摘要:
The present invention concerns a process for preparing a polymer comprising at least one gel polymerization step (E) in which the following are contacted: ethylenically unsaturated water-soluble monomers, the same or different; a source of free radicals adapted to the polymerization of the said monomers, typically a redox system; and a radical polymerization control agent, preferably comprising a thiocarbonylthio —S(C═S)— group; with a concentration of monomers in the reaction medium of step (E) sufficiently high to cause gelling of the medium if polymerization was conducted without the control agent.
摘要:
Colloidal dispersions of inorganic particles in a liquid phase include ampholytic copolymers containing at least one macromolecular chain B and a moiety A bonded to a single end thereof and in which the macromolecular chain B includes cationic units Bc, deriving from cationic monomers Bc and the moiety A is a polymeric or non-polymeric group containing at least one anionic or potentially anionic group; such dispersions may have a positive zeta potential within a pH ranging from 1 to 11.
摘要:
The present invention relates to novel polymeric microgels and to a method suitable for the preparation thereof. The novel microgels comprise cationic units.
摘要:
The invention relates to novel ampholytic copolymers having a controlled architecture. These copolymers can particularly be used in aqueous compositions.
摘要:
The invention relates to novel hybrid compounds containing at least one polysaccharide entity (PS), such as guar, in which at least one hydroxyl function is substituted by at least one A polyoxyalkylene entity (PEG). The swivel Ro between the entity PS and the entity A is obtained by click chemistry and has the following formula (II.1) or (II.2), in which Z is a carbon or nitrogen atom. These hybrid compounds can be used as emulsifiers, particularly in cosmetics.
摘要:
Compounds containing macromolecular chains and having a structured architecture are prepared by polymerization of macromolecular monomers containing diallylamine structural units.
摘要:
An aqueous or aqueous-alcoholic crease-resistant formulation comprising a cationic surfactant (CSA), for the treatment after washing in aqueous or aqueous-alcoholic medium of articles made of textile fibers, said formulation also comprising a soluble or dispersible copolymer of controlled architecture (C) that is compatible with the surfactant (CSA) at the pH of said formulation and at the pH of use of said formulation, and comprising at least one nonionic hydrophobic organic polymer block B, and at least one ionic or ionizable organic polymer block A, the copolymer (C) making possible to give said articles properties of crease resistance and/or of ease of ironing.
摘要:
The invention concerns a method for preparing a polymer, comprising a step which consists in contacting: (A) at least a living organic polymer having at its chain end a dithiocarbonylated or dithiophosphorylated function capable of being reactivated; (B) at least a source of free radicals; and (C) at least an organic compound bearing a labile hydrogen atom, whereby the dithiocarbonylated or dithiophosphorylated function present on said living organic polymer is substituted by a hydrogen atom.
摘要:
The invention concerns a method for preparing a first generation polymer comprising a step which consists in radical polymerization of a composition containing: at least an ethylenically unsaturated monomer a free radical source, and at least a disulfide compound.
摘要:
The invention concerns a method for preparing polymers, characterised in that it consists in contacting: at least an ethylenically unsaturated polymer, at least a source of free radicals, and at least a compound of general formula (IA) wherein R2 represents a group formula (I); R3 being advantageously an electron-attracting group.