摘要:
This invention is concerned with a ruthenium-iodo-optically active bidentate phosphine complex of the formula (I):[Ru--(I).sub.q --(T.sup.1).sub.n (SOL).sub.r (L)].sub.m (T.sup.2).sub.p (I).sub.s (I)wherein T.sup.1 represents a carboxylic acid anion, SOL represents a polar solvent, L represents an optically active bidentate phosphine ligand, T.sup.2 represents an anion different from halogen atom anions and carboxylic acid anions, n denotes 0 or 1, r denotes 0, 3 or 4, m denotes 1 or 2, q denotes 0 or 1, or where m is 2, q may represent 1 or 1.5, p denotes 0 or 1, and s denotes 0, 1 or 2 is prepared. Said phosphine complex is usefull as an efficient catalyst for asymmetrically hydrogenating 4-methylene-2-oxetanone into optically active 4-methyl-2-oxetanone.
摘要:
An optically active compound which itself generally exhibits no antiferroelectric liquid crystal phase, but which can be added to an antiferroelectric liquid crystal or composition thereof having a high threshold voltage to reduce the threshold voltage of the resulting composition. Also disclosed is an antiferroelectric liquid crystal composition containing the optically active compound, a process for reducing the threshold voltage of an antiferroelectric liquid crystal composition, a process for producing the optically active compound, and a process for producing an optically active carboxylic acid as an intermediate.
摘要:
A phenothiazine or phenoxazine derivative represented by the following general formula (1), a charge-transporting material comprising the derivative, and an electrophotographic photoreceptor containing the charge-transporting material are disclosed. The charge-transporting material has good solubility in binder polymers, satisfactory sensitivity, and a low residual potential In general formula (1) Ar.sup.1 and Ar.sup.2 may be the same or different and each represents an optionally substituted aryl group; R.sup.1 and R.sup.2 may be the same or different and each represents a hydrogen atom, a lower alkyl group, or an optionally substituted aryl group; R.sup.3 represents a lower alkyl group, an alicyclic hydrocarbon group having 5 to 7 carbon atoms, an optionally substituted aryl group, or an optionally substituted aralkyl group; X represents a sulfur atom or an oxygen atom; and n and m each represents an integer of 0 or 1.
摘要翻译:公开了由以下通式(1)表示的吩噻嗪或吩恶嗪衍生物,包含该衍生物的电荷输送材料和含有电荷输送材料的电子照相感光体。 电荷输送材料在粘合剂聚合物中具有良好的溶解性,令人满意的灵敏度和低的残余电位。通式(1)Ar 1和Ar 2可以相同或不同,表示任选取代的芳基; R 1和R 2可以相同或不同,各自表示氢原子,低级烷基或任意取代的芳基; R3表示低级烷基,碳原子数5〜7的脂环族烃基,可以具有取代基的芳基或任意取代的芳烷基; X表示硫原子或氧原子; n和m各自表示0或1的整数。
摘要:
A triphenylamine derivative, represented by the following general formula (1): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 each represents a hydrogen atom, a lower alkyl group, an alkoxy group, a halogen atom or an aryl group which may have a substituent group; and m and n each represents 0 or 1.
摘要:
A charge transporting material high in solubility in a binder polymer and having high carrier mobility is disclosed, which contains a carbazole derivative represented by the following general formula (1): ##STR1## wherein Ar.sup.1 and Ar.sup.2, which may be the same or different, each represents an aryl group which may have a substituent group; R.sup.1 and R.sup.2, which may be the same or different, each represents a lower alkyl group or an aryl group which may have a substituent group; R.sup.3 represents a lower alkyl group, an alicyclic alkyl group having 5 to 7 carbon atoms, an aryl group which may have a substituent group, or an aralkyl group which may have a substituent group; and m and n each represents an integer of 0 or 1. An electrophotographic photoreceptor containing the charge transporting material is also disclosed.
摘要翻译:公开了含有由下列通式(1)表示的咔唑衍生物的在粘合剂聚合物中溶解度高且载流子迁移率高的电荷输送材料:其中Ar 1和Ar 2可以相同 各自表示可以具有取代基的芳基; R 1和R 2可以相同或不同,表示可以具有取代基的低级烷基或芳基; R3表示低级烷基,具有5〜7个碳原子的脂环族烷基,可具有取代基的芳基或可具有取代基的芳烷基; m和n各自表示0或1的整数。还公开了含有电荷输送材料的电子照相感光体。
摘要:
A triphenylamine derivative, a charge-transporting material comprising the triphenylamine derivative, and an electrophotographic photoreceptor containing a charge-transporting layer comprising the triphenylamine derivative are disclosed, wherein the triphenylamine derivative is represented by the following general formula (1): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, and R.sup.5 may be the same or different and each represents a hydrogen atom, a lower alkyl group, an alkoxy group, a halogen atom, or an aryl group which may have a substituent, or R.sup.1 and R.sup.2 and/or R.sup.3 and R.sup.4 may be taken together to form a ring, and n represents 0 or 1.
摘要:
An optically active compound represented by formula (I): ##STR1## wherein R.sup.1 represents an alkyl group having from 3 to 9 carbon atoms; R.sup.2 represents an alkyl group having from 3 to 7 carbon atoms; m and n each represent 1 or 2 provided that they do not simultaneously represent 1; and C.sup.*1 and C.sup.*2, both represent an optically active carbon atom, and a liquid crystal composition containing the same are disclosed. The compound exhibits chiral nematic and smectic phases and are excellent as a chiral dopant for ferroelectric liquid crystal compositions or nematic liquid crystal compositions.
摘要:
An electrophotographic photoreceptor is disclosed, comprising an electroconductive support having a light-sensitive layer containing a charge generating substance and a charge transporting substance, wherein said charge transporting substance is a 1,4-benzodithiafulvene derivative represented by formula (I): ##STR1## wherein R.sup.1 represents a lower alkyl group, a benzyl group, a naphthyl group, or a phenyl group which may contain a substituent; R.sup.2 represents a phenyl group which may contain a substituent or an N-alkyl-substituted carbazole group; R.sup.3 represents a hydrogen atom or a phenyl group which may contain a substituent; R.sup.4 represents a hydrogen atom, a lower alkyl group, a hydroxyl group, or an alkoxy group or an aryloxy group represented by OR.sup.5 ; R.sup.5 represents a lower alkyl group, a benzyl group, or a phenyl group which may contain a substituent; and n represents an integer of 0 or 1.
摘要:
A new type of non-volatile bistable liquid crystal device is disclosed. The device has substrates spaced apart by such a distance that the molecular arrangement of the liquid crystal moaterial is helical and is arranged such that the liquid crystal molecules can selectively take up either of two optically anisotropic stable conditions in dependence puon an applied electric field. The transition between the two stable conditions takes place via an intermediate conditon in which the liquid crystal molecules are reearranged in helical form and represent an optically isotropic condition.