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    Preparation of metal complexes
    53.
    发明授权
    Preparation of metal complexes 失效
    金属络合物的制备

    公开(公告)号：US07102006B2

    公开(公告)日：2006-09-05

    申请号：US10524331

    申请日：2003-08-13

    申请人： Alexander Vogel ,  Edmund M. Carnahan

    发明人： Alexander Vogel ,  Edmund M. Carnahan

    IPC分类号： C07F7/00 ,  B01J31/00

    CPC分类号： C07F7/28 ,  C07F7/00

    摘要： A process for the preparation of Group 4 metal hydrocarbyl complex the steps of the process comprising contacting a Group 4 metal amide with a neutral source of a monovalent or divalent, Lewis base ligand group and a Lewis acid hydrocarbylating agent under conditions to form a Group 4 metal hydrocarbyl complex.

    摘要翻译： 一种制备第4族金属烃基络合物的方法，该方法的步骤包括使第4族金属酰胺与一价或二价路易斯碱配体基团和路易斯酸烃基化剂的中性源接触，形成第4族金属 金属烃基络合物。

    Process for preparing a supported polymerization catalyst using reduced amounts of solvent and polymerization process
    55.
    发明授权
    Process for preparing a supported polymerization catalyst using reduced amounts of solvent and polymerization process 有权
    使用减少量的溶剂和聚合方法制备负载型聚合催化剂的方法

    公开(公告)号：US06852811B1

    公开(公告)日：2005-02-08

    申请号：US09869578

    申请日：1999-12-06

    申请人： Edmund M. Carnahan ,  Ian M. Munro ,  Marc A. Springs

    发明人： Edmund M. Carnahan ,  Ian M. Munro ,  Marc A. Springs

    IPC分类号： C08F4/659 ,  C08F4/6592 ,  C08F210/16 ,  C08F4/52

    CPC分类号： C08F210/16 ,  C08F4/65908 ,  C08F4/6592 ,  C08F4/65927 ,  Y10S526/943 ,  C08F4/65916 ,  C08F210/14 ,  C08F2500/09

    摘要： The subject invention provides a process for preparing an olefin polymerization catalyst wherein a calcined and passivated silica support (support precursor) is sequentially contacted with a first solution of a metal complex or of a cocatalyst, and thereafter with a second solution of the other of the metal complex or the cocatalyst, wherein the second solution is provided in an amount such that 100 percent of the pore volume of the support precursor is not exceeded. Optionally, the compatible solvent of the first and/or second solutions is removed. The subject invention further provides a process for polymerizing one or more α-olefins in the presence of the olefin polymerization catalyst prepared by the process of the invention.

    摘要翻译： 本发明提供了一种制备烯烃聚合催化剂的方法，其中煅烧和钝化的二氧化硅载体（载体前体）依次与金属络合物或助催化剂的第一溶液接触，然后与另一种 金属络合物或助催化剂，其中提供的第二溶液的量使得不超过载体前体的100％孔体积。 任选地，除去第一和/或第二溶液的相容溶剂。 本发明还提供了在通过本发明的方法制备的烯烃聚合催化剂存在下聚合一种或多种α-烯烃的方法。

    Expanded anionic compounds comprising hydroxyl or quiescent reactive functionality and catalyst activators therefrom
    57.
    发明授权
    Expanded anionic compounds comprising hydroxyl or quiescent reactive functionality and catalyst activators therefrom 失效
    包括羟基或静止反应性官能团的膨胀的阴离子化合物及其催化剂活化剂

    公开(公告)号：US06627573B2

    公开(公告)日：2003-09-30

    申请号：US09904422

    申请日：2001-07-12

    申请人： David A. Babb ,  Richard E. Campbell, Jr. ,  David R. Neithamer ,  Grant B. Jacobsen ,  Edmund M. Carnahan

    发明人： David A. Babb ,  Richard E. Campbell, Jr. ,  David R. Neithamer ,  Grant B. Jacobsen ,  Edmund M. Carnahan

    IPC分类号： B01J3000

    CPC分类号： C08F10/00 ,  C07F5/027 ,  C07F5/062 ,  C07F5/066 ,  C07F7/0803 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65927 ,  C08F210/16 ,  C08F4/61908 ,  C08F4/65908 ,  C08F210/14 ,  C08F2500/12

    摘要： A compound useful as a cocatalyst or cocatalyst component, especially for use as an addition polymerization catalyst compound, corresponding to the formula: (A*+a)b(Z*J*j)−cd, wherein: A* is a cation of from 1 to 80, preferably 1 to 60 atoms, not counting hydrogen atoms, said A* having a charge +a, Z* is an anion group of from 1 to 50, preferably 1 to 30 atoms, not counting hydrogen atoms, further containing two or more Lewis base sites; J* independently each occurrence is a Lewis acid of from 1 to 80, preferably 1 to 60 atoms, not counting hydrogen atoms, coordinated to at least one Lewis base site of Z*, and optionally two or more such J* groups may be joined together in a moiety having multiple Lewis acidic functionality, j is a number from 2 to 12 and a, b, c, and d are integers from 1 to 3, with the proviso that a×b is equal to c×d, and provided further that one or more of A*, Z* or J* comprises a hydroxyl group or a polar group containing quiescent reactive functionality.

    摘要翻译： 用作助催化剂或助催化剂组分的化合物，特别是用作加成聚合催化剂化合物，其对应于下式：其中：A *是不计氢原子的1至80个，优选1至60个原子的阳离子，所述化合物 A *具有电荷+ a，Z *是1至50个，优选1至30个原子的阴离子基团，不计算氢原子，进一步含有两个或更多个路易斯碱基位点; J *各自独立地为路易斯酸 1至80个，优选1至60个原子，不计数氢原子，与Z *的至少一个路易斯碱碱基位点配位，并且任选地两个或多个这样的J *基团可以连接在具有多个路易斯酸官能团的部分中， j是2至12的数字，a，b，c和d是1至3的整数，条件是axb等于cxd，进一步提供A *，Z *或J *中的一个或多个包括 羟基或含有静止反应性官能团的极性基团。

    Zwitterionic catalyst activator
    58.
    发明授权
    Zwitterionic catalyst activator 有权
    两性离子催化剂活化剂

    公开(公告)号：US06344529B1

    公开(公告)日：2002-02-05

    申请号：US09445209

    申请日：1999-12-06

    申请人： Edmund M. Carnahan ,  Grant B. Jacobsen ,  Jerzy Klosin ,  Peter N. Nickias ,  David J. Schwartz ,  David R. Neithamer

    发明人： Edmund M. Carnahan ,  Grant B. Jacobsen ,  Jerzy Klosin ,  Peter N. Nickias ,  David J. Schwartz ,  David R. Neithamer

    IPC分类号： C08F452

    CPC分类号： C07F5/066 ,  C07F5/00 ,  C07F5/027 ,  C08F4/65916 ,  C08F4/65922 ,  C08F10/00 ,  C08F4/65908

    摘要： Disclosed are compounds useful as catalyst activators for olefin polymerization, comprising structures of the following formulae: wherein: L+ is a protonated derivative of an element of Group 15 of the Periodic Table of the Elements, additionally bearing two hydrocarbyl substituents of from 1 to 50 carbons each, or a positively charged derivative of an element of Group 14 of the Periodic Table of the Elements, said Group 14 element being substituted with three hydrocarbyl substituents of from 1 to 50 carbons each; R1 is a divalent linking group of from 1 to 40 non-hydrogen atoms; R2 independently each occurrence is a ligand group of from 1 to 50 nonhydrogen atoms with the proviso that in a sufficient number of occurrences to balance charge in the compound, R2 is L+—R1—; M1 is boron, aluminum or gallium; Arf independently each occurrence is a monovalent, fluorinated organic group containing from 6 to 100 non-hydrogen atoms; Y is a Group 15 element; and Z is a Group 14 element.

    摘要翻译： 公开了可用作烯烃聚合的催化剂活化剂的化合物，其包含下式的结构：其中：L +是元素周期表第15族元素的质子化衍生物，另外带有1至50个碳的烃基取代基 每个元素或元素周期表第14族元素的带正电荷的衍生物，所述第14族元素被各自为1至50个碳的三个烃基取代基取代; R 1为1至40的二价连接基团 非氢原子; R2各自独立地为1至50个非氢原子的配体基团，条件是在足够数量的化合物中平衡电荷的情况下，R2为L + -R1-; M1为硼，铝或 镓; Arf各自独立地为含有6至100个非氢原子的单价氟化有机基团; Y为第15族元素; 而Z是第14组元素。

    Catalytic olefin block copolymers with controlled block sequence distribution
    60.
    发明授权
    Catalytic olefin block copolymers with controlled block sequence distribution 有权
    具有受控块序列分布的催化烯烃嵌段共聚物

    公开(公告)号：US08053529B2

    公开(公告)日：2011-11-08

    申请号：US12066879

    申请日：2006-09-14

    申请人： Edmund M. Carnahan ,  Phillip D. Hustad ,  Roger L. Kuhlman ,  Timothy T. Wenzel

    发明人： Edmund M. Carnahan ,  Phillip D. Hustad ,  Roger L. Kuhlman ,  Timothy T. Wenzel

    IPC分类号： C08F297/00 ,  C08F2/00 ,  C08L23/00 ,  C08F4/643

    CPC分类号： C08F297/08 ,  C08F4/659 ,  C08F4/65908 ,  C08F4/6592 ,  C08F4/65927 ,  C08F10/00 ,  C08F210/06 ,  C08F210/16 ,  C08F2410/01 ,  C08F4/65912 ,  C08F2/38 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/20 ,  C08F2500/12 ,  C08F2500/08 ,  C08F4/64048 ,  C08F4/64193 ,  C08F4/64148 ,  C08F4/64144 ,  C08F2/001

    摘要： A process for the polymerization of one or more addition polymerizable monomers and the resulting polymer products, said process comprising: 1) contacting an addition polymerizable monomer or mixture of monomers under addition polymerization conditions in a reactor or reactor zone with a composition comprising at least one olefin polymerization catalyst and a cocatalyst and characterized by the formation of polymer chains from said monomer or monomers; 2) transferring the reaction mixture to a second reactor or reactor zone and optionally adding one or more additional reactants, catalysts, monomers or other compounds prior to, commensurate with, or after said transfer; and 3) causing polymerization to occur in said second reactor or reactor zone to form polymer chains that are differentiated from the polymer chains formed in step 1); said process being characterized by addition of a chain shuttling agent to the reaction mixture prior to, during, or subsequent to step 1) such that at least some of the resulting polymer molecules from step 3) comprise two or more chemically or physically distinguishable blocks or segments.

    摘要翻译： 一种用于聚合一种或多种可加聚单体和所得聚合物产物的方法，所述方法包括：1）在反应器或反应器区中的加成聚合条件下将加成聚合单体或单体混合物与包含至少一种 烯烃聚合催化剂和助催化剂，其特征在于由所述单体或单体形成聚合物链; 2）将反应混合物转移到第二反应器或反应器区，并任选地在所述转移之前，之后或之后加入一种或多种另外的反应物，催化剂，单体或其它化合物; 和3）在所述第二反应器或反应器区域中引起聚合以形成与步骤1）中形成的聚合物链不同的聚合物链; 所述方法的特征在于在步骤1）之前，期间或之后向反应混合物中加入链穿梭剂，使得来自步骤3）的所得聚合物分子中的至少一些包含两个或多个化学或物理上可区分的嵌段或 细分。