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69 条记录 (耗时 0.048 秒)

    Novel sulfonyl imide intermediates
    51.
    发明授权
    Novel sulfonyl imide intermediates 失效
    新型磺酰亚胺中间体

    公开(公告)号：US4257970A

    公开(公告)日：1981-03-24

    申请号：US76112

    申请日：1979-09-17

    申请人： Donald A. Tomalia

    发明人： Donald A. Tomalia

    IPC分类号： C07C311/00 ,  C07C143/74 ,  C07C143/90

    CPC分类号： C07C311/00

    摘要： Novel N-(haloalkyl)sulfonyl imides represented by the formula ##STR1## are prepared by the reaction of a 2-alkyl- or 2-aryl-oxazoline or oxazine with an arylene or alkane sulfonyl halide. In the formula for the novel sulfonyl imide, R.sub.1 and R.sub.2 are each independently C.sub.1 -C.sub.20 aryl, alkaryl or alkyl groups; R.sub.3, R.sub.4 and R.sub.5 are each hydrogen or methyl groups; n is the integer 0 or 1 and X is a chloro, bromo or iodo group. These novel sulfonyl imides are particularly useful in the preparation of N-(2-chloroethyl)- and N-(3-chloropropyl)sulfonamides.

    摘要翻译： 通过2-烷基 - 或2-芳基 - 恶唑啉或恶嗪与亚芳基或烷烃磺酰卤的反应制备由式I'表示的新型N-（卤代烷基）磺酰亚胺。 在新型磺酰亚胺的配方中，R 1和R 2各自独立地为C 1 -C 20芳基，烷芳基或烷基; R3，R4和R5各自为氢或甲基; n是0或1的整数，X是氯，溴或碘基。 这些新型磺酰亚胺特别可用于制备N-（2-氯乙基） - 和N-（3-氯丙基）磺酰胺。

    Vinyl substituted cyclic polyethers
    52.
    发明授权
    Vinyl substituted cyclic polyethers 失效
    乙烯基取代的环状聚醚

    公开(公告)号：US4139539A

    公开(公告)日：1979-02-13

    申请号：US751870

    申请日：1976-12-17

    申请人： Thomas A. Chamberlin ,  Donald A. Tomalia

    发明人： Thomas A. Chamberlin ,  Donald A. Tomalia

    IPC分类号： C07D323/00 ,  C08F16/26 ,  C08F20/28

    CPC分类号： C07D323/00 ,  C08F16/26 ,  C08F20/28

    摘要： Compounds represented by the formula ##STR1## AND ADDITION POLYMERS THEREOF WHERE M IS AN INTEGER FROM 2 TO ABOUT 10, X-- is chlorine, hydroxy, carboxy or--AC--(R).dbd.CH.sub.2--r is hydrogen or methyl, --R-- is an ethylene or propylene group and--AC--(R).dbd.CH.sub.2is one of ##STR2## These compounds and their addition polymers form complexes with alkali metal or alkaline earth metal salts and permit the concentration of aqueous solutions of said salts. For example, a compound of the formula ##STR3## is polymerized with an azobis(isobutyronitrile) catalyst to form addition polymers of the repeating unit ##STR4## When cross-linked, rendering it water-insoluble, such an addition polymer concentrates an aqueous solution of sodium chloride when contacted with same at about 0.degree. C.

    摘要翻译： 由下式表示的化合物及其添加聚合物，其中M是从2到约10的整数，X-是氯，羟基，羧基或-AC-（R）= CH 2 -R是氢或甲基，-R- 是乙烯或丙烯基，-AC-（R）= CH 2是之一

    Nanocomposites of dendritic polymers
    53.
    发明授权
    Nanocomposites of dendritic polymers 有权

    公开(公告)号：US06664315B2

    公开(公告)日：2003-12-16

    申请号：US09780973

    申请日：2001-02-10

    申请人： Donald A. Tomalia ,  Lajos Balogh

    发明人： Donald A. Tomalia ,  Lajos Balogh

    IPC分类号： C08J300

    CPC分类号： B82Y30/00 ,  C08G83/003 ,  C08J3/02 ,  C08J2300/00 ,  C08J2300/202 ,  Y10S977/753 ,  Y10S977/754 ,  Y10S977/788 ,  Y10S977/835

    摘要： In the present invention, an inorganic reactant is, or reactants are, localized with respect to a dendritic polymer by physical constraint within or by a non-covalent conjugation to the dendritic polymer. The localized inorganic reactant or reactants is/are subsequently transformed to form a reaction product which is immobilized with respect to the dendritic polymer. This immobilization occurs on a nanoscopic scale as a consequence of the combined effects of structural, chemical and physical changes without having covalent bonds between the product(s) and the dendritic container and results in new compositions of matter called dendritic nanocomposites. The resulting nanocomposite material can be used to produce revolutionary products such as water soluble elemental metals, with specific applications including magnetic resonance imaging, catalytic, magnetic, optical, photolytic and electroactive applications.

    Electrically conducting dendrimers
    56.
    发明授权
    Electrically conducting dendrimers 失效
    导电树枝状大分子

    公开(公告)号：US6043336A

    公开(公告)日：2000-03-28

    申请号：US311

    申请日：1998-01-26

    申请人： Larry L. Miller ,  Donald A. Tomalia ,  Robert G. Duan

    发明人： Larry L. Miller ,  Donald A. Tomalia ,  Robert G. Duan

    IPC分类号： C08G73/06 ,  C08G83/00 ,  C08G63/00 ,  C08G73/00

    CPC分类号： C08G83/003 ,  C08G73/0688 ,  Y10S424/16

    摘要： An electrically conductive polymer is comprised of the reaction product of a dendrimer and an electrophoric compound which exhibits .pi.-stacking upon reduction. The reaction product which is a peripherally modified dendrimer is formed and reduced, either chemically or electrochemically, in a polar solvent. The reduced electrophoric moieties aggregate (form .pi.-stacks) to form electrically conductive pathways. The reduced peripherally modified dendrimers of the invention can be cast into films and other solid forms to provide flexible electrical conductors and semiconductors. The conductive polymers of the invention exhibit electrical conductivities comparable to that of doped polyacetalene, but are oxygen and moisture stable.

    摘要翻译： PCT No.PCT / US96 / 12283 Sec。 371日期1998年1月26日 102（e）1998年1月26日PCT PCT 1996年7月25日PCT公布。 出版物WO97 / 05631 日期1997年2月13日导电聚合物由树枝状聚合物和电还原化合物的反应产物组成，其在还原时显示出π堆叠。 作为外围改性的树枝状聚合物的反应产物在极性溶剂中以化学或电化学方式形成和还原。 还原的电化学部分聚集（形成π-叠层）以形成导电通路。 本发明的减少的周边改性的树枝状大分子可以铸成薄膜和其它固体形式以提供柔性电导体和半导体。 本发明的导电聚合物表现出与掺杂的聚缩醛相当的电导率，但是氧和水分稳定。

    Ion exchange/chelation resins containing dense star polymers having ion exchange or chelate capabilities
    60.
    发明授权
    Ion exchange/chelation resins containing dense star polymers having ion exchange or chelate capabilities 失效
    含有具有离子交换或螯合能力的致密星形聚合物的离子交换/螯合树脂

    公开(公告)号：US4871779A

    公开(公告)日：1989-10-03

    申请号：US812479

    申请日：1985-12-23

    申请人： George R. Killat ,  Donald A. Tomalia

    发明人： George R. Killat ,  Donald A. Tomalia

    IPC分类号： B01J39/20 ,  B01J45/00 ,  C08F8/30 ,  C08G83/00

    CPC分类号： C08G83/003 ,  B01J39/20 ,  B01J45/00 ,  C08F8/32 ,  Y10S424/16

    摘要： Ion exchange resins and chelate resins are provided with ion exchange or chelate capability by depositing on an insoluble substrate dense star polymers having terminal group densities greater than conventional star polymers exhibiting greater and more uniform reactivity than their corresponding conventional star polymers. For example, a third generation, amine-terminated polyamidoamine dense star polymer prepared from ammonia, methyl acrylate and ethylenediamine having 1.24.times.10.sup.-4 amine moieties per unit volume (cubic Angstrom units) in contrast to the 1.58.times.10.sup.-6 amine moieties per unit volume contained by a conventional star polymer can be reacted with a chloromethylated styrene/divinyl copolymer (insoluble substrate) to form a desirably weak base anion exchange resin.

    摘要翻译： 离子交换树脂和螯合树脂具有离子交换或螯合能力，通过沉积在不溶性底物上，具有比其相应的常规星形聚合物显示更大和更均匀的反应性的常规星形聚合物的端基密度的致密星形聚合物。 例如，与每单位体积的1.58×10-6胺部分相反，由氨，甲基丙烯酸酯和乙二胺制备的第三代胺封端的聚酰氨胺胺致密星形聚合物，每单位体积（立方单位）具有1.24×10 -4胺部分 通过常规的星形聚合物可以与氯甲基化苯乙烯/二乙烯基共聚物（不溶性底物）反应，形成理想的弱碱阴离子交换树脂。