Abstract:
Provided are a curable composition including an amide compound that is represented by Formula (1) below and of which a density of sulfonic acid is 3.9 milliequivalent/g or greater, a functional polymer hardened product, a stack or a device including a functional polymer membrane, an amide compound, and a manufacturing method thereof. m represents an integer of 1 or greater, n represents an integer of 2 or greater, L1 represents a m+1-valent linking group, and L2 represents an n-valent linking group. R1 represents a hydrogen atom or an alkyl group, and R2 represents —SO3−M+ or —SO3R3 (R3 represents an alkyl group or an aryl group). Here, in a case where there are plural R2's, not all of the R2's are —SO3R3. M+ represents a hydrogen ion, an inorganic ion, or an organic ion.
Abstract:
Provided is an ion exchange film including a resin which is disposed in pores of a porous support and made of a styrene-acryl copolymer having a structure expressed by General Formula (PI) or (PII) below, a composition for forming the film, and a production method therefor. R1 and R2 represent a hydrogen atom or an alkyl group, Y1 and Y2 represent —O— or —N(Rx)-, and Rx represents a hydrogen atom or an alkyl group. L1 represents a p1+1-valent linking group having 2 or more carbon atoms, L2 represents a bivalent linking group, p1 represents an integer of 1 or greater, and n1, n2, and m1 represent integers of 1 or greater. Ra to Rg represent alkyl groups or aryl groups, 2 or 3 of Ra to Rc may be bonded to each other to form a ring, and 2 to 4 of Rd to Rg are bonded to each other to form a ring. X1− to X4− represent an organic or inorganic anion.
Abstract:
The present invention provides a polymer functional film obtained by polymerizing and curing a composition including (A) a styrene-based monomer represented by Formula (HSM); (B) a crosslinking agent represented by Formula (CL); and (C) a polymerization initiator represented by Formula (PI-1) or (PI-2), and a method for producing the same: in which R1 represents a halogen atom or —N+(R2)(R3)(R4)(X1−); n1 represents an integer from 1 to 10; here, R2 to R4 each independently represent a particular substituent; X1− represents an organic or inorganic anion;L1 represents an alkylene group or an alkenylene group; Ra, Rb, Rc and Rd each independently represent a particular substituent; n2 and n4 each independently represent an integer from 1 to 10; X2− and X3− each independently represent an organic or inorganic anion; andR5 to R10 each represent a hydrogen atom or a particular substituent.
Abstract:
A gas separation composite membrane, containing a gas permeable supporting layer, and a gas separating layer containing a crosslinked polyimide resin above the gas permeable supporting layer, in which the crosslinked polyimide resin has a structure in which 2 to 4 molecules of a polyimide compound is coordinated with a divalent to tetravalent central metal via an oxygen atom or a sulfur atom, and when the crosslinked polyimide resin has plural central metals, the plural central metals are linked via the polyimide chain of the polyimide compound; and a gas separating module, a gas separation apparatus and a gas separation method utilizing this gas separation composite membrane.
Abstract:
A functional polymer membrane having a pore volume fraction of 0.6% or more and 3.0% or less by allowing a reaction of curing a composition containing a polymerizable compound (A) and a copolymerizable monomer (B).