Method for the production of bisepoxides and dithiols
    51.
    发明申请
    Method for the production of bisepoxides and dithiols 审中-公开
    二环氧化物和二硫醇的生产方法

    公开(公告)号:US20090149666A1

    公开(公告)日:2009-06-11

    申请号:US12369825

    申请日:2009-02-12

    IPC分类号: C07D301/12 C07C319/02

    CPC分类号: C07D407/04 C07C323/12

    摘要: Process for the preparation of bisepoxides, wherein a conjugated diene of the formula I where R1 is selected from hydrogen and C1-C12-alkyl, unsubstituted or substituted by one or more S—H or O—H groups, is reacted in the presence of a catalyst which is obtainable by bringing at least one manganese compound selected from A2MnX4, AMnX3, MnY, MnX2 and MnX3 into contact with at least one ligand L of the formula II where X are identical or different and are selected from monovalent anions, Y is a divalent anion, A is selected from alkali metal and ammonium, which may be alkylated, R2 are identical or different and are selected from C1-C20-alkyl, and at least one coligand which is derived from monocarboxylic acids, dibasic or polybasic carboxylic acids or diamines, with at least one peroxide, up to 4 equivalents of peroxide being used per equivalent of C—C double bond.

    摘要翻译: 二环氧化物的制备方法,其中式I的共轭二烯,其中R1选自氢和未被取代或被一个或多个SH或OH基取代的C 1 -C 12 - 烷基,在催化剂存在下反应, 可以通过使至少一种选自A2MnX4,AMnX3,MnY,MnX2和MnX3的锰化合物与至少一种式II的配位体L进行接触,其中X是相同或不同的并且选自一价阴离子,Y是二价阴离子, A选自碱金属和铵,其可以被烷基化,R 2相同或不同,并且选自C 1 -C 20烷基和至少一种衍生自单羧酸,二元或多元羧酸或二胺的共配体, 至少一种过氧化物,每当量的CC双键使用多达4当量的过氧化物。

    Method For Producing Tetracarboxylic Acids
    52.
    发明申请
    Method For Producing Tetracarboxylic Acids 有权
    生产四羧酸的方法

    公开(公告)号:US20090124827A1

    公开(公告)日:2009-05-14

    申请号:US11911686

    申请日:2006-04-27

    IPC分类号: C07C51/16

    摘要: A process for preparing tetracarboxylic acids of the general formula I or salts thereof, wherein at least one compound of the general formula II a or II b (a) is first reacted with at least one epoxidation reagent and (b) then oxidized with nitric acid or at least one nitrogen oxide, where the variables are defined as follows: R1, R2 are the same or different and are selected from hydrogen, phenyl and C1-C10-alkyl.

    摘要翻译: 一种制备通式I的四羧酸或其盐的方法,其中至少一种通式II a或II b(a)的化合物首先与至少一种环氧化试剂反应,然后(b)然后用硝酸氧化 或至少一种氮氧化物,其中变量定义如下:R 1,R 2相同或不同,并且选自氢,苯基和C 1 -C 10 - 烷基。

    Method for producing propylene oxide
    56.
    发明授权
    Method for producing propylene oxide 有权
    生产环氧丙烷的方法

    公开(公告)号:US07378536B2

    公开(公告)日:2008-05-27

    申请号:US10553441

    申请日:2004-04-16

    IPC分类号: C07D301/03

    CPC分类号: C07D301/12

    摘要: Process for preparing propylene oxide, which comprises at least the steps (iii) and (iv) (iii) separating off propylene oxide from a mixture (M1) comprising propylene oxide and at least one solvent by distillation in a distillation column, giving a bottom stream and a vapor stream consisting essentially of propylene oxide; (iv) compressing the vapor stream obtained in (iii) by means of at least one compressor to give a compressed vapor.

    摘要翻译: 制备环氧丙烷的方法,其至少包括步骤(iii)和(iv)(iii)通过在蒸馏塔中蒸馏从包含环氧丙烷和至少一种溶剂的混合物(M1)中分离环氧丙烷,得到底部 气流和基本上由环氧丙烷组成的蒸气流; (iv)通过至少一个压缩机压缩(iii)中获得的蒸气流,得到压缩蒸气。