Silicon-oxy-carbide glass method of preparation and articles
    53.
    发明授权
    Silicon-oxy-carbide glass method of preparation and articles 失效
    硅 - 碳化硅玻璃的制备方法和制品

    公开(公告)号:US5180694A

    公开(公告)日:1993-01-19

    申请号:US574879

    申请日:1990-08-30

    Abstract: Methyl silicone resins are pyrolized in a non-oxidizing atmosphere to form a translucent glass comprised of silicon, oxygen and carbon where silicon atoms are chemically bonded to carbon and oxygen atoms, but there are essentially no chemical bonds between carbon and oxygen atoms. The translucent silicon-oxy-carbide glasses of this invention resist devitrification and decomposition in oxidizing or reducing atmospheres at temperatures of about 1250.degree. C. or greater. Methods for forming silicon-oxy-carbide glass articles are disclosed, along with specific methods for forming silicon-oxy-carbide glass fibres, composites, and cellular structures.

    Abstract translation: 甲基硅氧烷树脂在非氧化性气氛中进行热解,以形成由硅,氧和碳组成的半透明玻璃,其中硅原子与碳和氧原子化学键合,但碳和氧原子之间基本上没有化学键。 本发明的半透明硅 - 碳化碳玻璃在约1250℃或更高的温度下,在氧化或还原气氛中抗失真和分解。 公开了形成硅 - 碳化硅玻璃制品的方法以及形成硅 - 碳化硅玻璃纤维,复合材料和蜂窝结构的具体方法。

    Polyalkoxysilyl-terminated polydiorganosiloxanes, methods for their
preparation, and room temperature vulcanizable compositions containing
them
    55.
    发明授权
    Polyalkoxysilyl-terminated polydiorganosiloxanes, methods for their preparation, and room temperature vulcanizable compositions containing them 失效
    聚烷氧基甲硅烷基封端的聚二有机硅氧烷,其制备方法和含有它们的室温可硫化组合物

    公开(公告)号:US4863992A

    公开(公告)日:1989-09-05

    申请号:US225992

    申请日:1988-07-29

    CPC classification number: C08G77/18 C08G77/08

    Abstract: Polyalkoxysilyl-terminated polydiorganosiloxanes which are relatively stable in viscosity over prolonged storage periods are prepared by endcapping a silanol-terminated polydiorganosiloxane in the presence of a catalytic amount of an acidic amine salt which subsequently decomposes to substantially inert products, preferably an amine salt of formic acid, and in the absence of silicon-nitrogen compounds and enoxysilanes normally used as catalyst quenchers and scavengers. The products are useful for the preparation of scavenger-free room temperature vulcanizable compositions, particularly when combined with certain N-alkoxy-silylalkyl-substituted compounds as adhesion promoters.

    Abstract translation: 在延长保存期间粘度相对稳定的聚烷氧基甲硅烷基封端的聚二有机硅氧烷通过在催化量的酸性胺盐存在下封端硅烷醇封端的聚二有机硅氧烷来制备,其随后分解成基本上惰性的产物,优选甲酸的胺盐 ,并且在没有通常用作催化剂猝灭剂和清除剂的硅氮化合物和烯氧硅烷的情况下。 该产品可用于制备无清除剂的室温可硫化组合物,特别是当与某些N-烷氧基 - 甲硅烷基烷基取代的化合物作为粘合促进剂组合时。

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