公开(公告)号：US06616865B1

公开(公告)日：2003-09-09

申请号：US09546930

申请日：2000-04-11

申请人： Cheng Zhang ,  Harold R. Fetterman ,  William Steier ,  Joseph Michael

发明人： Cheng Zhang ,  Harold R. Fetterman ,  William Steier ,  Joseph Michael

IPC分类号： F21V900

CPC分类号： C08K5/0041 ,  C09B23/0066 ,  C09B23/0075 ,  C09B23/0091 ,  C09B23/145 ,  G02F1/065 ,  G02F1/3611 ,  G02F1/3612 ,  G02F1/3613 ,  G02F1/3614 ,  G02F1/3615 ,  G02F2001/212

摘要： Sterically stabilized second-order nonlinear optical chromophores and devices incorporating the same are embodied in a variety of chromophore materials. An exemplary preferred chromophore includes an electron donor group, an electron acceptor group and a ring-locked bridge structure therebetween, with the bridge structure being directly connected to the electron donor via a single bond. Another exemplary preferred chromophore includes an electron donor group, an electron acceptor group and a ring-locked bridge structure between the electron donor group and the electron acceptor group, with two free double bonds, one located between the donor and the bridge and the other located between the (fused) ring bridge and the acceptor. Another exemplary preferred chromophore includes an electron donor group, an electron acceptor group, and a bridge structure therebetween, with the chromophores having no carbon-carbon double bond between the donor and the (fused) ring bridge. In this class, there is only one unlocked carbon-carbon double bond between the (fused) ring bridge and the acceptor. Another exemplary preferred chromophore includes an electron donor group, an electron acceptor group, and a ring-locked bridge structure therebetween, with a built-in electron-withdrawing cyano group on the last ring of the (fused) bridge. Another exemplary preferred chromophore includes any electron donor group, an electron acceptor group including a linear conjugated triene bearing four cyano groups, and any bridge structure therebetween.

摘要翻译： 具有稳定的二阶非线性光学发色团和包含其的装置体现在各种发色团材料中。 示例性的优选发色团包括电子给体基团，电子受体基团和它们之间的环形锁定桥结构，桥结构通过单键直接连接到电子给体。 另一个示例性的优选发色团包括电子给体基团，电子受体基团和电子给体基团和电子受体基团之间的环锁桥结构，具有两个游离双键，一个位于供体和桥之间，另一个位于 （融合）环桥与受体之间。 另一个示例性的优选发色团包括电子给体基团，电子受体基团和它们之间的桥接结构，发色团在供体和（稠合）环桥之间不具有碳 - 碳双键。 在这个类中，（稠）环桥和受体之间只有一个解锁的碳 - 碳双键。 另一示例性的优选发色团包括电子给体基团，电子受体基团和它们之间的环形锁定桥结构，在（稠合）桥的最后一个环上具有内置的吸电子氰基。 另一个示例性的优选发色团包括任何电子给体基团，包含具有四个氰基的线性共轭三烯的电子受体基团以及它们之间的任何桥接结构。

公开(公告)号：US5635576A

公开(公告)日：1997-06-03

申请号：US528109

申请日：1995-09-13

申请人： Franck Foll ,  Dominique Bosc ,  Alain Rousseau ,  Bernard Boutevin

发明人： Franck Foll ,  Dominique Bosc ,  Alain Rousseau ,  Bernard Boutevin

IPC分类号： C07C251/24 ,  C08F20/36 ,  C09B55/00 ,  C09B69/10 ,  G02F1/361 ,  C08F126/02 ,  C08F124/00

CPC分类号： G02F1/3613 ,  C07C251/24 ,  C08F20/36 ,  C09B55/002 ,  C09B69/107 ,  G02F1/3611

摘要： The invention relates to a crosslinkable material containing a polymer onto which chromophores are laterally grafted, characterized in that each chromophore is within a polymer unit which corresponds to the following formula (I): ##STR1## in which: X represents a part of the polymer chain,A is a group --NO.sub.2, --CN, --C(CN).dbd.C(CN).sub.2 or --SO.sub.2 R.sub.4, R.sub.4 being a C.sub.1 to C.sub.6 alkyl,D is a nitrogen, sulphur or oxygen atom,R.sub.1 is a hydrogen atom or a C.sub.1 to C.sub.6 alkyl if D is a nitrogen atom, or nothing if D is a sulphur or oxygen atom,R.sub.2 is a C.sub.1 to C.sub.6 aliphatic alkyl group,and E is a group chosen from --OH, --O--CO--(CH.sub.2).sub.n --COOH, --O--W, --O--CO--R.sub.3 O--W and --O--R.sub.3 --O--W, n being an integer between 2 and 6, W being a photodimerizable group and R.sub.3 being a C.sub.1 to C.sub.6 alkyl,and the said material additionally containing complementary anchoring functional groups capable of attaching themselves to E during the crosslinking.

摘要翻译： 本发明涉及含有聚合物的可交联材料，其上发色团被横向接枝，其特征在于每个发色团都在与下式（I）相对应的聚合物单元内：其中：X表示部分 的聚合物链，A是-NO 2，-CN，-C（CN）= C（CN）2或-SO 2 R 4基团，R 4是C 1 -C 6烷基，D是氮，硫或氧原子，R 1是 如果D为氮原子，则为氢原子或C1至C6烷基，如果D为硫或氧原子，则为R2，C1为C6脂肪族烷基，E为选自-OH，-O- CO-（CH 2）n -COOH，-OW，-O-CO-R 3 O-W和-O-R 3 -OW，n为2至6的整数，W为可光二聚化基团，R 3为C 1至C 6烷基 ，并且所述材料另外含有能够在交联期间自身附着于E的互补锚定官能团。

公开(公告)号：US5501821A

公开(公告)日：1996-03-26

申请号：US19815

申请日：1993-02-19

申请人： Craig S. Willand ,  Douglas R. Robello ,  Edward J. Urankar ,  Abraham Ulman

发明人： Craig S. Willand ,  Douglas R. Robello ,  Edward J. Urankar ,  Abraham Ulman

IPC分类号： G02F1/361 ,  F21V9/00

CPC分类号： G02F1/3613 ,  G02F1/361 ,  G02F1/3617

摘要： An optical article, for the transmission of electromagnetic radiation. The optical article includes a medium, which exhibits a second-order electric susceptibility greater than 10.sup.-9 electrostatic units. The medium includes polar aligned dipole subunits. Each dipole subunit has a plurality of noncentrosymmetric molecular dipoles and a connector system. Each molecular dipole has an electron donor moiety, an electron acceptor moiety, and a linking moiety. The linking moiety has a pair of covalent bonds to the connector system. Each molecular dipole has a conjugated .pi. bonding system extending from the electron donor moiety along the linking moiety to the electron acceptor moiety to permit oscillation of the molecular dipole between a ground state and an excited state, which states differ in polarity. The connector system joins the linking moieties to complete a solitary ring or a system of fused rings, which retain the molecular dipoles in substantially parallel relative relation.

摘要翻译： 一种用于传输电磁辐射的光学制品。 光学制品包括介质，其表现出大于10-9静电单位的二次电磁化率。 介质包括极性对准的偶极子单元。 每个偶极子单元具有多个非中心对称分子偶极子和连接器系统。 每个分子偶极子具有电子供体部分，电子受体部分和连接部分。 连接部分与连接器系统具有一对共价键。 每个分子偶极具有从电子供体部分沿着连接部分延伸到电子受体部分的共轭π键合体系，以允许分子偶极子在基态和激发态之间的振荡，其状态极性不同。 连接器系统连接连接部分以完成孤立环或稠环系统，其将分子偶极保持为基本平行的相对关系。

公开(公告)号：US5486559A

公开(公告)日：1996-01-23

申请号：US289044

申请日：1994-08-11

申请人： Johannes F. J. Engbersen ,  Erik Kelderman ,  David N. Reinhoudt ,  Willem Verboom

发明人： Johannes F. J. Engbersen ,  Erik Kelderman ,  David N. Reinhoudt ,  Willem Verboom

IPC分类号： C08K5/05 ,  C08K5/06 ,  C08L101/00 ,  C08L101/12 ,  G02F1/35 ,  G02F1/355 ,  G02F1/361 ,  C08K5/13 ,  G02B6/00

CPC分类号： G02F1/3613 ,  G02F1/3611 ,  G02F1/3615

摘要： The invention relates to an optically non-linear active waveguiding material comprising an optically transparent polymer and a donor group and acceptor group-containing triphenylcarbinol as a dopant. Said dopants have a high hyperpolarizability and have a charge-transfer absorption band which is about the same as that of their corresponding compounds having only one donor-.pi.-acceptor unit. The triphenylcarbinols were found to display good solubility in polymers. Nitro-functionalized triphenylcarbinols are preferred because of their charge-transfer absorption band at a low wavelength (.lambda..sub.max at about 290 nm). Aldehyde-functionalized calix(4)arenes were also found to have this low wavelength charge-transfer absorption band (.lambda..sub.max at about 270 nm). Triphenyls comprising stilbene donor-.pi.-acceptor units are preferred because of their high hyperpolarizability.

摘要翻译： 本发明涉及一种光学非线性有源波导材料，其包含光学透明聚合物和供体基团和含受体基团的三苯基甲醇作为掺杂剂。 所述掺杂剂具有高的超极化性，并且具有电荷转移吸收带，其与仅具有一个供体-π-受体单元的相应化合物的电荷转移吸收带大致相同。 发现三苯基甲醇在聚合物中表现出良好的溶解性。 硝基官能化三苯基甲醇是优选的，因为它们在低波长下的电荷转移吸收带（约290nm处的λmax）。 还发现醛官能化杯（4）芳烃具有这种低波长电荷转移吸收带（λmax在约270nm）。 由于它们具有高的超极化性，所以包含二苯乙烯供体-π-受体单元的三苯基是优选的。

公开(公告)号：US5381429A

公开(公告)日：1995-01-10

申请号：US62341

申请日：1993-05-14

申请人： Hisashi Minemoto ,  Yusuke Ozaki ,  Nobuo Sonoda

发明人： Hisashi Minemoto ,  Yusuke Ozaki ,  Nobuo Sonoda

IPC分类号： G02F1/35 ,  G02F1/355 ,  G02F1/361 ,  G02F1/37 ,  H01S3/094 ,  H01S3/108 ,  H01S3/10

CPC分类号： G02F1/3613

摘要： A laser apparatus includes a semiconductor laser, an optical resonater and a wavelength converter made of a nonlinear optical material. The nonlinear optical material has at least one of aromatic ring and metal ion, and wherein at least one element selected from the group consisting of ion bonding hydrogen, hydrogen bonding hydrogen and hydrogen of water of crystallization is replaced with deuterium. The nonlinear optical material is formed by removing water of crystallization from an organic ionic crystal containing at least one of aromatic ring and metal ion, and recrystallizing with a solvent comprising at least one of ionic bonding deuterium, hydrogen bonding deuterium, and heavy water.

摘要翻译： 激光装置包括半导体激光器，光谐振器和由非线性光学材料制成的波长转换器。 非线性光学材料具有芳环和金属离子中的至少一种，并且其中选自离子键氢，氢键氢和结晶水的氢中的至少一种元素被氘代替。 通过从含有芳香环和金属离子中的至少一种的有机离子晶体除去结晶水，通过含有离子键氘，氢键氘和重水中的至少一种的溶剂重结晶而形成非线性光学材料。

公开(公告)号：US5347394A

公开(公告)日：1994-09-13

申请号：US43407

申请日：1993-04-06

申请人： Katsuya Wakita ,  Tetsuji Kawakami ,  Nobuo Sonoda ,  Hisashi Minemoto

发明人： Katsuya Wakita ,  Tetsuji Kawakami ,  Nobuo Sonoda ,  Hisashi Minemoto

IPC分类号： G02F1/361 ,  G02F1/35

CPC分类号： G02F1/361 ,  G02F1/3611 ,  G02F1/3613

摘要： The invention provides a nonlinear optical material comprising a compound represented by the general formula (1): ##STR1## wherein R.sup.1 denotes an electron attractive group, R.sup.2 denotes a group selected from the group consisting of a hydrogen atom, methyl group, methoxy group and electron attractive group, R.sup.3 denotes a straight-chain alkylene group, and X denotes an oxygen or sulfur atom. The invention also relates to a method of manufacturing a nonlinear optical material comprising the steps of dissolving a compound represented by the general formula (1) in an organic solvent, and evaporating the solvent while keeping its temperature constant or lowering its temperature, thereby growing a crystal of the compound represented by the general formula (1). The nonlinear optical material of the invention possessing a molecular structure realized by linking structures having a strong electron attractive group and weak electron donative portion with straight-chain alkylene portions, and thus a nonlinear optical material having a shortened absorption edge wavelength and excellent crystallinity may be obtained. These nonlinear optical materials can be effectively utilized as the nonlinear optical material for an optical wavelength converter.

摘要翻译： 本发明提供一种包含由通式（1）表示的化合物的非线性光学材料：其中R1表示吸电子基团，R2表示选自氢原子，甲基， 甲氧基和吸电子基团，R3表示直链亚烷基，X表示氧或硫原子。 本发明还涉及一种制造非线性光学材料的方法，包括以下步骤：将由通式（1）表示的化合物溶解在有机溶剂中，并蒸发溶剂同时保持其温度恒定或降低其温度，从而生长 由通式（1）表示的化合物的晶体。 本发明的非线性光学材料具有通过将具有强电子吸引基团和弱电子给体部分的结构与直链亚烷基部分连接而实现的分子结构，因此具有缩短的吸收边缘波长和优异结晶度的非线性光学材料可以是 获得。 这些非线性光学材料可以有效地用作光学波长转换器的非线性光学材料。

公开(公告)号：US5332827A

公开(公告)日：1994-07-26

申请号：US109897

申请日：1993-08-23

申请人： Kevin R. Stewart ,  Eugene P. Boden ,  Christopher P. Yakymyshyn

发明人： Kevin R. Stewart ,  Eugene P. Boden ,  Christopher P. Yakymyshyn

IPC分类号： G02B6/122 ,  G02F1/065 ,  G02F1/361 ,  G02F1/377 ,  C07D211/70

CPC分类号： G02F1/361 ,  G02B6/1221 ,  G02F1/065 ,  G02F1/3613 ,  G02F1/377

摘要： Deuterated organic salts useful in nonlinear optical applications are disclosed herein. More particularly, optoelectronic devices and systems are prepared from said deuterated organic salts and the preferred salt is perdeuterated 4'-dimethylamino-4-methylstilbazolium p-toluenesulfonate.

公开(公告)号：US5292888A

公开(公告)日：1994-03-08

申请号：US82704

申请日：1993-06-28

申请人： Kevin R. Stewart

发明人： Kevin R. Stewart

IPC分类号： C07D213/38 ,  G02F1/361 ,  C07D211/70

CPC分类号： G02F1/3613 ,  C07D213/38

摘要： Stilbazolium salts that retain high second harmonic generation properties as well as high melting points are disclosed herein. More particularly, novel 4'-dimethylamino-N-methylstilbazolium cyclopentanesulfonate and homologs thereof which are expected to be useful in optoelectric devices and systems are disclosed.

摘要翻译： 本文公开了保持高二次谐波产生特性以及高熔点的均苯三唑鎓盐。 更具体地，公开了期望可用于光电装置和系统的新型4'-二甲基氨基-N-甲基茋环戊烷磺酸盐及其同系物。

公开(公告)号：US5266365A

公开(公告)日：1993-11-30

申请号：US843494

申请日：1992-02-28

申请人： John J. Kester ,  H. Craig Silvis

发明人： John J. Kester ,  H. Craig Silvis

IPC分类号： C08G59/20 ,  C08G59/32 ,  C08G59/50 ,  G02F1/361 ,  C08G59/40 ,  G02F1/00

CPC分类号： G02F1/3616 ,  C08G59/20 ,  C08G59/32 ,  C08G59/5033 ,  G02F1/3611 ,  G02F1/3613 ,  Y10T428/31511

摘要： The present invention is directed to an epoxy-containing polymeric material having nonlinear optical properties, particularly a glycidyl amine polymer, and a process for making the nonlinear optical (NLO) epoxy-containing polymeric material including poling the polymeric material under high voltage at elevated temperature for a period of time to bring about orientation of the nonlinear optical functionalities in the polymer. The polymers have enhanced thermal stability and good NLO properties.

摘要翻译： 本发明涉及具有非线性光学特性的含环氧基的聚合物材料，特别是缩水甘油胺聚合物，以及制造非线性光学（NLO）环氧树脂聚合物材料的方法，包括在高温下在高温下极化聚合物材料 在一段时间内引起聚合物中非线性光学官能团的取向。 聚合物具有增强的热稳定性和良好的NLO性能。

公开(公告)号：US5045239A

公开(公告)日：1991-09-03

申请号：US362464

申请日：1989-03-17

申请人： Seizo Miyata ,  Toshiyuki Watanabe ,  Yoshitaka Goto ,  Akio Hayashi ,  Masaharu Nakayama

发明人： Seizo Miyata ,  Toshiyuki Watanabe ,  Yoshitaka Goto ,  Akio Hayashi ,  Masaharu Nakayama

IPC分类号： G02F1/361

CPC分类号： G02F1/3613

摘要： A non-linear optical material comprises a derivative of chalcone represented by the following general formulae (I) or (II) of: ##STR1## wherein R.sub.1 and R.sub.2 each represent a halogen atom, a hydroxyl group, an amino group, a dimethylamino group, a nitro group, a cyano group, a phenyl group, an acetyl group, an alkyl group having 1 to 18 carbon atoms or an alkyloxy group having 1 to 22 carbon atoms; n.sub.1 and n.sub.2 each represent an interger of from 0 to 21; and m.sub.1 and m.sub.2 each represent an integer of from 0 to 5.

摘要翻译： PCT No.PCT / JP88 / 00740 Sec。 371日期：1989年3月17日 102（e）日期1989年3月17日PCT提交1988年7月22日PCT公布。 出版物WO89 / 01181 日期：1989年2月9日。非线性光学材料包含由以下通式（I）或（II）表示的查耳酮衍生物：其中R 1和R 2各自 表示卤素原子，羟基，氨基，二甲基氨基，硝基，氰基，苯基，乙酰基，碳原子数1〜18的烷基或具有1〜22个的烷氧基的烷基 碳原子 n1和n2分别表示从0到21的整数; m1和m2各自表示0〜5的整数。