公开(公告)号：US06469217B2

公开(公告)日：2002-10-22

申请号：US09845888

申请日：2001-04-30

申请人： Satoru Saito ,  Haruyoshi Tatsu ,  Vera Grinevskaya

发明人： Satoru Saito ,  Haruyoshi Tatsu ,  Vera Grinevskaya

IPC分类号： C07C4311

CPC分类号： B01J31/0232 ,  B01J31/0209 ,  B01J2231/48 ,  C08G65/226 ,  C08G65/2639

摘要： The polymerization initiator-containing solution obtained by mixing a specific perfluorodicarboxylic acid fluoride (A) with CsF in an aprotic polar solvent with stirring to conduct reaction and thereby form a polymerization initiator (B) and then allowing the reaction solution to stand for not less than 72 hours at a temperature of 0 to 30° C. A polymerization initiator-containing solution comprises a specific polymerization initiator (B′) and an aprotic polar solvent. The process for preparing a perfluoropolyether comprises polymerizing hexafluoropropylene oxide in the presence of the polymerization initiator-containing solution.

摘要翻译： 通过在搅拌下将特定的全氟二羧酸氟化物（A）与CsF混合在搅拌下得到的含聚合引发剂的溶液进行反应，从而形成聚合引发剂（B），然后使反应溶液静置不少于 在0〜30℃的温度下72小时。含聚合引发剂的溶液包含特定的聚合引发剂（B'）和非质子极性溶剂。 制备全氟聚醚的方法包括在含聚合引发剂的溶液的存在下聚合六氟环氧丙烷。

公开(公告)号：US06174928B1

公开(公告)日：2001-01-16

申请号：US09277453

申请日：1999-03-26

申请人： Fumiyo Mizuide ,  Haruyoshi Tatsu ,  Sergey Vasilievich Sokolov ,  Michail Vasiliyevich Zhuravlev ,  Igor Vladimirovich Kokotin ,  Olga Viktorinovna Blagodatova

发明人： Fumiyo Mizuide ,  Haruyoshi Tatsu ,  Sergey Vasilievich Sokolov ,  Michail Vasiliyevich Zhuravlev ,  Igor Vladimirovich Kokotin ,  Olga Viktorinovna Blagodatova

IPC分类号： C08J1110

CPC分类号： C08J11/22 ,  C08F8/00 ,  C08G59/066 ,  C08G59/423 ,  C08J11/16 ,  C08J2327/12 ,  Y02W30/705 ,  Y02W30/706 ,  Y10S525/938 ,  C08F14/18

摘要： A fluorinated oligomer having COOH groups at both end and a &rgr;50° value of 1,000 to 10,000 is produced by swelling a fluorine rubber crosslinking product in an organic solvent, followed by decomposition in the presence of a base and a peroxide. The obtained fluorinated oligomer is soluble in solvent and thus easy to separate from fillers, etc., and can be effectively used as a chain-elongating agent for epoxy resin, isocyanate resin, oxazoline resin, etc.

摘要翻译： 通过在有机溶剂中使氟橡胶交联产物溶胀，然后在碱和过氧化物的存在下分解，得到在两端具有COOH基团并且rho50值为1,000至10,000的氟化低聚物。 所得氟化低聚物可溶于溶剂，易于与填料等分离，可有效用作环氧树脂，异氰酸酯树脂，恶唑啉树脂等的增链剂

公开(公告)号：US6160051A

公开(公告)日：2000-12-12

申请号：US315771

申请日：1999-05-20

申请人： Haruyoshi Tatsu ,  Yasuyoshi Hisamatsu

发明人： Haruyoshi Tatsu ,  Yasuyoshi Hisamatsu

IPC分类号： C08F293/00 ,  C08F261/06 ,  C08F283/06

CPC分类号： C08F261/06 ,  C08F214/22

摘要： A fluorine-containing copolymer having a solvent resistance and a cold resistance is produced by subjecting vinylidene fluoride and at least one of other fluorine-containing monomers to copolymerization reaction in the presence of a polyfluoropolyether having iodo groups at both terminals, represented by the following formula:I(R)pCF(CF.sub.3)O[CF.sub.2 CF(CF.sub.3)O]mRf[OCF(CF.sub.3)CF.sub.2 ]nOCF(CF.sub.3)(R)pIwherein Rf: perfluoroalkylene group of C.sub.2 -C.sub.6 ; R: alkylene group or polyfluoroalkylene group of C.sub.2 -C.sub.8 ; these alkylene groups may contain an ether bond or may be an alkyleneamide-containing or phenylene diamide-containing group; m+n: 20 or more; and p: 0 or 1. The copolymerization reaction is carried out preferably in the presence of a bromine-containing or iodine-containing monomer compound.

摘要翻译： 具有耐溶剂性和耐寒性的含氟共聚物通过在具有两端具有碘基的多氟聚醚的存在下，将下列式（1）表示的偏二氟乙烯和其它含氟单体中的至少一种进行共聚反应来制造： ：C（CF 3）O] m R f [OCF（CF 3）CF 2] n OCF（CF 3）（R）p I其中R 1表示C 1 -C 6的全氟亚烷基; R：C2-C8的亚烷基或多氟亚烷基; 这些亚烷基可以含有醚键，也可以是含有亚烷基酰胺或亚苯基二酰胺的基团。 m + n：20以上; 和p：0或1.共聚反应优选在含溴或含碘单体化合物的存在下进行。

公开(公告)号：US6150485A

公开(公告)日：2000-11-21

申请号：US248430

申请日：1999-02-11

申请人： Satoru Saito ,  Haruyoshi Tatsu

发明人： Satoru Saito ,  Haruyoshi Tatsu

IPC分类号： C08F214/22 ,  C08F214/24 ,  C08F214/18 ,  C08F214/12 ,  C08F214/20 ,  C08F214/26

CPC分类号： C08F214/24 ,  C08F214/222

摘要： Fluorine-containing elastomers produced through copolymerization reaction of vinylidene fluoride, tetrafluoroethylene, perfluoro(lower alkyl vinyl ether) and chlorotrifluoroethylene in the presence of a bromine-containing monomer compound and an iodine- and bromine-containing compound, where hexafluoropropene can be further copolymerized, have not only a distinguished resistance to amine-based additives and also distinguished low-temperature characteristic and engine oil resistance, and also a lower cost attained by reduced copolymer proportion of perfluoro(lower alkyl vinyl ether).

公开(公告)号：US6011129A

公开(公告)日：2000-01-04

申请号：US113736

申请日：1998-07-10

申请人： Satoru Saito ,  Haruyoshi Tatsu

发明人： Satoru Saito ,  Haruyoshi Tatsu

IPC分类号： C08F214/22 ,  C08F214/24 ,  C08F214/18 ,  C08F214/20 ,  C08F214/26 ,  C08F216/12

CPC分类号： C08F214/24 ,  C08F214/222

摘要： Fluorine-containing elastomers produced through copolymerization reaction of vinylidene fluoride, tetrafluoroethylene, perfluoro(lower alkyl vinyl ether) and chlorotrifluoroethylene in the presence of a bromine-containing monomer compound and an iodine- and bromine-containing compound, where hexafluoropropene can be further copolymerized, have not only a distinguished resistance to amine-based additives and also distinguished low-temperature characteristic and engine oil resistance, and also a lower cost attained by reduced copolymer proportion of perfluoro(lower alkyl vinyl ether).

摘要翻译： 在含溴单体化合物和含碘和溴的化合物存在下，可以进一步共聚六氟丙烯，通过偏二氟乙烯，四氟乙烯，全氟（低级烷基乙烯基醚）和氯三氟乙烯的共聚反应制备的含氟弹性体， 不仅对胺类添加剂具有显着的抵抗性，还具有显着的低温特性和发动机耐油性，而且通过降低全氟（低级烷基乙烯基醚）的共聚物比例也可以降低成本。

公开(公告)号：US05998564A

公开(公告)日：1999-12-07

申请号：US235966

申请日：1999-01-22

申请人： Takehiro Sonoi ,  Haruyoshi Tatsu ,  Satoru Saito ,  Sergei Rafailovich Sterlin ,  Victor Filippovich Cherstokov ,  Nina Ivanovna Delyagina

发明人： Takehiro Sonoi ,  Haruyoshi Tatsu ,  Satoru Saito ,  Sergei Rafailovich Sterlin ,  Victor Filippovich Cherstokov ,  Nina Ivanovna Delyagina

IPC分类号： C07C303/08 ,  C07C309/39 ,  C07C319/02 ,  C07C323/09 ,  C08K5/37 ,  C08K5/375 ,  C08L27/12 ,  C08G75/02

CPC分类号： C07C319/02 ,  C07C303/08 ,  C07C309/39 ,  C08K5/37 ,  C08K5/375

摘要： 2.2'-bis(3-mercaptophenyl)hexafluoropropane [bisthio-phenol AF] is obtained in good yield by chlorosulfonating 2.2'-bisphenylhexafluoropropane and reducing the thus quantitatively obtained 2,2'-bis(3-chlorosulfonylphenyl)-hexafluoropropane with zinc under acidic conditions and is effectively used as a cross-linking agent for a fluorine-containing elastomer having halogenophenyl groups as cross-linkable groups.

摘要翻译： 通过氯磺化2.2'-双苯基六氟丙烷得到2,2'-双（3-巯基苯基）六氟丙烷[双苯酚AF]，并在酸性条件下用锌还原定量得到的2,2'-双（3-氯磺酰基苯基） - 六氟丙烷 有效地用作具有卤代苯基作为交联基团的含氟弹性体的交联剂。

公开(公告)号：US5910552A

公开(公告)日：1999-06-08

申请号：US818819

申请日：1997-03-14

申请人： Satoru Saito ,  Haruyoshi Tatsu

发明人： Satoru Saito ,  Haruyoshi Tatsu

IPC分类号： C08F2/38 ,  C08F16/14 ,  C08F214/26 ,  C08F216/14 ,  C08K5/00 ,  C08L27/18 ,  C08F16/24

CPC分类号： C08K5/0025 ,  C08F214/262 ,  C08F216/1408 ,  C08F216/1416 ,  C08L27/18

摘要： A novel fluorine-containing copolymer elastomer having bromine groups as cross-linkable groups, which comprises about 45 to about 80% by mole of tetrafluoroethylene, about 50 to about 20% by mole of a perfluoro(vinylether) represented by the following general formula:CF.sub.2 .dbd.CFO(CF.sub.2).sub.2 (OCF.sub.2)nOCF.sub.3where n is an integer of 1 to 5, and about 0.2 to about 5% by mole of a bromine-containing unsaturated monomer compound, sum total being 100% by mole, gives vulcanization products having distinguished resistances to chemicals, low temperature and heat.

摘要翻译： 具有溴基作为可交联基团的新型含氟共聚物弹性体，其包含约45至约80摩尔％的四氟乙烯，约50至约20摩尔％的由以下通式表示的全氟（乙烯基醚）： CF 2 = CFO（CF 2）2（OCF 2）n OCF 3，其中n为1〜5的整数，以及约0.2〜约5摩尔％的含溴不饱和单体化合物，总和为100摩尔％，得到硫化产物 对化学品，耐低温和耐热性的抵抗力。

公开(公告)号：US5898054A

公开(公告)日：1999-04-27

申请号：US980236

申请日：1997-11-28

申请人： Satoru Saito ,  Kuniyoshi Kawasaki ,  Haruyoshi Tatsu

发明人： Satoru Saito ,  Kuniyoshi Kawasaki ,  Haruyoshi Tatsu

IPC分类号： C08F2/00 ,  C08F214/18 ,  C08F214/22

CPC分类号： C08F214/22 ,  C08F214/184 ,  C08F2438/01

摘要： A peroxide-vulcanizable fluorine-containing elastomer containing iodines as cross-linking sites, capable of producing vulcanization products having a distinguished heat resistance is produced by polymerization reaction of a fluorinated olefin having 2 to 8 carbon atoms in the presence of a diiodide compound represented by the following general formula:I--R--where R is a divalent fluorohydrocarbon group, chlorofluorohydrocarbon group or hydrocarbon group, having 2 to 8 carbon atoms, respectively, and 2,2-difluoroiodoethylene.

摘要翻译： 通过在二碘化合物的存在下，在具有2-8个碳原子的氟化烯烃存在下，通过聚合反应制备含有碘作为交联位点的可过氧化物硫化的含氟弹性体，其能够生产具有显着耐热性的硫化产物， 以下通式：IR-其中R是二价氟代烃基，分别具有2-8个碳原子的氯氟烃基或烃基和2,2-二氟碘乙烯。

公开(公告)号：US5891964A

公开(公告)日：1999-04-06

申请号：US675603

申请日：1996-07-03

申请人： Takehiro Sonoi ,  Haruyoshi Tatsu ,  Satoru Saito ,  Sergei Rafailovich Sterlin ,  Victor Filippovich Cherstokov ,  Nina Ivanovna Delyagina

发明人： Takehiro Sonoi ,  Haruyoshi Tatsu ,  Satoru Saito ,  Sergei Rafailovich Sterlin ,  Victor Filippovich Cherstokov ,  Nina Ivanovna Delyagina

IPC分类号： C07C303/08 ,  C07C309/39 ,  C07C319/02 ,  C07C323/09 ,  C08K5/37 ,  C08K5/375 ,  C08L27/12 ,  C08F8/34

CPC分类号： C07C319/02 ,  C07C303/08 ,  C07C309/39 ,  C08K5/37 ,  C08K5/375

摘要： 2,2 bis(3-mercaptophenyl)hexafluoropropane �bisthiophenol AF! is obtained in good yield by chlorosulfonating 2,2'-bisphenylhexafluoropropane and reducing the thus quantitatively obtained 2,2'-bis(3-chlorosulfonylphenyl)hexafluoropropane with zinc under acidic conditions and is effectively used as a cross-linking agent for a fluorine-containing elastomer having halogenophenyl groups as cross-linkable groups.

摘要翻译： 通过氯磺化2,2'-双苯基六氟丙烷获得2,2双（3-巯基苯基）六氟丙烷[双硫酚AF]，并在酸性条件下用锌还原定量得到的2,2'-双（3-氯磺酰基苯基）六氟丙烷 并且有效地用作具有卤代苯基作为可交联基团的含氟弹性体的交联剂。

公开(公告)号：US5717037A

公开(公告)日：1998-02-10

申请号：US732133

申请日：1996-10-18

申请人： Satoru Saito ,  Riichi Iwa ,  Haruyoshi Tatsu ,  Rondarev Dmitrii Stefanovich ,  Sokolov Sergey Vasilyevich ,  Berenblit Vsevolod Vulfovich

发明人： Satoru Saito ,  Riichi Iwa ,  Haruyoshi Tatsu ,  Rondarev Dmitrii Stefanovich ,  Sokolov Sergey Vasilyevich ,  Berenblit Vsevolod Vulfovich

IPC分类号： C07C231/02 ,  C07C235/06 ,  C07C253/20 ,  C07C255/10 ,  C07C255/13 ,  C08F8/18 ,  C08F116/12

CPC分类号： C07C231/02 ,  C07C255/10

摘要： A perfluoro unsaturated nitrile compound represented by the following general formula: CF.sub.2 .dbd.CFO(CF.sub.2)nOCF(CF.sub.3)CN is produced by reaction of chlorine or bromine to a perfluoro unsaturated carboxylic acid ester represented by the following general formula: CF.sub.2 .dbd.CFO(CF.sub.2)nOCF(CF.sub.3)COOR followed by reaction with ammonia, thereby converting the ester group to an acid amide group, and then conducting a dehydration reaction and a dehalogenation reaction of the resulting perfluoro unsaturated carboxylic acid amide represented by the following general formula: CF.sub.2 .dbd.CFO(CF.sub.2)nOCF(CF.sub.3)CONH.sub.2 in any desired sequence, and is effectively applied as a cross-linking site monomer for fluorine-containing elastomers.

摘要翻译： 由以下通式表示的全氟不饱和腈化合物：CF2 = CFO（CF2）nOCF（CF3）CN，其通过氯或溴与由以下通式表示的全氟不饱和羧酸酯反应制备：CF 2 = CFO（CF 2） nOCF（CF 3）COOR随后与氨反应，从而将酯基转化为酰胺基，然后进行由以下通式表示的所得全氟不饱和羧酸酰胺的脱水反应和脱卤反应：CF 2 = CFO（ CF2）nOCF（CF3）CONH2，并且有效地用作含氟弹性体的交联位点单体。