Process for removal of mercury from a liquid hydrocarbon
    51.
    发明授权
    Process for removal of mercury from a liquid hydrocarbon 失效
    从液态碳氢化合物中除去汞的工艺

    公开(公告)号:US5037552A

    公开(公告)日:1991-08-06

    申请号:US352024

    申请日:1989-05-15

    IPC分类号: C10G25/00 C10G29/10 C10G53/08

    摘要: A liquid hydrocarbon such as a natural gas liquid generally contains a small amount of mercury in a state of elemental mercury, ionized mercury, ionizable mercury compounds, which are requested to be removed thoroughly. Further, organic mercury compounds are contained in some natural gas liquid and other liquid hydrocarbons depending on their district of production, and its removal is also necessary.Already known adsorbents can adsorb elemental mercury and organic mercury compounds in a liquid hydrocarbon, but they hardly adsorb ionizable mercury compounds and ionized mercury derived from the ionizable mercury compounds.According to the preesent invention which comprises contacting the liquid hydrocarbon with a sulfur compound represented by a general formula MM'S.sub.x, wherein M is selected from a group consisting of alkali metal and ammonium radical, M' is selected from a group consisting of alkali metal, ammonium radical and hydrogen an x is a number of at least 1, the sulfur compound and mercury in the liquid hydrocarbon reacts to form mercury sulfide which is insoluble in the liquid hydrocarbon to be separated therefrom.If the liquid hydrocarbon contains organic mercury compounds together with elemental mercury ionized mercury and ionizable mercury compounds, the above-mentioned process is to be combined with a process of contacting the liquid hydrocarbon with an adsorbent comprising heavy metal sulfide to adsorb the organic mercury compounds together with the mercury sulfide which is formed in the above-mentioned process.

    Process for recovering hydrocarbon and other values from shale oil rock
    54.
    发明授权
    Process for recovering hydrocarbon and other values from shale oil rock 失效
    从页岩油岩中回收烃和其他值的方法

    公开(公告)号:US4454017A

    公开(公告)日:1984-06-12

    申请号:US343956

    申请日:1982-02-01

    申请人: Rollan Swanson

    发明人: Rollan Swanson

    CPC分类号: C10G29/10 C10G1/00 C10G45/00

    摘要: An improved method for recovering hydrocarbon and other values from shale oil rock, whereby shale oil rock, during the reaction with a reagent and steam, is shattered to the extent that the hydrocarbon values and the unwanted pulverized gangue is collected such as via cyclones or a dust collector; the desired hydrocarbon values as volatile products may be recovered or further reacted in a separate reactor; a series of cyclones may be used to separate the dust from the hydrocarbon values; recoveries of over 90% of the hydrocarbon values and higher are achieved; as a further advantage, the collected dust may be used as an intermediate for making cement.

    摘要翻译: 一种用于从页岩油岩石中回收烃和其它值的改进方法,其中在与试剂和蒸汽反应期间,页岩油岩石被粉碎到可以收集烃值和不需要的粉碎g石的程度,例如通过旋风分离器或 除尘器; 作为挥发性产物的所需烃值可以在单独的反应器中回收或进一步反应; 可以使用一系列旋风分离灰尘与碳氢化合物的值; 达到90%以上的碳氢化合物值和更高的回收率; 作为另一个优点,收集的灰尘可以用作制造水泥的中间体。

    Demetallization of heavy oils
    55.
    发明授权
    Demetallization of heavy oils 失效
    重油脱金属

    公开(公告)号:US4421638A

    公开(公告)日:1983-12-20

    申请号:US481085

    申请日:1983-03-31

    IPC分类号: C10G29/10 C10G29/02

    CPC分类号: C10G29/10

    摘要: An improved process for removing metals from heavy oils and other hydrocarbon feed streams is disclosed. The process includes adding phosphorus sulfide to the hydrocarbon feed stream under suitable demetallizing conditions. It is believed that phosphorus sulfide reacts with the metals contained in the hydrocarbon containing feed stream to form oil insoluble compounds that can be removed from the hydrocarbon containing feed stream by any conventional method, such as filtration, centrifugation, or decantation.

    摘要翻译: 公开了一种用于从重油和其他烃进料流中除去金属的改进方法。 该方法包括在合适的脱金属条件下向烃进料流中加入硫化磷。 据信,硫化磷与含烃进料流中所含的金属反应形成油不溶性化合物,其可以通过任何常规方法如过滤,离心或倾析从含烃进料流中除去。

    Removal of oxygen from petroleum charge stocks
    56.
    发明授权
    Removal of oxygen from petroleum charge stocks 失效
    从石油充电库中清除氧气

    公开(公告)号:US3974066A

    公开(公告)日:1976-08-10

    申请号:US586330

    申请日:1975-06-12

    IPC分类号: C10G29/10 C10G29/04

    CPC分类号: C10G29/10

    摘要: A method is disclosed for the treatment of a petroleum charge stock which comprises the treatment of said petroleum charge stock with an aqueous solution containing a metal phthalocyanine compound and a compound selected from the group consisting of an alkali metal sulfide and an alkali metal sulfite.

    摘要翻译: 公开了一种用于处理含石油原料的方法,该方法包括用含有金属酞菁化合物的水溶液和选自碱金属硫化物和碱金属亚硫酸盐的化合物处理所述石油原料。