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公开(公告)号:US10017607B2
公开(公告)日:2018-07-10
申请号:US14781600
申请日:2014-04-07
Applicant: ALLNEX NETHERLANDS B.V.
Inventor: Richard Hendrikus Gerrit Brinkhuis , Ferry Ludovicus Thys , Elwin Aloysius Cornelius Adrianus De Wolf
IPC: C08G63/91 , C09D167/02 , C08J3/24 , C08G63/181 , C08K3/013
CPC classification number: C08G63/916 , C08G63/181 , C08G63/91 , C08J3/24 , C08J2367/00 , C08K3/013 , C09D167/02
Abstract: The present invention relates to a crosslinkable composition crosslinkable by Real Michael Addition (RMA) reaction comprising a component with at least 2 activated unsaturated groups (hereafter referred to as the RMA acceptor groups) and a component with at least 2 acidic protons C—H in activated methylene or methane groups (hereafter referred to as the RMA donor groups) which components can react to form a crosslinked network.
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62.
公开(公告)号:US20180163083A1
公开(公告)日:2018-06-14
申请号:US15563956
申请日:2016-04-18
Applicant: ALLNEX NETHERLANDS B.V.
Inventor: Richard Hendrikus Gerrit BRINKHUIS , Michael Anthony GESSNER , Dirk Emiel Paula MESTACH , Ramesh SUBRAMANIAN , William Jay DEGOOYER , Ajaya NANDA , Eric Matthew MCCRACKEN , Francesca FALLANI , Monique Alexina MBALLA MBALLA , Martin BOSMA
IPC: C09D167/08 , C08G63/91 , C08J3/24
CPC classification number: C09D167/08 , B05D3/067 , C08F8/00 , C08G63/914 , C08J3/24 , C08J2367/08 , C08L67/08 , C09D5/00
Abstract: The invention relates to RMA crosslinkable coating composition, a method for the preparation thereof and a resulting coating having easy to clean properties useful in applications like graffiti resistant, sanitisable coatings and in flooring, said composition comprising RMA crosslinkable component with at least 2 RMA donor groups and at least 2 RMA acceptor groups characterized by having fatty components selected from the group of fatty acids, fatty alcohols, fatty amines, fatty thiols and dimeric fatty acid in an amount represented by an Oil Content OC between 0, preferably 4 and 40 wt %, and crosslinking density XLD of at least 1.4 a glass transition Tg of at least 290 in combination providing a easy to clean value ΔE less than 20. The invention also relates to RMA crosslinkable fatty resins for use in RMA crosslinkable top coatings.
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63.
公开(公告)号:US20180155573A1
公开(公告)日:2018-06-07
申请号:US15889291
申请日:2018-02-06
Applicant: Allnex Netherlands B.V.
Inventor: Richard Hendrikus Gerrit BRINKHUIS , Antonius Johannes Wilhelmus BUSER , Petrus Johannes Maria David ELFRINK , Ferry Ludovicus THYS , Nicole MANGNUS-VERHAGEN , Elwin Aloysius Cornelius Adrianus DE WOLF
IPC: C09D167/00 , B01J31/02 , C08K5/00 , C08K5/21 , C09D133/14 , C08K3/01 , C08J3/24 , C09D175/06
Abstract: An RMA crosslinkable composition having at least one crosslinkable component including reactive components A and B each including at least 2 reactive groups, the at least 2 reactive groups of component A being acidic protons (C—H) in activated methylene or methine groups and the at least 2 reactive groups of component B are activated unsaturated groups (C═C) and a base catalyst (C) which reactive components A and B crosslink by Real Michael Addition (RMA) reaction under action of the base catalyst, characterised in that the at least one crosslinkable component including reactive components A and B in the composition have a total hydroxy number of less than 60, preferably less than 40 and more preferably less than 20 mg KOH/g solids. Further, specific resins A and B having a low hydroxy number for use in RMA cross-linkable compositions and a process for the manufacture thereof.
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