摘要:
Process for the preparation of bisepoxides, wherein a conjugated diene of the formula I where R1 is selected from hydrogen and C1-C12-alkyl, unsubstituted or substituted by one or more S—H or O—H groups, is reacted in the presence of a catalyst which is obtainable by bringing at least one manganese compound selected from A2MnX4, AMnX3, MnY, MnX2 and MnX3 into contact with at least one ligand L of the formula II where X are identical or different and are selected from monovalent anions, Y is a divalent anion, A is selected from alkali metal and ammonium, which may be alkylated, R2 are identical or different and are selected from C1-C20-alkyl, and at least one coligand which is derived from monocarboxylic acids, dibasic or polybasic carboxylic acids or diamines, with at least one peroxide, up to 4 equivalents of peroxide being used per equivalent of C—C double bond.
摘要:
A process for preparing tetracarboxylic acids of the general formula I or salts thereof, wherein at least one compound of the general formula II a or II b (a) is first reacted with at least one epoxidation reagent and (b) then oxidized with nitric acid or at least one nitrogen oxide, where the variables are defined as follows: R1, R2 are the same or different and are selected from hydrogen, phenyl and C1-C10-alkyl.
摘要:
Process for the catalyzed reaction of an organic compound with a hydroperoxide in at least one reactor using at least two different zeolite catalysts, wherein at least two of the different zeolite catalysts are used physically separately from one another.
摘要:
The present invention provides a process for the epoxidation of propene which comprises reacting propene with hydrogen peroxide in the presence of methanol as solvent and a titanium zeolite catalyst, the process further comprising separating propylene oxide from the reaction mixture to obtain a mixture comprising methanol, water, at least one carboxylic acid and at least one carbonyl compound, wherein the at least one carboxylic acid is at least partially neutralized, said process optionally comprising a hydrogenation stage.
摘要:
The present invention relates to a process for purifying a gas mixture comprising dinitrogen monoxide and to the use of a gas mixture purified in this way as an oxidant for olefins. In a further embodiment, the present invention also relates to a process for preparing ketones comprising the oxidation of an olefin with a gas mixture which has been purified in accordance with the invention and comprises dinitrogen monoxide.
摘要:
Process for preparing propylene oxide, which comprises at least the steps (iii) and (iv) (iii) separating off propylene oxide from a mixture (M1) comprising propylene oxide and at least one solvent by distillation in a distillation column, giving a bottom stream and a vapor stream consisting essentially of propylene oxide; (iv) compressing the vapor stream obtained in (iii) by means of at least one compressor to give a compressed vapor.
摘要:
The invention relates to a continuously operated process for the purification by distillation of the 1,2-propylene glycol formed as by-product in the synthesis of propylene oxide, wherein the mixture formed in the synthesis which contains the 1,2-propylene glycol is separated in a dividing wall column into low-, intermediate- and high-boiling fractions and the 1,2-propylene glycol is taken off as intermediate boiler at the side offtake of the column.
摘要:
A process for the preparation of propylene oxide in the presence of methanol, in which propylene oxide is separated from a mixture propylene oxide and methanol, and the resultant methanol containing mixture is worked up, including seperating methanol from a mixture comprising methanol and methyl formate during the work-up.
摘要:
In a continuous process for reacting an organic compound with hydroperoxide in the presence of a catalyst, the reaction is carried out in a reactor assembly comprising at least two reactors connected in parallel.
摘要:
In a process for reacting an organic compound with a hydroperoxide using at least one heterogeneous catalyst, both the pH and the temperate of the reaction medium are changed during the reaction