Method of making internal dehydration products of sugar alcohols
    61.
    发明授权
    Method of making internal dehydration products of sugar alcohols 有权
    糖醇内部脱水产物的制备方法

    公开(公告)号:US09315515B2

    公开(公告)日:2016-04-19

    申请号:US14437258

    申请日:2013-10-04

    IPC分类号: C07D493/04 A61K31/34

    CPC分类号: C07D493/04 A61K31/34

    摘要: A process is provided for making isohexides such as isosorbide with reduced color and/or improved color stability on storage, wherein ionic species in the crude dehydration product mixture are chromatographically substantially separated from the remainder of the crude product mixture, then the remainder is refined to yield a finished product for further use or sale.

    摘要翻译: 提供了一种用于制备异辛烷,例如具有降低的颜色的异山梨醇和/或储存时改善的颜色稳定性的异己酸酯,其中粗脱水产物混合物中的离子物质与粗产物混合物的其余部分进行色谱分离,然后将其余物质精制至 生产成品进一步使用或销售。

    Monoallyl, monoglycidyl ethers and bisglycidyl ethers of isohexides
    62.
    发明授权
    Monoallyl, monoglycidyl ethers and bisglycidyl ethers of isohexides 有权
    单烯丙基,单缩水甘油醚和异己烯的双缩水甘油醚

    公开(公告)号:US09290509B2

    公开(公告)日:2016-03-22

    申请号:US14401143

    申请日:2013-06-10

    发明人: Kenneth Stensrud

    IPC分类号: C07D493/04

    CPC分类号: C07D493/04

    摘要: An improved, high yielding process is disclosed for making bisglycidyl ether derivatives of isosorbide, isomannide and/or isoidide, wherein up to quantitative yields overall are demonstrated. In another related aspect, a process is disclosed for making novel monoallyl, monoglycidyl ether derivatives or a combination of monoallyl, monoglycidyl ether derivatives and bisglycidyl ether derivatives via the same diallyl isohexide intermediate.

    摘要翻译: 公开了一种改进的高产率方法,用于制备异山梨醇,异烟肼和/或异氰酸酯的双缩水甘油醚衍生物,其中总体上达到定量产率。 在另一相关方面,公开了通过相同的二烯丙基异己烯中间体制备新的单烯丙基,单缩水甘油醚衍生物或单烯丙基,单缩水甘油醚衍生物和双缩水甘油醚衍生物的组合的方法。

    COMPOUNDED SURFACE TREATED CARBOXYALKYLATED STARCH POLYCRYLATE COMPOSITES
    65.
    发明申请
    COMPOUNDED SURFACE TREATED CARBOXYALKYLATED STARCH POLYCRYLATE COMPOSITES 审中-公开
    化合物表面处理的羧甲基纤维素聚酰胺复合材料

    公开(公告)号:US20150352520A1

    公开(公告)日:2015-12-10

    申请号:US14399013

    申请日:2013-04-19

    摘要: A dual-surface treated composite superabsorbent particle comprising a polycarboxylate polymer (e.g., saponified polyacrylamide) and a carboxylated starch polymer is disclosed. The surface of the particle is cross linked through esterification with a C2-C4 polyol exemplified with glycerol. In addition, the surface region is crosslinked through ionic bonds with a trivalent metal ion exemplified with aluminum. In a critical method of making, the acidification of the surface with the polyol occurs prior to treatment with the trivalent metal ion, which results is a hybrid particle that can include up to about 40% of carboxymethyl starch yet exhibit a FSC of at least 47 g/g, a CRC of at least 27 g/g, an AUL of at least 18 g/g under a load of 0.7 psi, and a SFR of at least 180 ml/min. Also disclosed is a method of making that includes a surface esterification prior to aluminum treatment.

    摘要翻译: 公开了一种包含多羧酸盐聚合物(例如皂化聚丙烯酰胺)和羧化淀粉聚合物的双表面处理复合超吸收颗粒。 颗粒的表面通过酯化与C2-C4多元醇交联,以甘油为例。 此外,表面区域通过离子键与以铝为例列举的三价金属离子交联。 在制备的关键方法中,用三元金属离子处理之前,用多元醇进行表面酸化发生,这是一种杂化颗粒,其可以包括高达约40%的羧甲基淀粉,但表现出至少47的FSC g / g,至少27g / g的CRC,在0.7psi负载下至少18g / g的AUL和至少180ml / min的SFR。 还公开了一种制备方法,其包括在铝处理之前的表面酯化。

    Esterification of 2,5-Furan-Dicarboxylic Acid
    67.
    发明申请
    Esterification of 2,5-Furan-Dicarboxylic Acid 有权
    2,5-呋喃二羧酸的酯化

    公开(公告)号:US20150315166A1

    公开(公告)日:2015-11-05

    申请号:US14650586

    申请日:2013-12-09

    IPC分类号: C07D307/68 C12P17/04

    摘要: A method of making a furan dicarboxylate by means of reacting 2,5-furan dicarboxylic acid (FDCA) with an alcohol or mixture of alcohols in a CO2-predominant atmosphere without the presence of any other acid catalyst is described. The reaction is conducted under conditions that correspond to either supercritical, critical or near-critical temperatures and pressures for the alcohol species and/or CO2 gas.

    摘要翻译: 描述了通过在不含任何其它酸催化剂的情况下,在二氧化碳主导气氛中使2,5-呋喃二羧酸(FDCA)与醇或醇的混合物反应制备呋喃二羧酸酯的方法。 反应在对应于醇物质和/或CO 2气体的超临界,临界或近临界温度和压力的条件下进行。

    Removal of organic salts from bio-derived glycol products of polyol hydrogenolysis
    68.
    发明授权
    Removal of organic salts from bio-derived glycol products of polyol hydrogenolysis 有权
    从多元醇氢解的生物衍生的二醇产物中除去有机盐

    公开(公告)号:US09174902B2

    公开(公告)日:2015-11-03

    申请号:US14419549

    申请日:2013-08-21

    摘要: A method for reducing contaminants in the production of a bio-derived glycol product of polyol hydrogenolysis is described. The method involves subjecting an aqueous, polyol product mixture (from the hydrogenolysis conversion of biologically-derived carbohydrate feedstock) to ion-exclusion chromatography to separate and reduce impurities from an eluant fraction containing a desired product, and distilling the eluant fraction to yield the desired product (e.g., propylene glycol or ethylene glycol). The reaction product mixture can be introduced into a continuous ion-exclusion chromatography system to reduce the impurities and produce in a high-throughput manner a finished otherwise commercially acceptable glycol product.

    摘要翻译: 描述了一种用于减少多元醇氢解的生物衍生的二醇产物生产中的污染物的方法。 该方法包括使水性多元醇产物混合物(来自生物衍生的碳水化合物原料的氢解转化)经受离子排阻色谱以从含有所需产物的洗脱液组分中分离和减少杂质,并蒸馏洗脱剂级分以产生所需的 产品(例如丙二醇或乙二醇)。 可以将反应产物混合物引入连续离子排阻色谱系统中以减少杂质并以高通量方式产生成品的商业上可接受的二醇产物。

    HYDROGENOLYSIS CATALYSTS AND USES THEREOF
    70.
    发明申请
    HYDROGENOLYSIS CATALYSTS AND USES THEREOF 有权
    氢解催化剂及其用途

    公开(公告)号:US20150290628A1

    公开(公告)日:2015-10-15

    申请号:US14436372

    申请日:2013-10-16

    摘要: A hydrogenation catalyst comprising nickel, rhenium, and cadmium is disclosed. Process of using hydrogenation catalyst for producing propylene glycol from polyol feedstock are also disclosed. The present invention relates generally to catalysts and more particularly, to catalysts having an enhanced ability to produce propylene glycol from sugar alcohols while reducing the production of by-products.

    摘要翻译: 公开了一种包含镍,铼和镉的氢化催化剂。 还公开了使用氢化催化剂从多元醇原料生产丙二醇的方法。 本发明一般涉及催化剂,更具体地说,涉及具有增强从糖醇生产丙二醇的能力同时减少副产物生产的催化剂。