摘要:
A coal liquefaction process employing a first stage liquefaction step catalyzed by a soluble molybdenum-containing organophosphorodithioate catalyst is disclosed. In some embodiments, two consecutive liquefaction steps employ a molybdenum-containing organophosphorodithioate catalyst operating at a relatively high liquefaction temperature. In other embodiments, a second liquefaction process step operating at a relatively low temperature employs a hydrocracking catalyst to upgrade materials obtained from the first soluble catalyst liquefaction step. In some embodiments, an interstage gas separator removes gases such as carbon dioxide produced in the first liquefaction step from a partially liquefied mixture prior to further liquefying the mixture in the second liquefaction step.
摘要:
2,4-Heteroatom-substituted-molybdena-3,3-dioxocyclopentane hydro-conversion catalysts are disclosed. In some embodiments, inexpensive bulk catalysts in accordance with the present invention are synthesized from bulk triglyceridic epoxides or fatty acids.
摘要:
Hydroconversion processes employing 2,4-heteroatom-substituted-molybdena-3,3-dioxocyclopentane hydro-conversion catalysts are disclosed. In some embodiments, inexpensive bulk catalysts in accordance with the present invention are synthesized from bulk triglyceridic epoxides or fatty acids.
摘要:
A catalyst and process are disclosed for upgrading heavy feedstocks such as resid. The catalyst comprises a porous inorganic oxide support having an incremental pore volume maximum at a pore radius greater than 50 Angstroms bearing between 0.1 to 5.0 weight percent nickel and having at least 0.4 cc/g of pores having a radius less than 125 Angstroms. An ebullated bed hydroconversion process employing the catalyst also is disclosed.
摘要:
A heavy crude oil is fractionated into at least three liquid fractions which include a distillate fraction boiling in the 400.degree. F.-650.degree. F. range and a 650.degree. F.+ boiling range residuum. The distillate cut is hydrodesulfurized and the residuum is hydrodemetallized. The cuts thus hydrotreated, and at least a part of the third liquid fraction, are then combined to form an upgraded synthetic crude oil of relatively low sulfur content and relatively low vanadium and nickel content.
摘要:
A composition of matter is prepared by a process comprising the steps of impregnating a alumina-containing support material with a thiosulfate (preferably ammonium thiosulfate), drying the thus impregnated material, impregnating the dried material with a transition metal compound, drying and calcining the transition metal impregnated material. This composition of matter is used as catalyst composition for hydrogenating unsaturated hydrocarbon compounds, and as catalyst composition for hydrotreating hydrocarbon-containing feed streams (in particular heavy oils) which contain metal and sulfur compounds as impurities.In another embodiment, a hydrotreating process comprises contacting hydrocarbon-containing feed stream (in particular heavy oils), which contains compounds of sulfur and metals, in the presence of a fixed catalyst bed comprising (X) at least one layer of impregnated substantially spherical alumina-containing particles, which have been prepared by a process comprising the steps of impregnating a specific starting material with (NH.sub.4).sub.2 S.sub.2 O.sub.3 and then heating the thus impregnated material at about 500.degree.-900.degree. C. for improved crush strength retention. In a preferred embodiment, the fixed catalyst bed further comprises at least one layer (Y) of catalyst particles comprising a refractory inorganic carrier and at least one hydrogenation promoter. A composition of matter comprising the impregnated, spherical alumina-containing particles described above, and a process for preparing them are also provided.
摘要翻译:通过包括以下步骤的方法制备物质组合物,所述方法包括用硫代硫酸盐(优选硫代硫酸铵)浸渍含氧化铝的载体材料,干燥如此浸渍的材料,用过渡金属化合物浸渍干燥的材料,干燥和煅烧过渡 金属浸渍材料。 该物质组合物用作用于氢化不饱和烃化合物的催化剂组合物,以及用作加氢处理含有金属和硫化合物作为杂质的含烃进料流(特别是重油)的催化剂组合物。 在另一个实施方案中,加氢处理方法包括在固定的催化剂床存在下使包含硫和金属化合物的含烃进料流(特别是重油)与含有(X)至少一层浸渍的基本上为球形的氧化铝 其通过包括以下步骤制备的方法制备,所述方法包括用(NH 4)2 S 2 O 3浸渍特定原料,然后在约500-900℃加热如此浸渍的材料,以改善压碎强度保持性。 在优选的实施方案中,固定催化剂床还包含至少一层包含耐火无机载体和至少一种氢化促进剂的催化剂颗粒层(Y)。 还提供了包含上述浸渍的含球形氧化铝颗粒的物质组合物及其制备方法。
摘要:
A hydrotreating process comprises contacting a substantially liquid hydrocarbon-containing feed stream, which contains compounds of sulfur and metals (preferably Ni and/or V), in the presence of a fixed catalyst bed comprising at least one layer of substantially spherical alumina-containing particles which have been prepared by heating a specific starting material at about 500.degree.-900.degree. C. for improved crush strength retention. In a preferred embodiment, the fixed catalyst bed further comprises at least one layer (b) of catalyst particles comprising a refractory inorganic carrier and at least one hydrogenation promoter. A fixed catalyst bed comprising layers (a) and (b) is provided.
摘要:
A process for preparing impregnated substantially spherical alumina-containing particles comprises the steps of impregnating specific starting material with (NH.sub.4).sub.2 SO.sub.4 and then heating the thus impregnated material at about 500.degree.-900.degree. C. for improved crush strength retention. In a preferred embodiment a fixed catalyst bed comprises at least one layer of the alumina-containing particles and at least one layer of catalyst particles comprising a refractory inorganic carrier and at least one hydrogenation promoter.
摘要翻译:制备浸渍的基本上呈球形的含氧化铝颗粒的方法包括以下步骤:用(NH 4)2 SO 4浸渍特定原料,然后在约500-900℃下加热所浸渍的材料,以改善压碎强度保留。 在优选的实施方案中,固定的催化剂床包括至少一层含氧化铝的颗粒和至少一层包含耐火无机载体和至少一种氢化促进剂的催化剂颗粒层。
摘要:
A composition of matter is prepared by a process comprising the steps of impregnating a alumina-containing support material with a thiocyanate (preferably ammonium thiocyanate), drying the thus impregnated material, impregnating the dried material with a transition metal compound, drying and calcining the transition metal impregnated material. This composition of matter is used as catalyst composition for hydrotreating of hydrocarbon-containing feed streams (in particular heavy oils) which contain metal and sulfur compounds as impurities.In another embodiment, a hydrotreating process comprises contacting hydrocarbon-containing feed stream (in particular heavy oils), which contains compounds of sulfur and metals, in the presence of a fixed catalyst bed comprising (X) at least one layer of impregnated substantially spherical alumina-containing particles which have been prepared by a process comprising the steps of impregnating specific starting material with NH.sub.4 SCN and then heating the thus impregnated material at about 500.degree.-900.degree. C. for improved crush strength retention. In a preferred embodiment, the fixed catalyst bed further comprises at least one layer (Y) of catalyst particles comprising a refractory inorganic carrier and at least one hydrogenation promoter. A composition of matter comprising the impregnated, spherical alumina-containing particles described above, and a process for preparing them are also provided.
摘要:
A decomposable molybdenum compound selected from the group consisting of a mixture of a molybdenum dithiophosphate and a molybdenum carboxylate and a mixture of a molybdenum dithiocarbamate and a molybdenum carboxylate is disclosed. The decomposable molybdenum compound may be added, in a hydrovisbreaking process, to a hydrocarbon-containing feed stream prior to contacting the feed stream with hydrogen under suitable hydrovisbreaking conditions.