公开(公告)号：US11761120B2

公开(公告)日：2023-09-19

申请号：US17067922

申请日：2020-10-12

Applicant: Chevron Phillips Chemical Company LP

Inventor： Graham R. Lief ,  Eric J. Haschke

IPC: C08F4/6592 ,  C08F110/06 ,  D01F6/06 ,  B29C48/05 ,  B29K23/00 ,  B29L31/00 ,  C08F4/659

CPC classification number: D01F6/06 ,  B29C48/05 ,  C08F110/06 ,  B29K2023/10 ,  B29L2031/731 ,  C08F4/65912 ,  C08F4/65916 ,  C08F110/06 ,  C08F4/65927 ,  C08F110/06 ,  C08F2500/12 ,  C08F110/06 ,  C08F2500/12 ,  C08F2500/03 ,  C08F110/06 ,  C08F2500/12 ,  C08F2500/03 ,  C08F2500/15 ,  C08F110/06 ,  C08F2500/12 ,  C08F2500/15

Abstract: Disclosed herein are high melt flow polypropylene homopolymers generally characterized by a melt flow rate ranging from 200 g/10 min to 3000 g/10 min, a ratio of Mw/Mn ranging from 2 to 5, and a peak melting point ranging from 138° C. to 151° C. These polypropylene homopolymers can be produced by catalyst systems containing a racemic ansa-bis(indenyl)zirconocene compound, an activator-support, and an organoaluminum co-catalyst.

公开(公告)号：US20190256441A1

公开(公告)日：2019-08-22

申请号：US16401155

申请日：2019-05-02

Applicant: Chevron Phillips Chemical Company LP

Inventor： Graham R. Lief ,  Eric J. Haschke ,  Pasquale Iacono

IPC: C07C2/32 ,  C07C5/05 ,  B01J8/18 ,  B01J31/14 ,  B01J31/22 ,  C07C2/34 ,  B01J21/12

Abstract: The present invention discloses processes for oligomerizing an olefin feedstock containing C4 to C20 alpha olefins using a catalyst system containing a metallocene compound, an organoaluminum compound, and a suspension of a chemically-treated solid oxide. The liquid medium for the suspension of the chemically-treated solid oxide can be an alpha-olefin oligomer product formed by the oligomerization process.

公开(公告)号：US20240279371A1

公开(公告)日：2024-08-22

申请号：US18638423

申请日：2024-04-17

Applicant: Chevron Phillips Chemical Company LP

Inventor： Graham R. Lief ,  Qing Yang ,  Eric J. Haschke

IPC: C08F210/16 ,  C07F17/00 ,  C08F4/659 ,  C08F4/6592

CPC classification number: C08F210/16 ,  C07F17/00 ,  C08F4/65904 ,  C08F4/65925 ,  C08F4/65927

Abstract: Disclosed are metallocene compounds, catalyst compositions comprising at least one metallocene compound, processes for polymerizing olefins, methods for making catalyst compositions, olefin polymers and articles made from olefin polymers. In an aspect, a metallocene compound and catalyst composition are disclosed in which the metallocene contains at least one indenyl ligand, the indenyl ligand containing at least one halogenated substituent, such as a fluorinated substituent. These metallocene compounds and catalyst compositions can produce polyethylene having unexpectedly low levels of short chain branching.

公开(公告)号：US20190077727A1

公开(公告)日：2019-03-14

申请号：US15701577

申请日：2017-09-12

Applicant: Chevron Phillips Chemical Company LP

Inventor： Graham R. Lief ,  Eric J. Haschke ,  Pasquale Iacono

IPC: C07C2/32 ,  C07C5/05 ,  B01J31/14 ,  B01J31/22 ,  B01J8/18 ,  B01J21/12

CPC classification number: C07C2/32 ,  B01J8/02 ,  B01J8/06 ,  B01J8/10 ,  B01J8/1836 ,  B01J8/1854 ,  B01J21/12 ,  B01J27/053 ,  B01J27/12 ,  B01J31/143 ,  B01J31/2295 ,  B01J2231/20 ,  B01J2531/48 ,  B01J2531/49 ,  C07C2/34 ,  C07C5/05 ,  C07C2527/12 ,  C07C2531/14 ,  C07C2531/16 ,  C07C2531/22 ,  C07C11/02

Abstract: The present invention discloses processes for oligomerizing an olefin feedstock containing C4 to C20 alpha olefins using a catalyst system containing a metallocene compound, an organoaluminum compound, and a suspension of a chemically-treated solid oxide. The liquid medium for the suspension of the chemically-treated solid oxide can be an alpha-olefin oligomer product formed by the oligomerization process.

公开(公告)号：US20180105478A1

公开(公告)日：2018-04-19

申请号：US15297179

申请日：2016-10-19

Applicant: Chevron Phillips Chemical Company LP

Inventor： Graham R. Lief ,  Uriah J. Kilgore ,  Eric J. Haschke

IPC: C07C2/32 ,  B01J31/18 ,  B01J31/14 ,  C08F10/00

CPC classification number: C07C2/32 ,  B01J31/143 ,  B01J31/1616 ,  B01J31/1805 ,  B01J31/183 ,  B01J2231/20 ,  B01J2531/824 ,  B01J2531/847 ,  C07C2527/053 ,  C07C2527/125 ,  C07C2531/14 ,  C07C2531/22 ,  C08F10/00 ,  Y02P20/52 ,  C07C11/02 ,  C08F110/06 ,  C08F2500/02 ,  C08F4/7006

Abstract: Disclosed herein are catalyst systems containing an alpha-diimine nickel halide complex, a chemically-treated solid oxide, and an optional co-catalyst. These catalyst systems can be used to reduce the light oligomer content of propylene oligomer streams, for instance, by oligomerizing olefin feedstocks containing C6 to C27 propylene oligomers to produce oligomer compositions having higher molecular weights.

公开(公告)号：US10927053B2

公开(公告)日：2021-02-23

申请号：US16401155

申请日：2019-05-02

Applicant: Chevron Phillips Chemical Company LP

Inventor： Graham R. Lief ,  Eric J. Haschke ,  Pasquale Iacono

IPC: C07C2/32 ,  C07C5/05 ,  B01J31/14 ,  B01J31/22 ,  B01J8/18 ,  B01J21/12 ,  C07C2/34 ,  B01J27/053 ,  B01J8/02 ,  B01J8/10 ,  B01J27/12 ,  B01J8/06

Abstract: The present invention discloses processes for oligomerizing an olefin feedstock containing C4 to C20 alpha olefins using a catalyst system containing a metallocene compound, an organoaluminum compound, and a suspension of a chemically-treated solid oxide. The liquid medium for the suspension of the chemically-treated solid oxide can be an alpha-olefin oligomer product formed by the oligomerization process.

公开(公告)号：US20180194879A1

公开(公告)日：2018-07-12

申请号：US15915170

申请日：2018-03-08

Applicant: Chevron Phillips Chemical Company LP

Inventor： Graham R. Lief ,  Uriah J. Kilgore ,  Eric J. Haschke

IPC: C08F10/06 ,  B01J31/16 ,  C07C5/03 ,  C07C2/32

CPC classification number: C08F10/06 ,  B01J21/12 ,  B01J27/12 ,  B01J31/143 ,  B01J31/1608 ,  B01J31/1616 ,  B01J31/1625 ,  B01J31/1633 ,  B01J31/2295 ,  B01J2231/20 ,  B01J2531/0263 ,  B01J2531/48 ,  B01J2531/49 ,  C07C2/32 ,  C07C5/03 ,  C07C2531/22 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F110/06 ,  C08F2420/02 ,  C08F2500/04 ,  C08F2500/17 ,  C08F4/65904 ,  C08F2500/02 ,  C08F2500/03

Abstract: Disclosed herein are dual catalyst compositions containing an unbridged metallocene compound, a bridged metallocene compound, a chemically-treated solid oxide, and an optional co-catalyst. These catalyst compositions can be used for the oligomerization of propylene to produce an oligomer product. For example, a heavy propylene oligomer can be recovered from the oligomer product, and the heavy propylene oligomer can be characterized by a high flash point and viscosity index, and a low pour point.

公开(公告)号：US09951158B2

公开(公告)日：2018-04-24

申请号：US15235145

申请日：2016-08-12

Applicant: Chevron Phillips Chemical Company LP

Inventor： Graham R. Lief ,  Uriah J. Kilgore ,  Eric J. Haschke

IPC: C08F10/06 ,  C07C2/32 ,  C07C5/03 ,  B01J31/16

CPC classification number: C08F10/06 ,  B01J31/00 ,  B01J31/1625 ,  B01J31/1633 ,  B01J2231/20 ,  B01J2531/0263 ,  B01J2531/48 ,  C07C2/32 ,  C07C5/03 ,  C07C2531/22 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F110/06 ,  C08F2420/02 ,  C08F2500/04 ,  C08F2500/17 ,  C08F4/65904 ,  C08F2500/02 ,  C08F2500/03

Abstract: Disclosed herein are dual catalyst compositions containing an unbridged metallocene compound, a bridged metallocene compound, a chemically-treated solid oxide, and an optional co-catalyst. These catalyst compositions can be used for the oligomerization of propylene to produce an oligomer product. For example, a heavy propylene oligomer can be recovered from the oligomer product, and the heavy propylene oligomer can be characterized by a high flash point and viscosity index, and a low pour point.

公开(公告)号：US20180044446A1

公开(公告)日：2018-02-15

申请号：US15235145

申请日：2016-08-12

Applicant: Chevron Phillips Chemical Company LP

Inventor： Graham R. Lief ,  Uriah J. Kilgore ,  Eric J. Haschke

IPC: C08F10/06 ,  C07C5/03 ,  B01J31/16 ,  C07C2/32

CPC classification number: C08F10/06 ,  B01J31/00 ,  B01J31/1625 ,  B01J31/1633 ,  B01J2231/20 ,  B01J2531/0263 ,  B01J2531/48 ,  C07C2/32 ,  C07C5/03 ,  C07C2531/22 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F110/06 ,  C08F2420/02 ,  C08F2500/04 ,  C08F2500/17 ,  C08F4/65904 ,  C08F2500/02 ,  C08F2500/03

Abstract: Disclosed herein are dual catalyst compositions containing an unbridged metallocene compound, a bridged metallocene compound, a chemically-treated solid oxide, and an optional co-catalyst. These catalyst compositions can be used for the oligomerization of propylene to produce an oligomer product. For example, a heavy propylene oligomer can be recovered from the oligomer product, and the heavy propylene oligomer can be characterized by a high flash point and viscosity index, and a low pour point.

公开(公告)号：US12297304B2

公开(公告)日：2025-05-13

申请号：US18638423

申请日：2024-04-17

Applicant: Chevron Phillips Chemical Company LP

Inventor： Graham R. Lief ,  Qing Yang ,  Eric J. Haschke

IPC: C07F17/00 ,  C08F4/659 ,  C08F4/6592 ,  C08F210/16

Abstract: Disclosed are metallocene compounds, catalyst compositions comprising at least one metallocene compound, processes for polymerizing olefins, methods for making catalyst compositions, olefin polymers and articles made from olefin polymers. In an aspect, a metallocene compound and catalyst composition are disclosed in which the metallocene contains at least one indenyl ligand, the indenyl ligand containing at least one halogenated substituent, such as a fluorinated substituent. These metallocene compounds and catalyst compositions can produce polyethylene having unexpectedly low levels of short chain branching.