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公开(公告)号：US20180163082A1
公开(公告)日：2018-06-14
申请号：US15563955
申请日：2016-04-18
Applicant: ALLNEX NETHERLANDS B.V.
Inventor： Rien GOEDEGEBUURE , Ferry Ludovicus THYS , Elwin Aloysius Cornelius Adrianus DE WOLF , Richard Hendrikus Gerrit BRINKHUIS , Michael Anthony GESSNER , Antonius Johannes Wilhelmus BUSER , David James SAUER
IPC: C09D167/02 , C09D163/00 , B05D3/02
CPC classification number: C09D167/02 , B05D1/02 , B05D3/0254 , B05D3/102 , C08G61/12 , C08G2261/135 , C08G2261/334 , C08J3/24 , C08J2367/02 , C08L63/00 , C08L67/02 , C08L2205/025 , C09D17/008 , C09D163/00
Abstract: The invention relates to a method for applying a RMA crosslinked coating with improved adhesion, comprising the steps of applying on the substrate surface a layer of a modified epoxy primer comprising an epoxy functional polymer binder and a crosslinker, wherein adhesion of the RMA crosslinked coating to the epoxy primer layer is improved by said primer comprising after curing functional groups X reactable with crosslinkable components of the RMA crosslinkable composition or a precursor of functional groups X, preferably a moisture deblockable precursor. The invention also relates to modified epoxy primers, compositions for improving adhesion of epoxy primers and use thereof to improve adhesion of RMA crosslinkable coatings.
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公开(公告)号：US20240294698A1
公开(公告)日：2024-09-05
申请号：US18567133
申请日：2022-07-05
Applicant: Allnex Netherlands B.V.
Inventor： Richard Hendrikus Gerrit BRINKHUIS , Pengcheng YANG
CPC classification number: C08G18/672 , B05D1/12 , C08G18/34 , C08J7/0427 , C09D5/03 , B05D2503/00 , C08G2150/20
Abstract: The invention is related to a powder coating composition comprising a crosslinkable composition and a catalyst system, wherein the crosslinkable composition is formed by a crosslinkable donor component A and a crosslinkable acceptor component B that are crosslinkable by a Real Michael Addition (RMA) reaction via the catalyst system, and which catalyst system is able to catalyze the RMA crosslinking reaction at a curing temperature below 140° C.; wherein the catalyst system comprises a (semi) crystalline precursor P, an activator C and optionally a retarder T.
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公开(公告)号：US20240166884A1
公开(公告)日：2024-05-23
申请号：US18425558
申请日：2024-01-29
Applicant: Allnex Netherlands B.V.
Inventor： Richard Hendrikus Gerrit BRINKHUIS , Robert WATSON , Martin BOSMA , Petrus Johannes Maria David ELFRINK , Antonius Johannes Wilhelmus BUSER , Pengcheng YANG , Roberto CAVALIERI , Massimiliano CENSI , Robertino CHINELLATO , Alessandro MINESSO
IPC: C09D5/03 , C08G18/42 , C08G18/60 , C08G18/62 , C08G18/73 , C08G18/75 , C08J3/12 , C08K5/09 , C08K5/105 , C08L33/08 , C08L63/00 , C08L75/06
CPC classification number: C09D5/03 , C08G18/4211 , C08G18/606 , C08G18/6225 , C08G18/73 , C08G18/755 , C08J3/12 , C08K5/09 , C08K5/105 , C08L33/08 , C08L63/00 , C08L75/06 , C08G2150/20 , C08L2312/00
Abstract: The invention relates to powder coating compositions suitable for low temperature powder coating crosslinking typically at curing temperature is between 75 and 140° C. which can be used for powder coating temperature-sensitive substrates like MDF, wood, plastic or temperature sensitive metal alloys.
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公开(公告)号：US20210115292A1
公开(公告)日：2021-04-22
申请号：US17133863
申请日：2020-12-24
Applicant: ALLNEX NETHERLANDS B.V.
Inventor： Richard Hendrikus Gerrit BRINKHUIS , Michael Anthony GESSNER , Dirk Emiel Paula MESTACH , Ramesh SUBRAMANIAN , William Jay DEGOOYER , Ajaya NANDA , Eric Matthew MCCRACKEN , Francesca FALLANI , Monique Alexina MBALLA MBALLA , Martin BOSMA
Abstract: The invention relates to RMA crosslinkable coating composition, a method for the preparation thereof and a resulting coating having easy to clean properties useful in applications like graffiti resistant, sanitisable coatings and in flooring, said composition comprising RMA crosslinkable component with at least 2 RMA donor groups and at least 2 RMA acceptor groups characterized by having fatty components selected from the group of fatty acids, fatty alcohols, fatty amines, fatty thiols and dimeric fatty acid in an amount represented by an Oil Content OC between 0, preferably 4 and 40 wt %, and crosslinking density XLD of at least 1.4 a glass transition Tg of at least 290 in combination providing a easy to clean value ΔE less than 20. The invention also relates to RMA crosslinkable fatty resins for use in RMA crosslinkable top coatings.
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公开(公告)号：US20210115291A1
公开(公告)日：2021-04-22
申请号：US17133832
申请日：2020-12-24
Applicant: ALLNEX NETHERLANDS B.V.
Inventor： Richard Hendrikus Gerrit BRINKHUIS , Michael Anthony GESSNER , Dirk Emiel Paula MESTACH , Ramesh SUBRAMANIAN , William Jay DEGOOYER , Ajaya NANDA , Eric Matthew MCCRACKEN , Francesca FALLANI , Monique Alexina MBALLA MBALLA , Martin BOSMA
Abstract: A RMA crosslinkable coating composition, a method for the preparation thereof and a resulting coating having easy to clean properties useful in applications like graffiti resistant, sanitisable coatings and in flooring, the composition comprising RMA crosslinkable component with at least 2 RMA donor groups and at least 2 RMA acceptor groups characterized by having fatty components selected from the group of fatty acids, fatty alcohols, fatty amines, fatty thiols and dimeric fatty acid in an amount represented by an Oil Content OC between 0, preferably 4 and 40 wt %, and crosslinking density XLD of at least 1.4 a glass transition Tg of at least 290 in combination providing a easy to clean value ΔE less than 20. The invention also relates to RMA crosslinkable fatty resins for use in RMA crosslinkable top coatings.
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Patent Agency Ranking
公开(公告)号：US20200347263A1
公开(公告)日：2020-11-05
申请号：US16934086
申请日：2020-07-21
Applicant: ALLNEX NETHERLANDS B.V.
Inventor： Elwin Aloysius Cornelius Adrianus DE WOLF , Ferry Ludovicus THYS , Richard Hendrikus Gerrit BRINKHUIS , Nicole MANGNUS-VERHAGEN , Antonius Johannes Wilhelmus BUSER
IPC: C09D167/02 , C09D133/06 , C09D167/06 , C08J3/24 , C08L67/02 , C09D17/00
Abstract: The invention relates to a process for the preparation of a RMA crosslinkable composition comprising at least one crosslinkable component comprising reactive components A and B each comprising at least 2 reactive groups wherein the at least 2 reactive groups of component A are acidic protons C—H in activated methylene or methine groups and the at least 2 reactive groups of component B are activated unsaturated groups C═C and base catalyst C and one or more N—H group containing reactivity moderating component D that are also a Michael addition donor reactable with component B under the action of catalyst C, characterized in that the one or more reactivity moderating components D have a melting temperature above 60° C. and is first dissolved in one or more crosslinkable components comprising reactive components A or B and the obtained pre-dissolved product is later mixed with other components of the RMA crosslinkable composition.
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公开(公告)号：US20180127615A1
公开(公告)日：2018-05-10
申请号：US15563952
申请日：2016-04-15
Applicant: ALLNEX NETHERLANDS B.V.
Inventor： Elwin Aloysius Cornelius Adrianus DE WOLF , Ferry Ludovicus THYS , Richard Hendrikus Gerrit BRINKHUIS , Nicole MANGNUS-VERHAGEN , Antonius Johannes Wilhelmus BUSER
IPC: C09D167/02 , C08L67/02 , C09D17/00 , C08J3/24
CPC classification number: C09D167/02 , C08J3/24 , C08J2367/02 , C08J2467/02 , C08L67/02 , C08L2205/025 , C08L2312/00 , C09D17/008 , C09D133/06 , C09D167/06
Abstract: The invention relates to a process for the preparation of a RMA crosslinkable composition comprising at least one crosslinkable component comprising reactive components A and B each comprising at least 2 reactive groups wherein the at least 2 reactive groups of component A are acidic protons C—H in activated methylene or methine groups and the at least 2 reactive groups of component B are activated unsaturated groups C═C and base catalyst C and one or more N—H group containing reactivity moderating component D that are also a Michael addition donor reactable with component B under the action of catalyst C, characterized in that the one or more reactivity moderating components D have a melting temperature above 60° C. and is first dissolved in one or more crosslinkable components comprising reactive components A or B and the obtained pre-dissolved product is later mixed with other components of the RMA crosslinkable composition.
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公开(公告)号：US20210062009A1
公开(公告)日：2021-03-04
申请号：US16956814
申请日：2019-01-25
Applicant: Allnex Netherlands B.V.
Inventor： Richard Hendrikus Gerrit BRINKHUIS , Robert WATSON , Martin BOSMA , Petrus Johannes Maria David ELFRINK , Antonius Johannes Wilhelmus BUSER , Pengcheng YANG , Roberto CAVALIERI , Massimiliano CENSI , Robertino CHINELLATO , Allessandro MINESSO
IPC: C09D5/03 , C08G18/42 , C08G18/60 , C08G18/62 , C08G18/73 , C08G18/75 , C08L63/00 , C08L75/06 , C08L33/08 , C08K5/09 , C08K5/105 , C08J3/12
Abstract: The invention relates to powder coating compositions suitable for low temperature powder coating crosslinking typically at curing temperature is between 75 and 140° C. which can be used for powder coating temperature-sensitive substrates like MDF, wood, plastic or temperature sensitive metal alloys.
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公开(公告)号：US20190161625A1
公开(公告)日：2019-05-30
申请号：US16314483
申请日：2017-07-04
Applicant: ALLNEX Netherlands B.V. , ALLNEX Resins UK Limited , ALLNEX Italy srl
Inventor： William WEAVER , Robert WATSON , Richard Hendrikus Gerrit BRINKHUIS , Martin BOSMA , Paul JONES , Steve WHITE , Dimitrios BAXEVANIS , Roberto CAVALIERI
IPC: C09D5/03 , C09D167/03 , C09D7/63
Abstract: The invention relates to a powder coating composition for low temperature curing that can be used on temperature sensitive substrates and, despite of the low curing temperature, has excellent flow properties and forms a coating with excellent appearance and nevertheless also good mechanical and weathering properties. The invention also relates to an advantageous process for the manufacture of the powder coating composition. Said powder coating composition comprises a poly-acid functional polyester component A, a poly-epoxy functional component B, a poly-anhydride functional component C and a thermosetting curing catalyst D. The invention also relates to a polyester for use in the powder coating compositions according to the invention, in particular for durable powder coatings.
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公开(公告)号：US20180282477A1
公开(公告)日：2018-10-04
申请号：US16002067
申请日：2018-06-07
Applicant: ALLNEX NETHERLANDS B.V.
Inventor： Richard Hendrikus Gerrit BRINKHUIS , Ferry Ludovicus THYS , Elwin Aloysius Cornelius Adrianus DE WOLF
IPC: C08G63/91 , C09D167/02 , C08J3/24 , C08G63/181 , C08K3/013
Abstract: The present invention relates to a crosslinkable composition crosslinkable by Real Michael Addition (RMA) reaction comprising a component with at least 2 activated unsaturated groups (hereafter referred to as the RMA acceptor groups) and a component with at least 2 acidic protons C—H in activated methylene or methine groups (hereafter referred to as the RMA donor groups) which components can react to form a crosslinked network. The composition comprises f. Component(s) A having at least 2 acidic C—H donor groups in activated methylene or methine and having a pKa(A) between 10.5 and 14, g. Component(s) B having at least 2 activated unsaturated acceptor groups, wherein a molar ratio R of acceptor groups to donor groups is between 3:1 to 1:6 and which component(s) B react with component(s) A by Real Michael Addition (RMA) to form a crosslinked network, h. basic component(s) C being a salt of a basic anion X— from an acidic X—H group containing compound wherein X is N, P, O, S or C, iv. in an amount xc between 0.001 and 1 meq/(gr of components A, B, C, D), v. anion X— being a Michael Addition donor reactable with component B and vi. anion X— is characterized by a pKa(C) of the corresponding acid X—H of more than two units lower than the pKa(A) of the majority component A and being lower than 10.5, i. optional component(s) D comprising one or more acidic X′—H groups wherein X′ is N, P, O, S or C, v. X′ being a same or different group as group X in component C, vi. the X′— anion being a Michael Addition donor reactable with component B, vii. the pKa(D) of the X′—H group in component D being more than two units lower than pKa(A) of the majority component A and being lower than 10.5, viii. the equivalent ratio Rd/c of acidic X′—H groups in component D over basic anion X— in component C is between 1% and 5000%,
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