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51.发明授权Coal liquefaction process using soluble molybdenum-containing organophosphorodithioate catalyst 失效煤液化过程中使用可溶性含钼有机二硫代磷酸酯催化剂
公开(公告)号：US5246570A
公开(公告)日：1993-09-21
申请号：US865837
申请日：1992-04-09
IPC分类号： C10G1/08
CPC分类号： C10G1/086
摘要： A coal liquefaction process employing a first stage liquefaction step catalyzed by a soluble molybdenum-containing organophosphorodithioate catalyst is disclosed. In some embodiments, two consecutive liquefaction steps employ a molybdenum-containing organophosphorodithioate catalyst operating at a relatively high liquefaction temperature. In other embodiments, a second liquefaction process step operating at a relatively low temperature employs a hydrocracking catalyst to upgrade materials obtained from the first soluble catalyst liquefaction step. In some embodiments, an interstage gas separator removes gases such as carbon dioxide produced in the first liquefaction step from a partially liquefied mixture prior to further liquefying the mixture in the second liquefaction step.
摘要翻译： 公开了采用由可溶性含钼有机二硫代磷酸酯催化剂催化的第一阶段液化步骤的煤液化方法。 在一些实施方案中，两个连续的液化步骤使用在较高液化温度下操作的含钼有机二硫代磷酸酯催化剂。 在其它实施方案中，在较低温度下操作的第二液化工艺步骤使用加氢裂化催化剂来升级从第一可溶性催化剂液化步骤获得的材料。 在一些实施例中，级间气体分离器在第二液化步骤中进一步液化混合物之前从部分液化的混合物中除去在第一液化步骤中产生的二氧化碳等气体。
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公开(公告)号：US5151172A
公开(公告)日：1992-09-29
申请号：US695426
申请日：1991-05-03
IPC分类号： C10G45/54
CPC分类号： C10G45/54
摘要： A process and catalyust are provided for hydrogenation of a hydrocarbon feedstock consisting essentially of material boiling between about 150.degree. F. and about 700.degree. F. which comprises reacting the feedstock with hydrogen at hydrogenation conditions in the presence of a catalyst comprising from about 0.1% to about 2.0% by weight each of palladium and platinum and a support comprising mordenite. The process of the present invention provides substantially improved dearomatization performance, increased desulfurization and denitrogenation, increased distillate product cetane number, increased distllate volume expansion, and utilizes a more durable catalyst.
摘要翻译： 提供了一种方法和催化剂，用于氢化烃原料，其基本上由沸点在约150°F至约700°F之间的材料进行氢化，其包括在氢化条件下使原料与氢气在催化剂存在下反应，所述催化剂包含约0.1％ 至约2.0重量％的钯和铂，以及包含丝光沸石的载体。 本发明的方法提供了显着改进的脱芳构化性能，增加的脱硫和脱氮，增加的馏出物产品十六烷值，增加的二馏液体积膨胀，并且使用更耐用的催化剂。
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公开(公告)号：US5091490A
公开(公告)日：1992-02-25
申请号：US717903
申请日：1991-06-19
CPC分类号： C08F10/00
摘要： Silica supported high activity olefin polymerization catalysts, methods of producing the catalysts and methods of using the catalysts in the polymerization of olefins are provided. The methods of producing the catalysts each basically comprise contacting a particulate silica support impregnated with tungsten oxide with the soluble complex produced by heating a mixture of a metal dihalide with a transition metal compound to produce a solid, and then reacting the solid with an organoaluminum halide. The catalysts produced have improved productivities and are less soluble in polymerization media.
摘要翻译： 提供二氧化硅负载的高活性烯烃聚合催化剂，制备催化剂的方法和在烯烃聚合中使用催化剂的方法。 制备催化剂的方法基本上包括使浸渍有氧化钨的颗粒状二氧化硅载体与通过加热金属二卤化物与过渡金属化合物的混合物产生的可溶性络合物接触以制备固体，然后使固体与有机铝卤化物 。 所生产的催化剂具有改进的生产率，并且在聚合介质中的溶解性较差。
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公开(公告)号：US4834865A
公开(公告)日：1989-05-30
申请号：US160524
申请日：1988-02-26
IPC分类号： C10G65/10
CPC分类号： C10G65/10
摘要： Disclosed is a hydrocracking process employing a plurality of reaction zones wherein at least one reaction zone contains a small nominal size hydrocracking catalyst (10 to 16 U.S. Sieve mesh size) and wherein the catalyst situated upstream of the small nominal size hydrocracking has a particle size greater than the small nominal size hydrocracking catalyst.
摘要翻译： 公开了一种采用多个反应区的加氢裂化方法，其中至少一个反应区含有标称尺寸小的加氢裂化催化剂（10-16孔筛网尺寸），其中位于小标称尺寸加氢裂化上游的催化剂的粒径更大 比标称型小型加氢裂化催化剂。
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55.发明授权
公开(公告)号：US4824556A
公开(公告)日：1989-04-25
申请号：US212838
申请日：1988-06-29
摘要： A composition of matter is prepared by a process comprising the steps of impregnating a alumina-containing support material with a thiosulfate (preferably ammonium thiosulfate), drying the thus impregnated material, impregnating the dried material with a transition metal compound, drying and calcining the transition metal impregnated material. This composition of matter is used as catalyst composition for hydrogenating unsaturated hydrocarbon compounds, and as catalyst composition for hydrotreating hydrocarbon-containing feed streams (in particular heavy oils) which contain metal and sulfur compounds as impurities.In another embodiment, a hydrotreating process comprises contacting hydrocarbon-containing feed stream (in particular heavy oils), which contains compounds of sulfur and metals, in the presence of a fixed catalyst bed comprising (X) at least one layer of impregnated substantially spherical alumina-containing particles, which have been prepared by a process comprising the steps of impregnating a specific starting material with (NH.sub.4).sub.2 S.sub.2 O.sub.3 and then heating the thus impregnated material at about 500.degree.-900.degree. C. for improved crush strength retention. In a preferred embodiment, the fixed catalyst bed further comprises at least one layer (Y) of catalyst particles comprising a refractory inorganic carrier and at least one hydrogenation promoter. A composition of matter comprising the impregnated, spherical alumina-containing particles described above, and a process for preparing them are also provided.
摘要翻译： 通过包括以下步骤的方法制备物质组合物，所述方法包括用硫代硫酸盐（优选硫代硫酸铵）浸渍含氧化铝的载体材料，干燥如此浸渍的材料，用过渡金属化合物浸渍干燥的材料，干燥和煅烧过渡 金属浸渍材料。 该物质组合物用作用于氢化不饱和烃化合物的催化剂组合物，以及用作加氢处理含有金属和硫化合物作为杂质的含烃进料流（特别是重油）的催化剂组合物。 在另一个实施方案中，加氢处理方法包括在固定的催化剂床存在下使包含硫和金属化合物的含烃进料流（特别是重油）与含有（X）至少一层浸渍的基本上为球形的氧化铝 其通过包括以下步骤制备的方法制备，所述方法包括用（NH 4）2 S 2 O 3浸渍特定原料，然后在约500-900℃加热如此浸渍的材料，以改善压碎强度保持性。 在优选的实施方案中，固定催化剂床还包含至少一层包含耐火无机载体和至少一种氢化促进剂的催化剂颗粒层（Y）。 还提供了包含上述浸渍的含球形氧化铝颗粒的物质组合物及其制备方法。
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公开(公告)号：US4802974A
公开(公告)日：1989-02-07
申请号：US25299
申请日：1987-03-12
申请人： Simon G. Kukes , Jesse R. Harris
发明人： Simon G. Kukes , Jesse R. Harris
摘要： A hydrotreating process comprises contacting a substantially liquid hydrocarbon-containing feed stream, which contains compounds of sulfur and metals (preferably Ni and/or V), in the presence of a fixed catalyst bed comprising (a) at least one layer of impregnated substantially spherical alumina-containing particles which have been prepared by a process comprising the steps of impregnating specific starting material with at least one dissolved magnesium compound and then heating the thus impregnated material at about 500.degree.-900.degree. C. for improved crush strength retention. In a preferred embodiment, the fixed catalyst bed further comprises at least one layer (b) of catalyst particles comprising a refractory inorganic carrier and at least one hydrogenation promoter. A composition of matter comprising the impregnated, spherical alumina-containing particles described above, and a process for preparing them are also provided.
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公开(公告)号：US4797195A
公开(公告)日：1989-01-10
申请号：US160683
申请日：1988-02-26
CPC分类号： C10G65/10
摘要： Disclosed is a hydrocracking process wherein the feedstock is contacted in a first reaction zone with a first reaction zone catalyst comprising a nickel component and a molybdenum component deposed on a support consisting essentially of a refractory inorganic oxide. The effluent from the first reaction zone is then contacted in a second reaction zone with a second reaction zone catalyst comprising a nickel component and a tungsten component deposed on a support component consisting essentially of an alumina component and a crystalline molecular sieve component. The effluent from the second reaction zone effluent is then contacted in a third reaction zone with a third reaction zone catalyst comprising a cobalt component and a molybdenum component deposed on a support component comprising a silica-alumina component and a crystalline molecular sieve component.
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公开(公告)号：US4724069A
公开(公告)日：1988-02-09
申请号：US896916
申请日：1986-08-15
IPC分类号： C07F15/02 , B01J23/88 , B01J23/94 , C07F15/06 , C10G45/02 , C10G45/12 , C10G45/00 , C10G45/06
CPC分类号： C10G45/02
摘要： An additive comprising a metal naphthenate selected from the group consisting of cobalt naphthenate and iron naphthenate is mixed with a hydrocarbon-containing feed stream. The hydrocarbon-containing feed stream containing the additive is then contacted in a hydrofining process with a catalyst composition comprising a support selected from the group consisting of alumina, silica and silica-alumina and a promoter comprising at least one metal selected from Group VIB, Group VIIB and Group VIII of the Periodic Table. The introduction of the inventive additive may be commenced when the catalyst is new, partially deactivated or spent with a beneficial result occuring in each case.
摘要翻译： 将包含选自环烷酸钴和环烷酸铁的环烷酸金属的添加剂与含烃进料流混合。 然后将含有添加剂的含烃进料物流在加氢精制过程中与包含选自氧化铝，二氧化硅和二氧化硅 - 氧化铝的载体的催化剂组合物和包含至少一种选自组VIB的金属的组合物 VIIB和第八期。 本发明添加剂的引入可以在催化剂是新的，部分失活的或在每种情况下产生有益结果的情况下消耗或开始。
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公开(公告)号：US4652361A
公开(公告)日：1987-03-24
申请号：US878558
申请日：1986-06-26
申请人： Simon G. Kukes , Stephen L. Parrott
发明人： Simon G. Kukes , Stephen L. Parrott
CPC分类号： B01J21/066 , B01J23/00 , B01J23/10 , C10G45/04
摘要： A composition of matter consisting essentially of alumina and at least one compound (preferably oxide) of yttrium and/or zirconium is provided and is employed as a catalyst in the hydrotreating of a substantially liquid hydrocarbon containing feed stream (particularly a heavy oil) which also contains compounds of nickel, vanadium and sulfur. The preferred preparation of the catalyst compositions of this invention comprises at least one impregnating step using a solution containing at least one aluminum compound, which is at least partially converted to aluminum oxide in a subsequent calcining step.
摘要翻译： 提供了基本上由氧化铝和至少一种钇和/或锆化合物（优选氧化物）组成的物质组合物，并且用作加氢处理基本上液体的含烃进料流（特别是重油）中的催化剂， 含有镍，钒和硫的化合物。 本发明的催化剂组合物的优选制备方法包括使用至少一种铝化合物的溶液进行至少一次浸渍步骤，该化合物在随后的煅烧步骤中至少部分转化为氧化铝。
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公开(公告)号：US4629719A
公开(公告)日：1986-12-16
申请号：US679344
申请日：1984-12-07
申请人： Simon G. Kukes , Robert L. Banks
发明人： Simon G. Kukes , Robert L. Banks
摘要： An improved olefin disproportionation catalyst produced by contacting an inorganic refractory oxide containing a catalytic amount of molybdenum oxide with a promoting amount of elemental metals of the group consisting of tin and magnesium.
摘要翻译： 一种改进的烯烃歧化催化剂，其通过使包含催化量的氧化钼的无机耐火氧化物与促进量的由锡和镁组成的组的元素金属接触而制备。
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