Coal liquefaction process using soluble molybdenum-containing
organophosphorodithioate catalyst
    1.
    发明授权
    Coal liquefaction process using soluble molybdenum-containing organophosphorodithioate catalyst 失效
    煤液化过程中使用可溶性含钼有机二硫代磷酸酯催化剂

    公开(公告)号:US5246570A

    公开(公告)日:1993-09-21

    申请号:US865837

    申请日:1992-04-09

    IPC分类号: C10G1/08

    CPC分类号: C10G1/086

    摘要: A coal liquefaction process employing a first stage liquefaction step catalyzed by a soluble molybdenum-containing organophosphorodithioate catalyst is disclosed. In some embodiments, two consecutive liquefaction steps employ a molybdenum-containing organophosphorodithioate catalyst operating at a relatively high liquefaction temperature. In other embodiments, a second liquefaction process step operating at a relatively low temperature employs a hydrocracking catalyst to upgrade materials obtained from the first soluble catalyst liquefaction step. In some embodiments, an interstage gas separator removes gases such as carbon dioxide produced in the first liquefaction step from a partially liquefied mixture prior to further liquefying the mixture in the second liquefaction step.

    摘要翻译: 公开了采用由可溶性含钼有机二硫代磷酸酯催化剂催化的第一阶段液化步骤的煤液化方法。 在一些实施方案中,两个连续的液化步骤使用在较高液化温度下操作的含钼有机二硫代磷酸酯催化剂。 在其它实施方案中,在较低温度下操作的第二液化工艺步骤使用加氢裂化催化剂来升级从第一可溶性催化剂液化步骤获得的材料。 在一些实施例中,级间气体分离器在第二液化步骤中进一步液化混合物之前从部分液化的混合物中除去在第一液化步骤中产生的二氧化碳等气体。

    Resid hydroprocessing method
    3.
    发明授权
    Resid hydroprocessing method 失效
    余热处理方法

    公开(公告)号:US5489375A

    公开(公告)日:1996-02-06

    申请号:US255647

    申请日:1994-06-08

    IPC分类号: C10G47/02 C10G47/26

    CPC分类号: C10G47/02 C10G47/26

    摘要: Hydroconversion processes employing 2,4-heteroatom-substituted-molybdena-3,3-dioxocyclopentane hydro-conversion catalysts are disclosed. In some embodiments, inexpensive bulk catalysts in accordance with the present invention are synthesized from bulk triglyceridic epoxides or fatty acids.

    摘要翻译: 公开了采用2,4-杂原子取代的钼 - 3,3-二氧代环戊烷氢转化催化剂的加氢转化方法。 在一些实施方案中,根据本发明的廉价的本体催化剂由块状甘油三酯环氧化物或脂肪酸合成。

    Process for demetallizing and desulfurizing heavy crude oil
    5.
    发明授权
    Process for demetallizing and desulfurizing heavy crude oil 失效
    重质原油脱金属脱硫工艺

    公开(公告)号:US4885080A

    公开(公告)日:1989-12-05

    申请号:US198767

    申请日:1988-05-25

    IPC分类号: C10G65/16

    CPC分类号: C10G65/16

    摘要: A heavy crude oil is fractionated into at least three liquid fractions which include a distillate fraction boiling in the 400.degree. F.-650.degree. F. range and a 650.degree. F.+ boiling range residuum. The distillate cut is hydrodesulfurized and the residuum is hydrodemetallized. The cuts thus hydrotreated, and at least a part of the third liquid fraction, are then combined to form an upgraded synthetic crude oil of relatively low sulfur content and relatively low vanadium and nickel content.

    摘要翻译: 重质原油分馏成至少三种液体馏分,其中包括在400°F-650°F范围内沸腾的馏出物馏分和650°F +沸点残渣。 蒸馏馏分加氢脱硫,渣油加氢脱金属。 然后将如此加氢处理的切口和至少一部分第三液体馏分组合以形成相对低的硫含量和相对低的钒和镍含量的升级的合成原油。

    Impregnated alumina-containing material
    6.
    发明授权
    Impregnated alumina-containing material 失效
    浸渍的含氧化铝的材料

    公开(公告)号:US4831004A

    公开(公告)日:1989-05-16

    申请号:US212843

    申请日:1988-06-29

    IPC分类号: B01J37/20 C10G45/04

    CPC分类号: C10G45/04 B01J37/20

    摘要: A composition of matter is prepared by a process comprising the steps of impregnating a alumina-containing support material with a thiosulfate (preferably ammonium thiosulfate), drying the thus impregnated material, impregnating the dried material with a transition metal compound, drying and calcining the transition metal impregnated material. This composition of matter is used as catalyst composition for hydrogenating unsaturated hydrocarbon compounds, and as catalyst composition for hydrotreating hydrocarbon-containing feed streams (in particular heavy oils) which contain metal and sulfur compounds as impurities.In another embodiment, a hydrotreating process comprises contacting hydrocarbon-containing feed stream (in particular heavy oils), which contains compounds of sulfur and metals, in the presence of a fixed catalyst bed comprising (X) at least one layer of impregnated substantially spherical alumina-containing particles, which have been prepared by a process comprising the steps of impregnating a specific starting material with (NH.sub.4).sub.2 S.sub.2 O.sub.3 and then heating the thus impregnated material at about 500.degree.-900.degree. C. for improved crush strength retention. In a preferred embodiment, the fixed catalyst bed further comprises at least one layer (Y) of catalyst particles comprising a refractory inorganic carrier and at least one hydrogenation promoter. A composition of matter comprising the impregnated, spherical alumina-containing particles described above, and a process for preparing them are also provided.

    摘要翻译: 通过包括以下步骤的方法制备物质组合物,所述方法包括用硫代硫酸盐(优选硫代硫酸铵)浸渍含氧化铝的载体材料,干燥如此浸渍的材料,用过渡金属化合物浸渍干燥的材料,干燥和煅烧过渡 金属浸渍材料。 该物质组合物用作用于氢化不饱和烃化合物的催化剂组合物,以及用作加氢处理含有金属和硫化合物作为杂质的含烃进料流(特别是重油)的催化剂组合物。 在另一个实施方案中,加氢处理方法包括在固定的催化剂床存在下使包含硫和金属化合物的含烃进料流(特别是重油)与含有(X)至少一层浸渍的基本上为球形的氧化铝 其通过包括以下步骤制备的方法制备,所述方法包括用(NH 4)2 S 2 O 3浸渍特定原料,然后在约500-900℃加热如此浸渍的材料,以改善压碎强度保持性。 在优选的实施方案中,固定催化剂床还包含至少一层包含耐火无机载体和至少一种氢化促进剂的催化剂颗粒层(Y)。 还提供了包含上述浸渍的含球形氧化铝颗粒的物质组合物及其制备方法。

    Hydrofining employing a support material for fixed beds
    7.
    发明授权
    Hydrofining employing a support material for fixed beds 失效
    加氢精制采用固定床支撑材料

    公开(公告)号:US4828683A

    公开(公告)日:1989-05-09

    申请号:US011989

    申请日:1987-02-06

    CPC分类号: B01J32/00 C10G65/04

    摘要: A hydrotreating process comprises contacting a substantially liquid hydrocarbon-containing feed stream, which contains compounds of sulfur and metals (preferably Ni and/or V), in the presence of a fixed catalyst bed comprising at least one layer of substantially spherical alumina-containing particles which have been prepared by heating a specific starting material at about 500.degree.-900.degree. C. for improved crush strength retention. In a preferred embodiment, the fixed catalyst bed further comprises at least one layer (b) of catalyst particles comprising a refractory inorganic carrier and at least one hydrogenation promoter. A fixed catalyst bed comprising layers (a) and (b) is provided.

    Hydrotreating process employing a pretreated alumina containing material
    9.
    发明授权
    Hydrotreating process employing a pretreated alumina containing material 失效
    使用预处理的含氧化铝材料的加氢处理方法

    公开(公告)号:US4778587A

    公开(公告)日:1988-10-18

    申请号:US52096

    申请日:1987-05-20

    IPC分类号: C10G45/04

    CPC分类号: C10G45/04

    摘要: A composition of matter is prepared by a process comprising the steps of impregnating a alumina-containing support material with a thiocyanate (preferably ammonium thiocyanate), drying the thus impregnated material, impregnating the dried material with a transition metal compound, drying and calcining the transition metal impregnated material. This composition of matter is used as catalyst composition for hydrotreating of hydrocarbon-containing feed streams (in particular heavy oils) which contain metal and sulfur compounds as impurities.In another embodiment, a hydrotreating process comprises contacting hydrocarbon-containing feed stream (in particular heavy oils), which contains compounds of sulfur and metals, in the presence of a fixed catalyst bed comprising (X) at least one layer of impregnated substantially spherical alumina-containing particles which have been prepared by a process comprising the steps of impregnating specific starting material with NH.sub.4 SCN and then heating the thus impregnated material at about 500.degree.-900.degree. C. for improved crush strength retention. In a preferred embodiment, the fixed catalyst bed further comprises at least one layer (Y) of catalyst particles comprising a refractory inorganic carrier and at least one hydrogenation promoter. A composition of matter comprising the impregnated, spherical alumina-containing particles described above, and a process for preparing them are also provided.

    摘要翻译: 通过包括以下步骤的方法制备物质组合物,所述方法包括用硫氰酸盐(优选硫氰酸铵)浸渍含氧化铝的载体材料,干燥所浸渍的材料,用过渡金属化合物浸渍干燥的材料,干燥和煅烧过渡 金属浸渍材料。 该物质组合物用作用于加氢处理含有金属和硫化合物作为杂质的含烃进料流(特别是重油)的催化剂组合物。 在另一个实施方案中,加氢处理方法包括在固定的催化剂床存在下使包含硫和金属化合物的含烃进料流(特别是重油)与含有(X)至少一层浸渍的基本上为球形的氧化铝 通过包括以下步骤制备的颗粒,所述方法包括以下步骤:用NH 4 SCN浸渍特定原料,然后在约500-900℃下加热所浸渍的材料,以改善压碎强度保持性。 在优选的实施方案中,固定催化剂床还包含至少一层包含耐火无机载体和至少一种氢化促进剂的催化剂颗粒层(Y)。 还提供了包含上述浸渍的含球形氧化铝颗粒的物质组合物及其制备方法。