present invention provides dual catalyst systems and polymerization processes employing these dual catalyst systems. The disclosed polymerization processes can produce olefin polymers at higher production rates, and these olefin polymers may have a higher molecular weight and/or a lower melt index.

公开(公告)号：US20130079477A1

公开(公告)日：2013-03-28

申请号：US13681443

申请日：2012-11-20

Applicant: Chevron Phillips Chemical Company LP

Inventor： Albert P. Masino ,  Rex E. Murray ,  Qing Yang ,  Steve J. Secora ,  Kumudini C. Jayaratne ,  William B. Beaulieu ,  Errun Ding ,  Gary L. Glass ,  Alan L. Solenberger ,  Ted H. Cymbaluk

IPC: C08F4/76

CPC classification number: C08F4/642 ,  C08F4/12 ,  C08F4/52 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F4/76 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F2500/01 ,  C08F2500/12 ,  C08F2500/08 ,  C08F210/14

Abstract: The present invention provides dual catalyst systems and polymerization processes employing these dual catalyst systems. The disclosed polymerization processes can produce olefin polymers at higher production rates, and these olefin polymers may have a higher molecular weight and/or a lower melt index.

Abstract translation: 本发明提供了使用这些双重催化剂体系的双重催化剂体系和聚合方法。 公开的聚合方法可以以更高的生产速率生产烯烃聚合物，并且这些烯烃聚合物可以具有较高的分子量和/或较低的熔体指数。

公开(公告)号：US20130053523A1

公开(公告)日：2013-02-28

申请号：US13663528

申请日：2012-10-30

Applicant: Chevron Phillips Chemical Company LP

Inventor： Kumudini C. Jayaratne ,  Michael D. Jensen ,  Qing Yang

IPC: C08F4/76 ,  C08F4/6592 ,  C08F4/52 ,  C08F2/04 ,  C08F2/34

CPC classification number: B01J31/2295 ,  B01J31/143 ,  B01J2531/0263 ,  B01J2531/48 ,  B01J2531/49 ,  C08F4/65912 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/00 ,  C08F210/16 ,  Y10S526/941 ,  Y10S526/943 ,  C08F4/65904 ,  C08F210/14 ,  C08F2500/05 ,  C08F2500/07 ,  C08F2500/12

Abstract: Catalyst compositions comprising a first metallocene compound, a second metallocene compound, an activator-support, and an organoaluminum compound are provided. An improved method for preparing cyclopentadienyl complexes used to produce polyolefins is also provided.

Abstract translation: 提供了包含第一茂金属化合物，第二茂金属化合物，活化剂 - 载体和有机铝化合物的催化剂组合物。 还提供了用于制备用于制备聚烯烃的环戊二烯基络合物的改进方法。

公开(公告)号：US20130029837A1

公开(公告)日：2013-01-31

申请号：US13647411

申请日：2012-10-09

Applicant: Chevron Phillips Chemical Company LP

Inventor： Qing Yang ,  Max P. McDaniel ,  Tony R. Crain

IPC: B01J27/053 ,  B01J27/135

CPC classification number: C08F110/02 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65927 ,  C08F10/00 ,  C08F4/65916 ,  C08F2500/03 ,  C08F2500/04

Abstract: The present invention provides metal-containing sulfated activator-supports, and polymerization catalyst compositions employing these activator-supports. Methods for making these metal-containing sulfated activator-supports and for using such components in catalyst compositions for the polymerization of olefins are also provided.

Abstract translation: 本发明提供了含金属的硫酸化活化剂 - 载体和使用这些活化剂 - 载体的聚合催化剂组合物。 还提供了制备这些含金属的硫酸化活化剂 - 载体和用于烯烃聚合的催化剂组合物中使用这些组分的方法。

公开(公告)号：US20240279371A1

公开(公告)日：2024-08-22

申请号：US18638423

申请日：2024-04-17

Applicant: Chevron Phillips Chemical Company LP

Inventor： Graham R. Lief ,  Qing Yang ,  Eric J. Haschke

IPC: C08F210/16 ,  C07F17/00 ,  C08F4/659 ,  C08F4/6592

CPC classification number: C08F210/16 ,  C07F17/00 ,  C08F4/65904 ,  C08F4/65925 ,  C08F4/65927

Abstract: Disclosed are metallocene compounds, catalyst compositions comprising at least one metallocene compound, processes for polymerizing olefins, methods for making catalyst compositions, olefin polymers and articles made from olefin polymers. In an aspect, a metallocene compound and catalyst composition are disclosed in which the metallocene contains at least one indenyl ligand, the indenyl ligand containing at least one halogenated substituent, such as a fluorinated substituent. These metallocene compounds and catalyst compositions can produce polyethylene having unexpectedly low levels of short chain branching.

公开(公告)号：US20240247085A1

公开(公告)日：2024-07-25

申请号：US18585446

申请日：2024-02-23

Applicant: Chevron Phillips Chemical Company LP

Inventor： Qing Yang ,  Max P. McDaniel ,  Tony R. Crain

IPC: C08F4/659 ,  C08F4/52 ,  C08F4/64 ,  C08F4/6592 ,  C08F110/02 ,  C08F210/16

CPC classification number: C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F110/02 ,  C08F210/16 ,  C08F4/52 ,  C08F4/64 ,  C08F2410/07 ,  C08F2500/09

Abstract: Methods for preparing a metallocene-based catalyst composition that can impact the long chain branching of ethylene homopolymers and copolymers produced using the catalyst composition are described. The catalyst composition can be prepared by contacting a metallocene compound, a hydrocarbon solvent, and a first organoaluminum compound for a first period of time to form a metallocene solution, and then contacting the metallocene solution with an activator-support and a second organoaluminum compound for a second period of time to form the catalyst composition.

公开(公告)号：US12037421B2

公开(公告)日：2024-07-16

申请号：US18357209

申请日：2023-07-24

Applicant: Chevron Phillips Chemical Company LP

Inventor： Qing Yang ,  Ryan N. Rose ,  Max P. McDaniel ,  Zhihui Gu

IPC: C08F4/6592 ,  C08F4/02 ,  C08F4/52 ,  C08F4/642 ,  C08F4/659 ,  C08F110/02 ,  C08F210/16

CPC classification number: C08F110/02 ,  C08F4/025 ,  C08F4/52 ,  C08F4/642 ,  C08F4/65912 ,  C08F4/65916 ,  C08F210/16 ,  C08F2410/07 ,  C08F2420/00

Abstract: Methods for preparing metallocene-based catalyst compositions include the steps of contacting an alcohol compound and an organoaluminum compound for a first period of time to form a precontacted mixture, and contacting the precontacted mixture with an activator-support and a metallocene compound for a second period of time to form the catalyst composition. Such catalyst compositions can contain an activator-support, a metallocene compound, an organoaluminum compound, and a dialkyl aluminum alkoxide, and these catalyst compositions have increased catalytic activity for the polymerization of olefins.

公开(公告)号：US20240043577A1

公开(公告)日：2024-02-08

申请号：US18489106

申请日：2023-10-18

Applicant: Chevron Phillips Chemical Company LP

Inventor： Qing Yang ,  Max P. McDaniel ,  Tony R. Crain

IPC: C08F4/659 ,  C08F4/6592 ,  C08F110/02 ,  C08F210/16

CPC classification number: C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F110/02 ,  C08F210/16 ,  C08F2410/07 ,  C08F4/52

Abstract: Methods for preparing a metallocene-based catalyst composition that can impact the long chain branching of ethylene homopolymers and copolymers produced using the catalyst composition are described. The catalyst composition can be prepared by contacting a metallocene compound, a hydrocarbon solvent, and a first organoaluminum compound for a first period of time to form a metallocene solution, and then contacting the metallocene solution with an activator-support and a second organoaluminum compound for a second period of time to form the catalyst composition.

公开(公告)号：US11851505B2

公开(公告)日：2023-12-26

申请号：US17142312

申请日：2021-01-06

Applicant: Chevron Phillips Chemical Company LP

Inventor： Errun Ding ,  Qing Yang ,  Randall S. Muninger ,  Youlu Yu ,  Yongwoo Inn

IPC: C08F10/02 ,  C08F2/34 ,  C08F4/6592

CPC classification number: C08F10/02 ,  C08F2/34 ,  C08F4/65922 ,  C08F2500/01 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/17

Abstract: Disclosed herein are ethylene-based polymers generally characterized by a melt index of less than 1 g/10 min, a density from 0.93 to 0.965 g/cm3, a CY-a parameter at 190° C. of less than 0.2, an average number of short chain branches per 1000 total carbon atoms of the polymer in a molecular weight range of 400,000 to 600,000 g/mol that is greater than that in a molecular weight range of 40,000 to 60,000 g/mol, and an average number of long chain branches per 1000 total carbon atoms of the polymer in a molecular weight range of 400,000 to 600,000 g/mol that is greater than that in a molecular weight range of 4,000,000 to 6,000,000 g/mol. The ethylene polymers can be used to fabricate pipes, blown films, and blow molded products, and the ethylene polymers can be produced with a dual catalyst system containing a single atom bridged or two carbon atom bridged metallocene compound with two indenyl groups or an indenyl group and a cyclopentadienyl group, and a single atom bridged metallocene compound with a fluorenyl group and a cyclopentadienyl group with an alkenyl substituent.