公开(公告)号：US5714612A

公开(公告)日：1998-02-03

申请号：US578926

申请日：1995-12-27

申请人： Kenji Kimura ,  Motohiko Samizo ,  Shinya Tanaka ,  Yukihiro Honda ,  Manji Sasaki ,  Shinichi Yachigo

发明人： Kenji Kimura ,  Motohiko Samizo ,  Shinya Tanaka ,  Yukihiro Honda ,  Manji Sasaki ,  Shinichi Yachigo

IPC分类号： C07D211/58 ,  C07B61/00 ,  C07D211/94 ,  C08K5/3432 ,  C08K5/3435 ,  C08L101/00 ,  C07D211/30

CPC分类号： C08K5/3435

摘要： A hindered piperidine compound represented by the formula of ##STR1## wherein R.sup.1 is a 2,2,6,6-tetramethyl-4-piperidyl group of which the N-position is substituted or not, a hydrogen atom, a C.sub.1 -C.sub.18 arylalkyl group which may contain a cyclic portion, or a C.sub.7 -C.sub.18 arylalkyl group, R.sup.2 is a hydrogen atom, a C.sub.1 -C.sub.10 alkyl group which may contain a cyclic portion, a C.sub.1 -C.sub.18 alkyloxy group which may contain a cyclic portion, or a hydroxyl group, and n is an integer of 2 to 8, effectively stabilizes organic materials having a property to deteriorate by the action of light. A method for producing the compound represented by the above formula is also disclosed.

摘要翻译： 由下式表示的受阻哌啶化合物，其中R1是其N-取代的2,2,6,6-四甲基-4-哌啶基，氢原子，C 1 -C 18芳烷基 可以含有环状部分的基团，或C 7〜C 18芳烷基，R 2为氢原子，可含有环状部分的C 1〜C 10烷基，可含有环状部分的C 1 -C 18烷氧基，或 羟基，n为2〜8的整数，有效地使通过光的作用使具有劣化性的有机材料稳定化。 还公开了由上式表示的化合物的制备方法。

公开(公告)号：US5428091A

公开(公告)日：1995-06-27

申请号：US171622

申请日：1993-12-22

申请人： Hiroomi Abe ,  Takeshi Fujii ,  Masashi Yamamoto ,  Shinichi Yachigo ,  Hideo Nagasaki ,  Naoki Inui

发明人： Hiroomi Abe ,  Takeshi Fujii ,  Masashi Yamamoto ,  Shinichi Yachigo ,  Hideo Nagasaki ,  Naoki Inui

IPC分类号： C08K5/32 ,  C08K5/34 ,  C08L21/00 ,  C08L23/00 ,  C08L23/04 ,  C08L25/00 ,  C08L51/06 ,  C08L71/12 ,  C08L53/00

CPC分类号： C08L23/04 ,  C08K5/32 ,  C08K5/34 ,  C08L71/12 ,  Y10S525/905

摘要： A thermoplastic resin composition which comprises 100 parts by weight of a composition comprising 95-5 % by weight of at least one polyolefinresin (A) selected from homopolymers of ethylene or .alpha.-olefin or copolymers thereof and these homopolymers or copolymers modified with a polyfunctional compound (E) and/or an unsaturated monomer (L) and 5-95 % by weight of at least one polyphenylene-ether-resin (B) selected from polyphenylene ether, modified polyphenylene ether with the above (E) and/or (L) and a composition comprising the polyphenylene or modified polyphenylene ether and an aromatic vinyl polymer resin (M) and 0.001-10 parts by weight of a dinitrodiamine (D) of the following formula (I). ##STR1## (wherein X represents a divalent chain aliphatic group, a cyclic aliphatic group or an aromatic group which may contain a halogen or an oxygen atom, R.sup.1 represents a hydrogen atom, a chain aliphatic group, a cyclic aliphatic group or an aromatic group and when both of X and R.sup.1 are chain aliphatic groups, the nitrogen atoms may further bond each other to form a ring through X and R.sup.1 ; R.sup.2 and R.sup.3 are independently a hydrogen atom or an alkyl group of 1-12 carbon atoms and R.sup.2 and R.sup.3 may bond to form a ring).

摘要翻译： 一种热塑性树脂组合物，其包含100重量份的组合物，其包含95-5重量％的至少一种选自乙烯或α-烯烃的均聚物或其共聚物的聚烯烃树脂（A），以及这些均聚物或共聚物，其被多官能化合物 （E）和/或不饱和单体（L）和5-95重量％的至少一种选自聚苯醚的聚苯醚树脂（B），具有上述（E）和/或（L）的改性聚苯醚 ）和包含聚亚苯基或改性聚苯醚和芳族乙烯基聚合物树脂（M）的组合物和0.001-10重量份下式（I）的二硝基二胺（D）。 （I）（其中X表示二价链脂肪族基团，环状脂肪族基团或可以含有卤素或氧原子的芳香族基团，R 1表示氢原子，链状脂肪族基团，环状脂肪族基团或 芳族基团，当X和R 1都是链状脂肪族基团时，氮原子可以进一步通过X和R 1彼此键合形成环; R2和R3独立地是氢原子或1-12个碳原子的烷基 并且R 2和R 3可以键合形成环）。

公开(公告)号：US5338869A

公开(公告)日：1994-08-16

申请号：US87866

申请日：1993-07-09

申请人： Kikumitsu Inoue ,  Manji Sasaki ,  Shinichi Yachigo

发明人： Kikumitsu Inoue ,  Manji Sasaki ,  Shinichi Yachigo

IPC分类号： C07D493/10 ,  G01N23/20 ,  C07D319/06

CPC分类号： C07D493/10

摘要： A hydroxyphenylpropionic ester represented by the formula of ##STR1## which has a crystal structure showing a sharp X-ray diffraction peak at a diffraction angle 2.theta.=7.9.degree. by X-ray diffraction measurement using an X-ray of a Cu-K.sub..alpha. wavelength. This novel crystal exhibits largely advantageous effects in industrial production and usage of the ester because of its high purity, high quality, excellent filterability owing to the large crystal growth, and excellent fluidity owing to the large bulk specific gravity.

摘要翻译： 由下式表示的羟基苯基丙酸酯，其具有通过X射线衍射测定在衍射角2θ= 7.9°处显示出尖锐X射线衍射峰的晶体结构，使用X射线 Cu-Kα波长。 由于其高纯度，高质量，由于大的晶体生长而具有优异的过滤性，并且由于体积比重大而具有优异的流动性，因此该新颖的晶体在工业生产和酯的使用方面具有很大的有益效果。

公开(公告)号：US5322947A

公开(公告)日：1994-06-21

申请号：US4667

申请日：1993-01-14

申请人： Shinya Tanaka ,  Manji Sasaki ,  Shinichi Yachigo ,  Hiroki Yamamoto ,  Eiiti Yoneyama

发明人： Shinya Tanaka ,  Manji Sasaki ,  Shinichi Yachigo ,  Hiroki Yamamoto ,  Eiiti Yoneyama

IPC分类号： B01D9/02 ,  C07D211/58 ,  C08K5/3435 ,  C07D401/14

CPC分类号： C07D211/58 ,  C08K5/3435

摘要： Crude N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)alkanediamine represented by the formula: ##STR1## wherein n is an integer of 2 to 10, is purified by crystallization from a ketone solvent of 3 to 9 carbon atoms. The purified product thus obtained has a purity of 98% by weight or more, a 2,2,6,6-tetramethyl-4-piperidone content of 150 ppm or less, and an initial APHA value of 30 or less. The purified product is also inhibited from discoloration with the passage of time.

摘要翻译： 由下式表示的N，N'-双（2,2,6,6-四甲基-4-哌啶基）链烷二胺，其中n为2〜10的整数，通过从酮溶剂 3至9个碳原子。 由此获得的纯化产物的纯度为98重量％以上，2,2,6,6-四甲基-4-哌啶酮含量为150ppm以下，初始APHA值为30以下。 纯化的产品随着时间的推移也被抑制变色。

公开(公告)号：US5180764A

公开(公告)日：1993-01-19

申请号：US681363

申请日：1991-04-08

申请人： Hideo Nagasaki ,  Naoki Inui ,  Shinichi Yachigo ,  Hiroomi Abe ,  Takeshi Fujii ,  Masashi Yamamoto

发明人： Hideo Nagasaki ,  Naoki Inui ,  Shinichi Yachigo ,  Hiroomi Abe ,  Takeshi Fujii ,  Masashi Yamamoto

IPC分类号： C08K5/32

CPC分类号： C08K5/32

摘要： A thermoplastic resin is stabilized by incorporating therein a dinitrodiamine compound represented by the formula of ##STR1## wherein X is a divalent aliphatic, alicyclic or aromatic group which may contain halogen or oxygen in the group, R.sup.1 is hydrogen or an aliphatic, alicyclic or aromatic group, provided that two nitrogen atoms linking through X may further link through R.sup.1 when both X and R.sup.1 are the aliphatic groups, and R.sup.2 and R.sup.3 independently of one another are each hydrogen or an alkyl of 1 to 12 carbon atoms, provided that R.sup.2 and R.sup.3 may conjointly form a ring. The composition thus blended is improved in thermal processing stability. Further, a modified polyolefin resin is improved in mechanical properties, particularly in impact strength, by the incorporation of the dinitrodiamine compound.

公开(公告)号：US4939196A

公开(公告)日：1990-07-03

申请号：US291965

申请日：1988-12-30

申请人： Manji Sasaki ,  Shinichi Yachigo ,  Kikumitsu Inoue ,  Shinya Tanaka ,  Fumitoshi Kojima ,  Takeshi Takata

发明人： Manji Sasaki ,  Shinichi Yachigo ,  Kikumitsu Inoue ,  Shinya Tanaka ,  Fumitoshi Kojima ,  Takeshi Takata

IPC分类号： C07C69/54 ,  C07C65/28 ,  C08K5/10 ,  C08K5/13 ,  C08L9/00

CPC分类号： C07C65/28 ,  C08K5/10

摘要： A compound represented by the formula of ##STR1## wherein R.sub.1 represents an alkyl having 1 to 5 carbon atoms;R.sub.2 represents an alkyl having 1 to 18 carbon atoms, an alkenyl having 2 to 5 carbon atoms, an aralkyl having 7 to 9 carbon atoms, phenyl, an aliphatic acyl having 2 to 5 carbon atoms, or benzoyl;R.sub.3 represents hydrogen or an alkyl having 1 to 11 carbon atoms; andR.sub.4 represents hydrogen or methyl.The compound is useful as a stabilizer for synthetic resins such as butadiene polymers. The butadiene polymer containing the compound is stable against thermal deterioration in the absence of oxygen, as well as against thermal oxidative deeterioration and thermal oxidative discoloration.

摘要翻译： 由下式表示的化合物：其中R 1表示具有1至5个碳原子的烷基; R 2表示碳原子数1〜18的烷基，碳原子数2〜5的烯基，碳原子数7〜9的芳烷基，苯基，碳原子数2〜5的脂肪族酰基或苯甲酰基。 R3代表氢或具有1至11个碳原子的烷基; R4表示氢或甲基。 该化合物可用作合成树脂如丁二烯聚合物的稳定剂。 含有该化合物的丁二烯聚合物对于不存在氧的热劣化以及热氧化脱臭和热氧化变色是稳定的。

公开(公告)号：US4385143A

公开(公告)日：1983-05-24

申请号：US298111

申请日：1981-08-31

申请人： Shinichi Yachigo ,  Yuko Takahashi ,  Tsutomu Mitsuda ,  Mitsuhisa Nakatani

发明人： Shinichi Yachigo ,  Yuko Takahashi ,  Tsutomu Mitsuda ,  Mitsuhisa Nakatani

IPC分类号： C07C59/52 ,  C07D251/34 ,  C08K5/134 ,  C08K5/3477 ,  C07C69/612 ,  C08K5/13 ,  C08K5/24

CPC分类号： C07D251/34 ,  C07C59/52 ,  C08K5/1345 ,  C08K5/3477

摘要： Synthetic resins, particularly polyolefins, are markedly improved in their resistances to heat and oxidation by the incorporation of a 2-methyl-4-t-butyl-5-hydroxyphenylalkanoic acid ester alone or in combination with a thioether-type antioxidant represented by the general formula ##STR1## wherein R represents an alkyl group of 12 to 20 carbon atoms, or by the general formula ##STR2## wherein R represents an alkyl group of 4 to 20 carbon atoms.

摘要翻译： 合成树脂，特别是聚烯烃，通过单独引入2-甲基-4-叔丁基-5-羟基苯基链烷酸酯或与通用化合物代表的硫醚型抗氧化剂组合，显着地提高了其耐热性和抗氧化性 其中R表示12〜20个碳原子的烷基，或通式为其中R表示4〜20个碳原子的烷基。