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    Method for functionalizing natural fatty substances
    53.
    发明授权
    Method for functionalizing natural fatty substances 有权
    功能化天然脂肪物质的方法

    公开(公告)号：US09108908B2

    公开(公告)日：2015-08-18

    申请号：US13807146

    申请日：2011-06-30

    申请人： Sylvain Caillol ,  Bernard Boutevin ,  Myriam Desroches

    发明人： Sylvain Caillol ,  Bernard Boutevin ,  Myriam Desroches

    IPC分类号： C08G65/14 ,  C07C319/18 ,  C11C3/00

    CPC分类号： C07C319/18 ,  C11C3/00

    摘要： The invention relates to a method for functionalizing natural fatty substances: According to said method, plant oils including at least two unsaturations and the derivatives thereof, fatty acids including at least one unsaturated compound and the derivatives thereof, and mixtures of same, are reacted with a thiol derivative of formula (I), at a temperature of between 0° C. and the temperature of total degradation of the natural fatty substance and in the presence of a thermal initiator compound or a redox initiator, or by UV radiation, or by UV radiation and in the presence of a photoinitiator. The invention also relates to the resulting functionalized fatty substances and to the use thereof for the preparation of polymers. The invention further relates to a method for preparing polymers from at least one functionalized fatty substance obtained by said functionalization method.

    摘要翻译： 本发明涉及一种功能化天然脂肪物质的方法：根据所述方法，包括至少两种不饱和的植物油及其衍生物，包含至少一种不饱和化合物的脂肪酸及其衍生物及其衍生物及其混合物与 式（I）的硫醇衍生物在0℃和天然脂肪物质的总降解温度之间，在热引发剂化合物或氧化还原引发剂的存在下，或通过UV辐射，或通过 UV辐射和光引发剂存在下。 本发明还涉及得到的官能化脂肪物质及其用于制备聚合物的用途。 本发明还涉及由通过所述官能化方法获得的至少一种官能化脂肪物质制备聚合物的方法。

    SHEET OF VEGETABLE WOOL FIBER IMPREGNATED WITH AN EXPOXIDIZED VEGETABLE OIL
    54.
    发明申请
    SHEET OF VEGETABLE WOOL FIBER IMPREGNATED WITH AN EXPOXIDIZED VEGETABLE OIL 审中-公开
    植物羊毛纤维被放置在外用的植物油上

    公开(公告)号：US20140083636A1

    公开(公告)日：2014-03-27

    申请号：US14110112

    申请日：2012-04-05

    申请人： Jean-Pierre Habas ,  Mylène Stemmelen ,  Vincent Lapinte ,  Sylvain Caillol ,  Bernard Boutevin ,  Maxime Ricbourg

    发明人： Jean-Pierre Habas ,  Mylène Stemmelen ,  Vincent Lapinte ,  Sylvain Caillol ,  Bernard Boutevin ,  Maxime Ricbourg

    IPC分类号： D21H17/53

    CPC分类号： D21H17/53 ,  D04H1/64

    摘要： A sheet of vegetable wool fiber is impregnated with a reactive mix made up of a partially or completely epoxidized vegetable oil and a hardener. The sheet can also be included in a panel. The method for manufacturing the sheet includes mixing an epoxidized vegetable oil and a hardener at a temperature higher than each one of the melting temperatures thereof and lower than each one of the breakdown temperatures thereof; and depositing the obtained mix on an assembly of vegetable wool fibers at a temperature higher than each one of the melting temperatures thereof and lower than each one of the breakdown temperatures thereof.

    摘要翻译： 用一部分或完全环氧化的植物油和硬化剂组成的反应性混合物浸渍一片植物羊毛纤维。 纸张也可以包含在面板中。 制造片材的方法包括在高于其每个熔融温度且低于其每一个击穿温度的温度下混合环氧化植物油和硬化剂; 并将得到的混合物在温度高于其每个熔融温度并低于其每一个击穿温度的植物纤维纤维组合物上沉积。

    Iodinated organic substances of low molecular mass and process for preparing them
    55.
    发明授权
    Iodinated organic substances of low molecular mass and process for preparing them 失效
    低分子量的碘化有机物质及其制备方法

    公开(公告)号：US08263811B2

    公开(公告)日：2012-09-11

    申请号：US12774844

    申请日：2010-05-06

    申请人： Patrick Lacroix-Desmazes ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

    发明人： Patrick Lacroix-Desmazes ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

    IPC分类号： C07C41/06 ,  C07C43/12 ,  C07C69/96 ,  C07C305/00 ,  C07C309/65

    CPC分类号： C07C41/06 ,  C07C68/06 ,  C08F2/38 ,  C08F4/00 ,  C08F218/08 ,  C08F220/18 ,  C07C69/96 ,  C07C43/174

    摘要： Process for preparing one or more iodinated organic substances having a molecular mass of less than 2000 (substances (S)) using (A) at least one free-radical-generating substance chosen from peroxides, diazo compounds, dialkyldiphenylalkanes, substances derived from tetraphenylethane, boranes and iniferter substances comprising at least one thiuram disulphide group, (B) an ethylenically unsaturated substance capable of adding a free radical to its ethylenic double bond, (C) molecular iodine, which comprises the steps according to which at least a fraction of (A), at least a fraction of (B) and at least a fraction of (C) are introduced into a reactor, and then the contents of the reactor are caused to react, while introducing therein the possible remainder of (A), the possible remainder of (B) and the possible remainder of (C), until a moment is reached when the content of the reactor is a mixture comprising one or more substances (S). Iodinated organic substances for whose preparation the abovementioned process is particularly well suited.

    摘要翻译： 使用（A）至少一种选自过氧化物，重氮化合物，二烷基二苯基烷烃的衍生自四苯基乙烷的物质的至少一种自由基产生物质制备一种或多种分子量小于2000的碘化有机物质（物质（S））的方法， 包含至少一种秋兰姆二硫基的硼烷和引发剂物质，（B）能够向其烯属双键加入自由基的烯属不饱和物质，（C）分子碘，其包括以下步骤：至少一部分（ A）中，将至少一部分（B）和至少一部分（C）引入反应器中，然后使反应器的内容物反应，同时在其中引入可能的剩余部分（A）， 当反应器的含量是包含一种或多种物质（S）的混合物时，直到达到一定时间为止（B）的剩余部分和（C）的可能剩余部分）。 上述方法制备的碘化有机物质特别适合。

    Iodinated organic substances of low molecular mass and process for preparing them
    57.
    发明授权
    Iodinated organic substances of low molecular mass and process for preparing them 失效
    低分子量的碘化有机物质及其制备方法

    公开(公告)号：US07741524B2

    公开(公告)日：2010-06-22

    申请号：US10553993

    申请日：2004-04-22

    申请人： Patrick Lacroix-Desmazes ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

    发明人： Patrick Lacroix-Desmazes ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

    IPC分类号： C07C41/06 ,  C07C43/12 ,  C07C69/96 ,  C07C305/00 ,  C07C309/65

    CPC分类号： C07C41/06 ,  C07C68/06 ,  C08F2/38 ,  C08F4/00 ,  C08F218/08 ,  C08F220/18 ,  C07C69/96 ,  C07C43/174

    摘要： Process for preparing one or more iodinated organic substances having a molecular mass of less than 2000 (substances (S)) using (A) at least one free-radical-generating substance chosen from peroxides, diazo compounds, dialkyldiphenylalkanes, substances derived from tetraphenylethane, boranes and iniferter substances comprising at least one thiuram disulphide group, (B) an ethylenically unsaturated substance capable of adding a free radical to its ethylenic double bond, (C) molecular iodine, which comprises the steps according to which at least a fraction of (A), at least a fraction of (B) and at least a fraction of (C) are introduced into a reactor, and then the contents of the reactor are caused to react, while introducing therein the possible remainder of (A), the possible remainder of (B) and the possible remainder of (C), until a moment is reached when the content of the reactor is a mixture comprising one or more substances (S). Iodinated organic substances for whose preparation the abovementioned process is particularly well suited.

    摘要翻译： 使用（A）至少一种选自过氧化物，重氮化合物，二烷基二苯基烷烃的衍生自四苯基乙烷的物质的至少一种自由基产生物质制备一种或多种分子量小于2000的碘化有机物质（物质（S））的方法， 包含至少一种秋兰姆二硫基的硼烷和引发剂物质，（B）能够向其烯属双键加入自由基的烯属不饱和物质，（C）分子碘，其包括以下步骤：至少一部分（ A）中，将至少一部分（B）和至少一部分（C）引入反应器中，然后使反应器的内容物反应，同时在其中引入可能的剩余部分（A）， 当反应器的含量是包含一种或多种物质（S）的混合物时，直到达到一定时间为止（B）的剩余部分和（C）的可能剩余部分）。 上述方法制备的碘化有机物质特别适合。

    PROCESS FOR PREPARING A COPOLYMER WITH CONTROLLED ARCHITECTURE, OF TELOMER OR BLOCK COPOLYMER TYPE, OBTAINED FROM VINYL PHOSPHONATE MONOMERS, BY IODINE TRANSFER POLYMERIZATION
    58.
    发明申请
    PROCESS FOR PREPARING A COPOLYMER WITH CONTROLLED ARCHITECTURE, OF TELOMER OR BLOCK COPOLYMER TYPE, OBTAINED FROM VINYL PHOSPHONATE MONOMERS, BY IODINE TRANSFER POLYMERIZATION 审中-公开
    通过碘转移聚合从乙烯基单体获得的具有受控结构的共聚物，由TELOMER或嵌段共聚物类型制备的方法

    公开(公告)号：US20090306297A1

    公开(公告)日：2009-12-10

    申请号：US12162341

    申请日：2007-01-24

    申请人： Mathias Destarac ,  Bernard Boutevin ,  David Ghislain ,  Graham Otter ,  Gary Woodward

    发明人： Mathias Destarac ,  Bernard Boutevin ,  David Ghislain ,  Graham Otter ,  Gary Woodward

    IPC分类号： C08L43/02 ,  C08L39/06

    CPC分类号： C08F2/38 ,  C08F230/02 ,  C08F293/005 ,  C08F2438/00

    摘要： The present invention relates to a process for synthesizing a copolymer having controlled architecture, comprising at least one block A obtained by the ITP polymerization of a mixture of ethylenically unsaturated monomers (A0), containing no monomers having vinyl phosphonate functions, and at least one block B obtained by polymerizing a mixture of ethylenically un-saturated monomers (B0) containing at least one monomer B1 which carries at least one vinyl phosphonate function. The present invention also relates to a process for synthesizing a copolymer having controlled architecture, of the telomer type, comprising at least one chain B obtained by polymerizing a mixture of ethylenically unsaturated monomers (B0) containing at least one monomer B1 which carries at least one vinyl phosphonate function, by ITP polymerization; to the telomer obtainable; and to the uses thereof.

    摘要翻译： 本发明涉及一种用于合成具有受控结构的共聚物的方法，其包含至少一种通过ITP聚合得到的嵌段A，所述嵌段A是不含烯键式不饱和单体（A0）的混合物，不含单体具有乙烯基膦酸酯官能团，和至少一个嵌段 B通过聚合含有至少一个携带至少一种乙烯基膦酸酯官能团的单体B1的烯属不饱和单体（B0）的混合物而获得。 本发明还涉及一种合成具有受控结构的调聚物类型的共聚物的方法，该方法包括至少一种通过聚合包含至少一个单体B1的烯属不饱和单体（B0）的混合物获得的链B，所述单体B1携带至少一种 乙烯基膦酸酯功能，通过ITP聚合; 可向调解人提供; 以及其用途。

    Radical polymerization processes for preparing halogenated polymers, and halogenated polymers
    59.
    发明授权
    Radical polymerization processes for preparing halogenated polymers, and halogenated polymers 有权
    用于制备卤化聚合物和卤代聚合物的自由基聚合方法

    公开(公告)号：US07285597B2

    公开(公告)日：2007-10-23

    申请号：US11687461

    申请日：2007-03-16

    申请人： Patrick Lacroix-Desmazes ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

    发明人： Patrick Lacroix-Desmazes ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

    IPC分类号： C08F293/00 ,  C08F4/04 ,  C08F4/28

    CPC分类号： C08F293/005 ,  C08F8/22 ,  C08F14/00 ,  C08F214/18 ,  C08F214/186 ,  C08F293/00 ,  C08L53/00 ,  C08L2666/02 ,  C08L2666/24

    摘要： Radical polymerization process for the preparation of halogenated polymers employing one or more ethylenically unsaturated monomers, at least one of which is chosen from halogenated monomers, molecular iodine and one or more radical-generating agents chosen from diazo compounds, peroxides and dialkyl diphenylalkanes Radical polymerization process for the preparation, starting from the halogenated polymers prepared by the process as described above, of block copolymers, at least one block of which is a halogenated polymer block. Halogenated polymers which have a number-average molecular mass Mn of greater than 1.0×104 and an Mz/Mw ratio of less than 1.65. Block copolymers, at least one block of which is a block of halogenated polymer identical to the halogenated polymers described above. Block copolymers comprising at least one halogenated polymer block which have a number-average molecular mass Mn of greater than 1.5×104 and a polydispersity index Mw/Mn of less than 1.60.

    摘要翻译： 用于制备卤化聚合物的自由基聚合方法，其使用一种或多种烯键式不饱和单体，其中至少一种选自卤代单体，分子碘和一种或多种选自重氮化合物，过氧化物和二烷基二烷基烷烃的自由基产生剂。自由基聚合方法 用于制备，从由上述方法制备的卤化聚合物开始的嵌段共聚物，其至少一个嵌段是卤代聚合物嵌段。 具有大于1.0×10 4的数均分子量Mn和小于1.65的Mz / Mw比的卤化聚合物。 嵌段共聚物，其至少一个嵌段是与上述卤化聚合物相同的卤代聚合物嵌段。 包含数均分子量Mn大于1.5×10 4的至少一种卤代聚合物嵌段和小于1.60的多分散指数Mw / Mn的嵌段共聚物。

    RADICAL POLYMERIZATION PROCESSES FOR PREPARING HALOGENATED POLYMERS, AND HALOGENATED POLYMERS
    60.
    发明申请
    RADICAL POLYMERIZATION PROCESSES FOR PREPARING HALOGENATED POLYMERS, AND HALOGENATED POLYMERS 有权
    用于制备低聚合聚合物的聚合方法和氢化聚合物

    公开(公告)号：US20070155929A1

    公开(公告)日：2007-07-05

    申请号：US11687461

    申请日：2007-03-16

    申请人： Patrick LACROIX-DESMAZES ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

    发明人： Patrick LACROIX-DESMAZES ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

    IPC分类号： C08F14/08

    CPC分类号： C08F293/005 ,  C08F8/22 ,  C08F14/00 ,  C08F214/18 ,  C08F214/186 ,  C08F293/00 ,  C08L53/00 ,  C08L2666/02 ,  C08L2666/24

    摘要： Radical polymerization process for the preparation of halogenated polymers employing one or more ethylenically unsaturated monomers, at least one of which is chosen from halogenated monomers, molecular iodine and one or more radical-generating agents chosen from diazo compounds, peroxides and dialkyl diphenylalkanes Radical polymerization process for the preparation, starting from the halogenated polymers prepared by the process as described above, of block copolymers, at least one block of which is a halogenated polymer block. Halogenated polymers which have a number-average molecular mass Mn of greater than 1.0×104 and an Mz/Mw ratio of less than 1.65. Block copolymers, at least one block of which is a block of halogenated polymer identical to the halogenated polymers described above. Block copolymers comprising at least one halogenated polymer block which have a number-average molecular mass Mn of greater than 1.5×104 and a polydispersity index Mw/Mn of less than 1.60.

    摘要翻译： 用于制备卤化聚合物的自由基聚合方法，其使用一种或多种烯键式不饱和单体，其中至少一种选自卤代单体，分子碘和一种或多种选自重氮化合物，过氧化物和二烷基二烷基烷烃的自由基产生剂。自由基聚合方法 用于制备，从由上述方法制备的卤化聚合物开始的嵌段共聚物，其至少一个嵌段是卤代聚合物嵌段。 具有大于1.0×10 4的数均分子量Mn和小于1.65的Mz / Mw比的卤化聚合物。 嵌段共聚物，其至少一个嵌段是与上述卤化聚合物相同的卤代聚合物嵌段。 包含数均分子量Mn大于1.5×10 4的至少一种卤代聚合物嵌段和小于1.60的多分散指数Mw / Mn的嵌段共聚物。