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公开(公告)号:US20210017195A1
公开(公告)日:2021-01-21
申请号:US16982490
申请日:2019-03-18
Applicant: Dow Global Technologies LLC , Dow Silicones Corporation
Inventor: Jordan Reddel , Robert David Grigg , Phillip Dene Hustad , Sukrit Mukhopadhyay , Steven Swier , Ken Kawamoto
Abstract: A process to functionalize organo-zinc compounds with halosilane electrophiles employs a basic additive. The process includes combining the organo-zinc compound, a halosilanes, and a nitrogen containing heterocycle as the basic additive. The presence of the basic additive facilitates successful substitution. Functionalized silanes and silyl-terminated polyolefins can be prepared using this process. The functionalized silanes may be useful as endblockers for polyorganosiloxanes having SiH and/or silicon bonded aliphatically unsaturated groups capable of undergoing hydrosilylation.
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公开(公告)号:US20200231738A1
公开(公告)日:2020-07-23
申请号:US16644284
申请日:2018-09-14
Applicant: Dow Global Technologies LLC , Northwestern University
Inventor: Arjun Raghuraman , William H. Heath , Sukrit Mukhopadhyay , Heather A. Spinney , David R. Wilson , Anthony P. Gies , Manjiri R. Paradkar , Justin M. Notestein , SonBinh T. Nguyen
Abstract: A method of producing a polyether polyol that includes reacting a low molecular weight initiator with one or more monomers in the presence of a polymerization catalyst, the low molecular weight initiator having a number average molecular weight of less than 1,000 g/mol and a nominal hydroxyl functionality at least 2, the one or more monomers including at least one selected from propylene oxide and butylene oxide, and the polymerization catalyst being a Lewis acid catalyst having the general formula M(R1)1(R2)1(R3)1(R4)0 or 1. Whereas, M is boron, aluminum, indium, bismuth or erbium, R1, R2, and R3 each includes a same fluoroalkyl-substituted phenyl group, and optional R4 includes a functional group or functional polymer group. The method further includes forming a polyether polyol having a number average molecular weight of greater than the number average molecular weight of the low molecular weight initiator in the presence of the Lewis acid catalyst.
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公开(公告)号:US20190252618A1
公开(公告)日:2019-08-15
申请号:US16329839
申请日:2017-10-20
Applicant: Dow Global Technologies LLC
Inventor: Robert David Grigg , Liam P. Spencer , John W. Kramer , David D. Devore , Brian Goodfellow , Chun Liu , Sukrit Mukhopadhyay , Thomas H. Peterson , William H. H. Woodward , Anatoliy N. Sokolov
CPC classification number: H01L51/0042 , H01L51/008 , H01L51/0081 , H01L51/0082 , H01L51/5056 , H01L51/5088
Abstract: Provided is an organic light-emitting diode comprising a substrate, an anode layer, optionally one or more hole injection layers, one or more hole transport layers, optionally one or more electron blocking layers, an emitting layer, optionally one or more hole blocking layers, optionally one or more electron transport layers, an electron injection layer, and a cathode, wherein either the hole injection layer, or the hole transport layer, or both of the hole injection layer and the hole transport layer, or layer that functions as both a hole injection layer and a hole transport layer, comprises a polymer that comprises one or more triaryl aminium radical cations having the structure (S1) wherein each of R11, R12, R13, R14, R15, R21, R22, R23, R24, R25, R31, R32, R33, R34, and R35 is independently selected from the group consisting of hydrogen, deuterium halogens, amine groups, hydroxyl groups, sulfonate groups, nitro groups, and organic groups, wherein two or more of R11, R12, R13, R14, R15, R21, R22, R23, R24, R25, R31, R32, R33, R34, and R35 are optionally connected to each other to form a ring structure; wherein one or more of R11, R12, R13, R14, R15, R21, R22, R23, R24, R25, R31, R32, R33, R34, and R35 is covalently bound to the polymer, and wherein A is an anion.
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54.
公开(公告)号:US20180340033A1
公开(公告)日:2018-11-29
申请号:US15988473
申请日:2018-05-24
Abstract: Disclosed herein is a composition comprising a co-continuous interpenetrating network of an organic polymer and a electroactive moiety; where the organic polymer is operative to depolymerize at a temperature of 50 to 500° C. and to repolymerize on a surface in the presence of the electroactive moiety; and where the electroactive moiety is an organic semiconductor that does not react with a repolymerized polymer. Disclosed herein too is a method comprising co-evaporating a polymeric precursor and an electroactive moiety onto a substrate; condensing the polymeric precursor and an electroactive moiety on the substrate; and polymerizing the polymeric precursor to form a co-continuous interpenetrating network of an organic polymer and an electroactive moiety; where the electroactive moiety is defined as a chemical functional group which is capable of transporting an electrical charge.
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公开(公告)号:US20180226584A1
公开(公告)日:2018-08-09
申请号:US15504389
申请日:2015-01-08
Applicant: Dow Global Technologies LLC , Rohm and Haas Electronic Materials LLC , Rohm and Haas Electronic Materials Korea Ltd.
Inventor: Liam P. Spencer , Hong-Yeop Na , Yoo-Jin Doh , Chun Liu , Minrong Zhu , Jichang Feng , Zhengming Tang , Shaoguang Feng , Kenneth L. Kearns, JR. , Timothy De Vries , Sukrit Mukhopadhyay , John W. Kramer , Peter Trefonas, III , David D. Devore , William H. H. Woodward
IPC: H01L51/00 , C07D209/86 , C08G61/12
CPC classification number: H01L51/0043 , C07D209/86 , C08G61/124 , C08G2261/124 , C08G2261/1424 , C08G2261/1434 , C08G2261/148 , C08G2261/18 , C08G2261/228 , C08G2261/312 , C08G2261/3142 , C08G2261/3162 , C08G2261/3241 , C08G2261/512 , C08G2261/95 , H01L51/0003 , H01L51/0034 , H01L51/004 , H01L51/005 , H01L51/5056 , H01L51/506 , H01L51/5072
Abstract: The present invention relates to a polymeric charge transfer layer comprising a polymer and a p-dopant. The polymer comprises as polymerized units, Monomer A, Monomer B, and Monomer C crosslinking agent. The present invention further relates to an organic electronic device, especially an organic light emitting device containing the polymeric charge transfer layer.
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公开(公告)号:US20180212180A1
公开(公告)日:2018-07-26
申请号:US15744888
申请日:2015-08-21
Applicant: Dow Global Technologies LLC
Inventor: Robert David Grigg , Liam P. Spencer , John W. Kramer , Chun Liu , Sukrit Mukhopadhyay , David D. Devore , Shaoguang Feng , Jichang Feng , Minrong Zhu
IPC: H01L51/50 , H01L51/00 , C07D209/82 , H01L51/52
CPC classification number: H01L51/5064 , C07D209/82 , C08F12/22 , C08F12/26 , C08F12/32 , C09D125/18 , H01L51/0034 , H01L51/0043 , H01L51/0051 , H01L51/006 , H01L51/0072 , H01L51/5012 , H01L51/5056 , H01L51/5072 , H01L51/5206 , H01L51/5221
Abstract: The present invention provides a polymeric charge transfer layer composition comprising a polymer comprising, as polymerized units, at least one Monomer A and at least one Monomer B. It further provides an organic light emitting device and an organic electronic device comprising the polymeric charge transfer layer.
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公开(公告)号:US20180138407A1
公开(公告)日:2018-05-17
申请号:US15567987
申请日:2016-04-22
Applicant: Dow Global Technologies LLC , Rohm and Haas Electronic Materials LLC , Rohm and Haas Electronic Materials Korea Ltd.
Inventor: Thomas P. Clark , David S. Laitar , Sukrit Mukhopadhyay , Aaron A. Rachford , Robert DJ Froese , David D. Devore , Bethany Neilson , Jeong-Hwan Jeon , Hong-Yeop Na
CPC classification number: H01L51/008 , C07F5/02 , C07F5/025 , C07F5/04 , C09K11/06 , C09K2211/1022 , H01L51/0067 , H01L51/0072 , H01L51/5012 , H01L51/5016 , H05B33/14
Abstract: A compound having a four-coordinate boron atom to which is connected a first C3-C25 substituent, a second C3-C25 substituent and a bridging substituent comprising from eight to forty non-hydrogen atoms and having two bonds to the boron atom;wherein: (i) each of the first and second C3-C25 substituents is bonded to the boron atom through a carbon, nitrogen or oxygen atom, and, optionally the first and second C3-C25 substituents are connected to form a single substituent having two bonds to the boron atom; (ii) at least one of the first and second C3-C25 substituents is a C6-C25 aromatic substituent; (iii) said aromatic substituent comprises at least one nitrogen atom which is bonded only to carbon or boron atoms; and (iv) the bridging substituent has at least one oxygen, nitrogen, sulfur or phosphorus atom bonded to the boron atom and at least one aromatic ring.
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公开(公告)号:US20180127403A1
公开(公告)日:2018-05-10
申请号:US15570578
申请日:2016-07-07
Inventor: Nolan T. McDougal , David S. Laitar , Sukrit Mukhopadhyay , Thomas P. Clark , David D. Devore , Kaitlyn Gray , Aaron A. Rachford , Robert DJ Froese
IPC: C07D413/14 , C07D413/04 , C07D401/14 , C07D401/04 , C09K11/06 , H01L51/00
CPC classification number: C07D413/14 , C07D401/04 , C07D401/14 , C07D413/04 , C09B11/24 , C09B15/00 , C09B19/00 , C09K11/06 , H01L51/0067 , H01L51/0071 , H01L51/0072 , H01L51/5012
Abstract: A compound having a tricyclic nucleus and having formula (I) wherein Ar is C3-C25 aryl in which at least one aromatic ring atom is nitrogen; X is O, S or CR9R10; R1, R2, R3, R4, R5 and R6 independently are hydrogen, deuterium, C1-C12 alkyl, C4-C12 aryl or C2-C12 alkenyl; R7 and R8 independently are hydrogen, deuterium, C1-C12 alkyl, C4-C12 aryl or C2-C12 alkenyl or R7 and R8 groups attached to a nitrogen atom are joined by a single bond, O, S or CR11R12 to form a single nitrogen-containing substituent; R9 and R10 independently are hydrogen, deuterium, C1-C12 alkyl, C4-C12 aryl or C2-C12 alkenyl; and R11 and R12 independently are hydrogen, deuterium, C1-C12 alkyl, C4-C12 aryl or C2-C12 alkenyl; provided that Ar does not contain an aromatic ring attached to the tricyclic nucleus which contains more than two aromatic ring nitrogen atoms.
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59.
公开(公告)号:US20240376269A1
公开(公告)日:2024-11-14
申请号:US18291765
申请日:2022-10-10
Applicant: Dow Global Technologies LLC
Inventor: Souvagya Biswas , Jason Fisk , Sukrit Mukhopadhyay
Abstract: A method for preparing an ester-functional siloxane includes hydrosilylation of an alkenyl ether and an organohydrogensiloxane oligomer. A platinum hydrosilylation catalyst and a promoter are used in the method.
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公开(公告)号:US20240270936A1
公开(公告)日:2024-08-15
申请号:US18560962
申请日:2022-08-01
Applicant: Dow Global Technologies LLC , Rohm and Haas Company
Inventor: Paul M. Mwasame , Xindi Yu , Decai Yu , Sukrit Mukhopadhyay , Yuanqiao Rao , Timothy J. Person
CPC classification number: C08K5/07 , C08J3/203 , C08J3/24 , H01B3/441 , C08J2323/06
Abstract: A polyolefin formulation comprises (A) a polyolefin polymer; at least one and at most two different (B) an acetoarenone compound of formula (I) and (C) a benzophenone compound of formula (II) as described in the specification. Also crosslinked products made therefrom; methods of making and using same; and articles containing same.
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