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公开(公告)号：US4797195A
公开(公告)日：1989-01-10
申请号：US160683
申请日：1988-02-26
CPC分类号： C10G65/10
摘要： Disclosed is a hydrocracking process wherein the feedstock is contacted in a first reaction zone with a first reaction zone catalyst comprising a nickel component and a molybdenum component deposed on a support consisting essentially of a refractory inorganic oxide. The effluent from the first reaction zone is then contacted in a second reaction zone with a second reaction zone catalyst comprising a nickel component and a tungsten component deposed on a support component consisting essentially of an alumina component and a crystalline molecular sieve component. The effluent from the second reaction zone effluent is then contacted in a third reaction zone with a third reaction zone catalyst comprising a cobalt component and a molybdenum component deposed on a support component comprising a silica-alumina component and a crystalline molecular sieve component.
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公开(公告)号：US4971680A
公开(公告)日：1990-11-20
申请号：US287399
申请日：1988-12-20
IPC分类号： B01J23/888 , B01J29/16 , C10G47/16
CPC分类号： B01J23/888 , B01J29/166 , C10G47/16
摘要： A hydrocarbon conversion process is disclosed involving the hydrocracking of a catalytic cycle oil in the presence of a catalyst having a nickel component, a tungsten component, and a support component containing a crystalline molecular sieve material present in an amount ranging from about 25 to about 60 wt. % based on the weight of the support component wherein at least about 1 to about 80 wt. % of the sieve material is a gallosilicate, based on the total weight of the sieve component.
摘要翻译： 公开了一种烃转化方法，其涉及在具有镍组分，钨组分和含有结晶分子筛材料的载体组分的催化剂存在下催化循环油的加氢裂化，所述结晶分子筛材料的存在量为约25至约60 重量 基于支持组分的重量，其中至少约1至约80重量％ 基于筛组分的总重量，筛材料的百分比是硅酸盐。
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公开(公告)号：US4797196A
公开(公告)日：1989-01-10
申请号：US160680
申请日：1988-02-26
IPC分类号： C10G65/10
CPC分类号： C10G65/10
摘要： Disclosed is a hydrocracking process wherein the feedstock is first contacted with a first catalyst containing a nickel component and a tungsten component supported on a support containing alumina and a crystalline molecular sieve followed by subsequent contact with a second hydrocracking catalyst containing a cobalt component and a molybdenum component supported on a support containing silica-alumina and a crystalline molecular sieve and the first catalyst. This subsequent contact with the second and first catalysts is carried out either serially or in one step wherein the first and second catalysts are physically mixed.
摘要翻译： 公开了加氢裂化方法，其中原料首先与含有镍组分的第一催化剂和负载在含有氧化铝和结晶分子筛的载体上的钨组分接触，随后与含有钴组分和钼的第二加氢裂化催化剂接触 负载在含有二氧化硅 - 氧化铝和结晶分子筛和第一催化剂的载体上的组分。 随后与第二和第一催化剂的接触是连续地或一个步骤进行，其中第一和第二催化剂被物理混合。
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公开(公告)号：US4834865A
公开(公告)日：1989-05-30
申请号：US160524
申请日：1988-02-26
IPC分类号： C10G65/10
CPC分类号： C10G65/10
摘要： Disclosed is a hydrocracking process employing a plurality of reaction zones wherein at least one reaction zone contains a small nominal size hydrocracking catalyst (10 to 16 U.S. Sieve mesh size) and wherein the catalyst situated upstream of the small nominal size hydrocracking has a particle size greater than the small nominal size hydrocracking catalyst.
摘要翻译： 公开了一种采用多个反应区的加氢裂化方法，其中至少一个反应区含有标称尺寸小的加氢裂化催化剂（10-16孔筛网尺寸），其中位于小标称尺寸加氢裂化上游的催化剂的粒径更大 比标称型小型加氢裂化催化剂。
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公开(公告)号：US4875991A
公开(公告)日：1989-10-24
申请号：US328576
申请日：1989-03-27
摘要： Disclosed is a hydrocracking process wherein the feedstock is contacted in a first reaction zone with a first reaction zone catalyst comprising a nickel component and a tungsten component deposed on a support component consisting essentially of an alumina component and a crystalline molecular sieve component. The effluent from the first reaction zone effluent is then contacted in a second reaction zone with a second reaction zone catalyst comprising a molybdenum component deposed on a support component comprising an alumina component and a crystalline molecular sieve component.
摘要翻译： 公开了一种加氢裂化方法，其中原料在第一反应区与第一反应区催化剂接触，所述第一反应区催化剂包含镍组分和钨组分，该组分和钨组分沉积在基本上由氧化铝组分和结晶分子筛组分组成的载体组分上。 然后将来自第一反应区流出物的流出物与第二反应区催化剂接触，第二反应区催化剂包含沉积在包含氧化铝组分和结晶分子筛组分的载体组分上的钼组分。
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公开(公告)号：US5322829A
公开(公告)日：1994-06-21
申请号：US31656
申请日：1993-03-15
申请人： David C. Artes , Simon G. Kukes
发明人： David C. Artes , Simon G. Kukes
CPC分类号： C10G45/08 , B01J23/755 , B01J23/85 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J35/108
摘要： A catalyst and process are disclosed for upgrading heavy feedstocks such as resid. The catalyst comprises a porous inorganic oxide support having an incremental pore volume maximum at a pore radius greater than 50 Angstroms bearing between 0.1 to 5.0 weight percent nickel and having at least 0.4 cc/g of pores having a radius less than 125 Angstroms. An ebullated bed hydroconversion process employing the catalyst also is disclosed.
摘要翻译： 公开了一种催化剂和方法，用于改质重质原料如渣油。 该催化剂包括多孔无机氧化物载体，其具有在孔半径大于50埃的0.1至5.0重量％的镍之间并具有至少0.4cc / g半径小于125埃的孔的增量孔体积最大值。 还公开了采用催化剂的沸腾床加氢转化方法。
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公开(公告)号：US4885080A
公开(公告)日：1989-12-05
申请号：US198767
申请日：1988-05-25
IPC分类号： C10G65/16
CPC分类号： C10G65/16
摘要： A heavy crude oil is fractionated into at least three liquid fractions which include a distillate fraction boiling in the 400.degree. F.-650.degree. F. range and a 650.degree. F.+ boiling range residuum. The distillate cut is hydrodesulfurized and the residuum is hydrodemetallized. The cuts thus hydrotreated, and at least a part of the third liquid fraction, are then combined to form an upgraded synthetic crude oil of relatively low sulfur content and relatively low vanadium and nickel content.
摘要翻译： 重质原油分馏成至少三种液体馏分，其中包括在400°F-650°F范围内沸腾的馏出物馏分和650°F +沸点残渣。 蒸馏馏分加氢脱硫，渣油加氢脱金属。 然后将如此加氢处理的切口和至少一部分第三液体馏分组合以形成相对低的硫含量和相对低的钒和镍含量的升级的合成原油。
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公开(公告)号：US4831004A
公开(公告)日：1989-05-16
申请号：US212843
申请日：1988-06-29
摘要： A composition of matter is prepared by a process comprising the steps of impregnating a alumina-containing support material with a thiosulfate (preferably ammonium thiosulfate), drying the thus impregnated material, impregnating the dried material with a transition metal compound, drying and calcining the transition metal impregnated material. This composition of matter is used as catalyst composition for hydrogenating unsaturated hydrocarbon compounds, and as catalyst composition for hydrotreating hydrocarbon-containing feed streams (in particular heavy oils) which contain metal and sulfur compounds as impurities.In another embodiment, a hydrotreating process comprises contacting hydrocarbon-containing feed stream (in particular heavy oils), which contains compounds of sulfur and metals, in the presence of a fixed catalyst bed comprising (X) at least one layer of impregnated substantially spherical alumina-containing particles, which have been prepared by a process comprising the steps of impregnating a specific starting material with (NH.sub.4).sub.2 S.sub.2 O.sub.3 and then heating the thus impregnated material at about 500.degree.-900.degree. C. for improved crush strength retention. In a preferred embodiment, the fixed catalyst bed further comprises at least one layer (Y) of catalyst particles comprising a refractory inorganic carrier and at least one hydrogenation promoter. A composition of matter comprising the impregnated, spherical alumina-containing particles described above, and a process for preparing them are also provided.
摘要翻译： 通过包括以下步骤的方法制备物质组合物，所述方法包括用硫代硫酸盐（优选硫代硫酸铵）浸渍含氧化铝的载体材料，干燥如此浸渍的材料，用过渡金属化合物浸渍干燥的材料，干燥和煅烧过渡 金属浸渍材料。 该物质组合物用作用于氢化不饱和烃化合物的催化剂组合物，以及用作加氢处理含有金属和硫化合物作为杂质的含烃进料流（特别是重油）的催化剂组合物。 在另一个实施方案中，加氢处理方法包括在固定的催化剂床存在下使包含硫和金属化合物的含烃进料流（特别是重油）与含有（X）至少一层浸渍的基本上为球形的氧化铝 其通过包括以下步骤制备的方法制备，所述方法包括用（NH 4）2 S 2 O 3浸渍特定原料，然后在约500-900℃加热如此浸渍的材料，以改善压碎强度保持性。 在优选的实施方案中，固定催化剂床还包含至少一层包含耐火无机载体和至少一种氢化促进剂的催化剂颗粒层（Y）。 还提供了包含上述浸渍的含球形氧化铝颗粒的物质组合物及其制备方法。
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公开(公告)号：US4828683A
公开(公告)日：1989-05-09
申请号：US011989
申请日：1987-02-06
申请人： Lloyd E. Gardner , Simon G. Kukes
发明人： Lloyd E. Gardner , Simon G. Kukes
摘要： A hydrotreating process comprises contacting a substantially liquid hydrocarbon-containing feed stream, which contains compounds of sulfur and metals (preferably Ni and/or V), in the presence of a fixed catalyst bed comprising at least one layer of substantially spherical alumina-containing particles which have been prepared by heating a specific starting material at about 500.degree.-900.degree. C. for improved crush strength retention. In a preferred embodiment, the fixed catalyst bed further comprises at least one layer (b) of catalyst particles comprising a refractory inorganic carrier and at least one hydrogenation promoter. A fixed catalyst bed comprising layers (a) and (b) is provided.
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10.发明授权Treated alumina material for fixed hydrofining beds and process for its preparation 失效用于固定加氢精制床的处理氧化铝材料及其制备方法
公开(公告)号：US4820676A
公开(公告)日：1989-04-11
申请号：US199744
申请日：1988-05-26
CPC分类号： C10G45/04 , B01J21/04 , B01J35/00 , B01J35/108 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1042
摘要： A process for preparing impregnated substantially spherical alumina-containing particles comprises the steps of impregnating specific starting material with (NH.sub.4).sub.2 SO.sub.4 and then heating the thus impregnated material at about 500.degree.-900.degree. C. for improved crush strength retention. In a preferred embodiment a fixed catalyst bed comprises at least one layer of the alumina-containing particles and at least one layer of catalyst particles comprising a refractory inorganic carrier and at least one hydrogenation promoter.
摘要翻译： 制备浸渍的基本上呈球形的含氧化铝颗粒的方法包括以下步骤：用（NH 4）2 SO 4浸渍特定原料，然后在约500-900℃下加热所浸渍的材料，以改善压碎强度保留。 在优选的实施方案中，固定的催化剂床包括至少一层含氧化铝的颗粒和至少一层包含耐火无机载体和至少一种氢化促进剂的催化剂颗粒层。
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