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    Polyethersulfone compositions with high heat and good impact resistance
    51.
    发明授权
    Polyethersulfone compositions with high heat and good impact resistance 有权
    具有高耐热性和耐冲击性的聚醚砜组合物

    公开(公告)号：US08106135B2

    公开(公告)日：2012-01-31

    申请号：US11552276

    申请日：2006-10-24

    申请人： Daniel Joseph Brunelle ,  Daniel Steiger

    发明人： Daniel Joseph Brunelle ,  Daniel Steiger

    IPC分类号： C08G75/23 ,  C08F283/06 ,  C08L81/00

    CPC分类号： C08G75/23 ,  C08L81/06

    摘要： Polyethersulfones having Tg greater than about 225° C. and a notched Izod value greater than about 1 ft-lb/in, as measured by ASTM D256, comprise from about 5 mol % to less than about 40 mol % structural units of formula 1; and from greater than about 60 mol % to about 95 mol % structural units of formula 2 wherein R1, R2, and R3 are independently at each occurrence a halogen atom, a nitro group, a cyano group, a C1-C12 aliphatic radical, C3-C12 cycloaliphatic radical, or a C3-C12 aromatic radical; n, m, q are independently at each occurrence integers from 0 to 4; and Q is a C3-C20 cycloaliphatic radical, or a C3-C20 aromatic radical.

    摘要翻译： Tg大于约225℃的聚醚砜和通过ASTM D256测量的大于约1ft-lb / in的缺口伊佐德值包含约5mol％至小于约40mol％的式1结构单元; 和大于约60mol％至约95mol％的式2的结构单元，其中R 1，R 2和R 3在每次出现时独立地为卤素原子，硝基，氰基，C 1 -C 12脂族基，C 3 -C 12脂环族基团或C 3 -C 12芳族基团; n，m，q各自独立地为0至4的整数; 且Q为C 3 -C 20脂环族基团或C 3 -C 20芳族基团。

    Copolyetherimides
    52.
    发明授权
    Copolyetherimides 有权
    共聚酰亚胺

    公开(公告)号：US07605222B2

    公开(公告)日：2009-10-20

    申请号：US11210164

    申请日：2005-08-22

    申请人： Qing Ye ,  David Bruce Hall ,  William David Richards ,  Daniel Joseph Brunelle ,  Havva Yagci Acar

    发明人： Qing Ye ,  David Bruce Hall ,  William David Richards ,  Daniel Joseph Brunelle ,  Havva Yagci Acar

    IPC分类号： C08G73/00

    CPC分类号： C08G73/1046 ,  C08G73/124

    摘要： Copolyetherimides compositions having high glass transition temperatures and outstanding ductility are presented. The copolyetherimides having Mw of at least 40,000 comprising isomeric bis(phthalimide) structural units within a relatively narrow range of isomer proportions exhibited Tgs of at least 240° C. and outstanding Notched Izod values. The copolyetherimides comprise oxydianiline residues and structural units of the formulas (I) and (II) (III). The copolyetherimides are characterized by a mole percentage of structural units derived from 4,4′-biphenol in a range from about 55% to about 85% of all bisphenol-derived structural units present in the copolyetherimide composition; a mole percentage of structural units derived from bisphenol A in a range from about 45% to about 15% of all bisphenol-derived structural units present in the copolyetherimide composition; and a total mole percentage of structural units derived from bisphenol A or 4,4′-biphenol of at least 95% of all bisphenol-derived structural units present in the copolyetherimide composition.

    摘要翻译： 提出了具有高玻璃化转变温度和优异延展性的共聚酰亚胺组合物。 具有至少40,000的Mw的共聚醚酰亚胺，其包含在相对窄的异构体比例范围内的异构双（邻苯二甲酰亚胺）结构单元，其Tg至少为240℃，并且具有优异的缺口伊佐德值。 共聚醚酰亚胺包括氧化二苯胺残基和式（I）和（II）（III）的结构单元。 共聚醚酰亚胺的特征在于衍生自4,4'-联苯酚的结构单元的百分比在共聚醚酰亚胺组合物中存在的所有双酚衍生的结构单元的约55％至约85％的范围内; 来自双酚A的结构单元的摩尔百分比在存在于共聚醚酰亚胺组合物中的所有双酚衍生的结构单元的约45％至约15％的范围内; 并且衍生自双酚A或4,4'-联苯酚的结构单元的总摩尔百分比为存在于共聚醚酰亚胺组合物中的所有双酚衍生的结构单元的至少95％。

    Carboxy-terminated oligomeric polyester compositions and method for making
    53.
    发明授权
    Carboxy-terminated oligomeric polyester compositions and method for making 失效
    羧基封端的低聚聚酯组合物及其制备方法

    公开(公告)号：US07557174B2

    公开(公告)日：2009-07-07

    申请号：US11528206

    申请日：2006-09-27

    申请人： Daniel Joseph Brunelle ,  Martino Colonna ,  Corrado Berti ,  Maurizio Fiorini ,  Enrico Binassi

    发明人： Daniel Joseph Brunelle ,  Martino Colonna ,  Corrado Berti ,  Maurizio Fiorini ,  Enrico Binassi

    IPC分类号： C08G63/00 ,  C08G63/87 ,  C08F20/00

    CPC分类号： C08G63/85 ,  C08G63/191 ,  C08G63/64

    摘要： The present invention provides carboxy-terminated oligomeric polyester compositions useful in the preparation of “weatherable” polymeric materials, for example weatherable copolyestercarbonates. In one aspect the present invention provides an oligomeric polyester composition comprising structural units derived from at least one diacid, at least one diaryl carbonate and at least one diol. The structural units derived from the diacid are present in a molar excess of from about 10% to about 40% based on a ratio of moles of diacid-derived structural units to moles of diol-derived structural units present in the oligomeric polyester composition. The oligomeric polyester composition is further characterized by the presence of at least some phenoxy end groups.

    摘要翻译： 本发明提供了可用于制备“耐候性”聚合物材料的羧基封端的低聚聚酯组合物，例如耐候性共聚酯碳酸酯。 在一个方面，本发明提供了包含衍生自至少一种二酸，至少一种碳酸二芳酯和至少一种二醇的结构单元的低聚聚酯组合物。 基于二酸衍生的结构单元的摩尔数与存在于低聚聚酯组合物中的二醇衍生的结构单元的摩尔数的比例，衍生自二酸的结构单元的摩尔过量为约10％至约40％。 低聚聚酯组合物的特征还在于存在至少一些苯氧基端基。

    Benzimidazole diamine-based polyetherimide compositions and methods for making them
    55.
    发明授权
    Benzimidazole diamine-based polyetherimide compositions and methods for making them 失效
    苯并咪唑二胺类聚醚酰亚胺组合物及其制备方法

    公开(公告)号：US07071282B2

    公开(公告)日：2006-07-04

    申请号：US10454006

    申请日：2003-06-03

    申请人： Havva Acar ,  Daniel Joseph Brunelle

    发明人： Havva Acar ,  Daniel Joseph Brunelle

    IPC分类号： C08G73/10 ,  C08G69/28 ,  C08L77/00

    CPC分类号： C08G73/1085 ,  C08G73/1053 ,  C08G73/18

    摘要： Disclosed herein are polyetherimide compositions comprising structural units of the formula: derived from at least one benzimidazole diamine, wherein R1 and R2 are independently selected from hydrogen and C1–C6 alkyl groups; “A” comprises structural units of the formulae: or mixtures of the foregoing structural units; wherein “D” is a divalent aromatic group, R3 and R10–R12 are independently selected from hydrogen, halogen, and C1–C6 alkyl groups; “q” is an integer having a value of 1 up to the number of positions available on the aromatic ring for substitution; and “W” is a linking group; and “B” comprises substituted and unsubstituted arylene groups having from about 6 to about 25 carbon atoms. Methods for producing the polyetherimide compositions are also disclosed herein.

    摘要翻译： 本文公开了包含下式结构单元的聚醚酰亚胺组合物：衍生自至少一种苯并咪唑二胺，其中R 1和R 2独立地选自氢和C 1 -C 6烷基， C 1 -C 6烷基; “A”包括下列结构单元：或前述结构单元的混合物; 其中“D”是二价芳族基团，R 3和R 10 -R 12独立地选自氢，卤素和C 1-4烷基， C 1 -C 6烷基; C 1 -C 6烷基; “q”是具有值为1的整数，直到芳环上取代的可用位置数; 和“W”是连接基团; “B”包括具有约6至约25个碳原子的取代和未取代的亚芳基。 本文还公开了制备聚醚酰亚胺组合物的方法。

    Copolyetherimides
    56.
    发明授权
    Copolyetherimides 有权
    共聚酰亚胺

    公开(公告)号：US06849706B1

    公开(公告)日：2005-02-01

    申请号：US10647888

    申请日：2003-08-25

    申请人： Daniel Joseph Brunelle ,  Havva Yagci Acar ,  Farid Fouad Khouri ,  William David Richards

    发明人： Daniel Joseph Brunelle ,  Havva Yagci Acar ,  Farid Fouad Khouri ,  William David Richards

    IPC分类号： C08G73/12 ,  C08G73/00

    CPC分类号： C08G73/123 ,  C08G73/124 ,  C08G73/125

    摘要： Copolyetherimides comprise phthalimide structural units comprising both 3- and 4-linkages, wherein the designations 3-linkage and 4-linkage refer to the isomeric positions on the phthalimide ring in the totality of phthalimide-comprising structural units in the copolymer. The products have excellent properties, including high glass transition and heat distortion temperatures, high ductility and good melt flow properties, and low polydispersity.

    摘要翻译： 共聚酰亚胺包括包含3-和4-键的邻苯二甲酰亚胺结构单元，其中3-键和4-键的名称是指共聚物中邻苯二甲酰亚胺包含的结构单元总共在邻苯二甲酰亚胺环上的异构位置。 该产品具有优异的性能，包括高玻璃化转变和热变形温度，高延展性和良好的熔体流动性能，以及低的多分散性。

    Method of polycarbonate preparation
    59.
    发明授权
    Method of polycarbonate preparation 有权

    公开(公告)号：US06576739B2

    公开(公告)日：2003-06-10

    申请号：US09735871

    申请日：2000-12-14

    申请人： Peter David Phelps ,  Elliott West Shanklin ,  Daniel Joseph Brunelle

    发明人： Peter David Phelps ,  Elliott West Shanklin ,  Daniel Joseph Brunelle

    IPC分类号： C08G6400

    CPC分类号： C08G64/24 ,  C07C68/02 ,  C07C69/96

    摘要： High molecular weight polycarbonates are prepared from hindered bisphenols in a reaction sequence involving conversion of the hindered bisphenol to the corresponding bischloroformate and subsequent treatment with an amine catalyst and aqueous base to effect polymerization by hydrolysis and condensation of the bischloroformate groups. Tertiary aliphatic and cycloaliphatic amine catalysts bearing at least one methyl group are found to be especially effective in promoting this polymerization reaction. Reaction rates and selectivities are shown to be superior to known methods employing tertiary amines lacking methyl groups attached to nitrogen, such as triethylamine. The inclusion of chain stoppers allows the preparation of well defined mixtures of polycarbonate oligomers from hindered bisphenols. Additionally, the methodology may be used to prepare symmetrical diaryl carbonates from hindered phenols.

    Weatherable polycarbonates comprising oxanilide structural units, method, and articles made therefrom
    60.
    发明授权
    Weatherable polycarbonates comprising oxanilide structural units, method, and articles made therefrom 有权
    耐候性聚碳酸酯，其包含草酰替苯胺结构单元，方法和由其制成的制品

    公开(公告)号：US06462168B1

    公开(公告)日：2002-10-08

    申请号：US09842616

    申请日：2001-04-25

    申请人： Tiberiu Mircea Siclovan ,  Daniel Joseph Brunelle ,  James Edward Pickett ,  Joseph Anthony Suriano

    发明人： Tiberiu Mircea Siclovan ,  Daniel Joseph Brunelle ,  James Edward Pickett ,  Joseph Anthony Suriano

    IPC分类号： C08G6400

    CPC分类号： C08G64/12

    摘要： In one embodiment the present invention is a polycarbonate comprising structural units derived from at least one dihydric phenol, a carbonate precursor, and at least one member selected from the group consisting of an oxanilide-comprising compound, an oxamate-comprising compound, and mixtures thereof. In another embodiment the present invention is a method for making a polycarbonate comprising structural units derived from at least one dihydric phenol and at least one member selected from the group consisting of an oxanilide-comprising compound, an oxamate-comprising compound, and mixtures thereof, which comprises the step of contacting under reactive conditions at least one dihydric phenol, a carbonate precursor, and at least one member selected from the group consisting of an oxanilide-comprising compound, an oxamate-comprising compound, and mixtures thereof. In still another embodiment the present invention is an article comprising a polycarbonate comprising oxanilide structural units. In still another embodiment the present invention is a method for making a symmetrical or unsymmetrical oxanilide-comprising dihydric phenol which comprises the step of contacting at least one aromatic amine bearing a hydroxy group with a diaryl oxalate or a dialkyl oxalate bearing alkyl groups each substituted with at least one electron-withdrawing group. In still another embodiment the present invention is a method for making an oxamate-comprising monohydric phenol which comprises the step of contacting an aromatic amine bearing a hydroxy group with a diaryl oxalate or a dialkyl oxalate bearing alkyl groups each substituted with at least one electron-withdrawing group.

    摘要翻译： 在一个实施方案中，本发明是包含衍生自至少一种二元酚，碳酸酯前体和至少一种选自由含草酰替苯的化合物，含草酸酯化合物及其混合物组成的组中的至少一种的结构单元的聚碳酸酯 。 在另一个实施方案中，本发明是一种制备聚碳酸酯的方法，该聚碳酸酯包含衍生自至少一种二元酚的结构单元和至少一种选自由含草酰替苯的化合物，含草酸酯化合物及其混合物组成的组， 其包括在反应条件下使至少一种二元酚，碳酸酯前体和选自由含草酰替苯的化合物，含草酸酯化合物及其混合物中的至少一种接触的步骤。 在另一个实施方案中，本发明是包含含有草酰替苯胺结构单元的聚碳酸酯的制品。 在另一个实施方案中，本发明是一种制备包含对称或不对称的草酰替苯胺的二元酚的方法，其包括使至少一种带有羟基的芳族胺与草酸二芳基酯或带有烷基的二烷基酯的烷基基团接触的步骤， 至少一个吸电子基团。 在另一个实施方案中，本发明是一种制备含草酸羟基的一元酚的方法，其包括使带有羟基的芳族胺与草酸二芳基酯或带有烷基的草酸二烷基酯接触的步骤，每个烷基取代有至少一个电子 - 退出组。