公开(公告)号：US11554964B2

公开(公告)日：2023-01-17

申请号：US17058338

申请日：2019-07-26

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Robert McGuire ,  Ulrich Mueller ,  Alexander Kromer

IPC: C01B39/44 ,  C01B39/04 ,  F01N3/20

Abstract: The present invention relates to a process for preparing a zeolitic material having a framework type FER and having a framework structure comprising silicon, aluminum, and oxygen, said process comprising (i) preparing an aqueous synthesis mixture comprising water; a zeolitic material having a framework type other than FER and having a framework structure comprising silicon, aluminum, and oxygen; a source of silicon other than the zeolitic material having a framework type other than FER; an organic structure directing agent comprising piperidine; a source of an alkali metal; and a source of a base; (ii) subjecting the aqueous synthesis mixture prepared according to (i) to hydrothermal synthesis conditions comprising heating the synthesis mixture to a temperature in the range of from 140 to 190° C. and keeping the synthesis mixture at a temperature in this range under autogenous pressure, obtaining a mother liquor comprising a solid material which comprises the zeolitic material having a framework type FER.

公开(公告)号：US20220339611A1

公开(公告)日：2022-10-27

申请号：US17761674

申请日：2020-09-18

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Trees Maria De Baerdemaeker ,  Ulrich Mueller ,  Feng-Shou Xiao ,  Xiangju Meng ,  Qinming Wu

IPC: B01J29/70 ,  C01B33/26 ,  B01J37/04 ,  B01J37/00 ,  B01J37/03 ,  B01J37/06 ,  B01J37/02 ,  B01J37/08 ,  B01J37/30 ,  B01J20/18 ,  B01J20/30 ,  C07C1/24

Abstract: A zeolitic material having the ITH framework structure type.A process for the preparation of a zeolitic material having the ITH framework structure type, the process comprising: (1) preparing a mixture comprising one or more specific organotemplates as structure direct-ing agents, one or more sources of YO2, optionally one or more sources of X2O3, seed crystals, and a solvent system, wherein Y is tetravalent element and X is a trivalent ele-ment,(2) heating the mixture obtained in (1) for crystallizing a zeolitic material having the ITH framework structure type comprising YO2 and optionally X2O3 in its framework structure; wherein the one or more organotemplates comprise a specific polymeric cation.

公开(公告)号：US20220298019A1

公开(公告)日：2022-09-22

申请号：US17596209

申请日：2020-06-05

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Feng-Shou Xiao ,  Xiangju Meng ,  Qinming Wu ,  Ulrich Mueller ,  Toshiyuki Yokoi ,  Weiping Zhang ,  Ute Kolb ,  Bernd Marler ,  Dirk De Vos ,  Xin Hong

IPC: C01B39/46 ,  C07C1/20

Abstract: The present invention relates to a zeolitic material having the IWR type framework structure, wherein the zeolitic material comprises YO2 and X2O3 in its framework structure, wherein Y is a tetravalent element and X is a trivalent element, and wherein the framework structure of the zeolitic material comprises less than 5 weight-% weight-% of Ge calculated as GeO2 and based on 100 weight-% weight-% of YO2 contained in the framework structure, and less than 5 weight-% weight-% of B calculated as B2O3 and based on 100 weight-% weight-% of X2O3 contained in the framework structure. Further, the present invention relates to a process for preparing a zeo-litic material having the IWR type framework structure, wherein the zeolitic material comprises YO2 and X2O3 in its framework structure, wherein Y is a tetravalent element and X is a trivalent element.

公开(公告)号：US11351525B2

公开(公告)日：2022-06-07

申请号：US16462430

申请日：2017-12-20

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Hans-Juergen Luetzel ,  Georg Uhl ,  Joaquim Henrique Teles ,  Dominic Riedel ,  Daniel Urbanczyk ,  Ulrike Wegerle ,  Markus Weber ,  Nicolai Tonio Woerz ,  Christian Mueller ,  Ruediger Schmitt ,  Xiana Romani Fernandez ,  Harald Wuerz

IPC: B01J29/70 ,  B01J35/02 ,  B01J37/00 ,  B01J37/02 ,  B01J37/10

Abstract: Use of an acid-treated titanium-containing zeolitic material having framework type MWW for preparing a composition having a relative plasticity of less than 1.

公开(公告)号：US11110442B2

公开(公告)日：2021-09-07

申请号：US16997038

申请日：2020-08-19

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Hans-Juergen Luetzel ,  Joaquim Henrique Teles ,  Dominic Riedel ,  Daniel Urbanczyk ,  Ulrike Wegerle ,  Markus Weber ,  Nicolai Tonio Woerz ,  Christian Mueller

IPC: B01J29/89 ,  B01J29/70 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  B01J37/08 ,  C01B39/02 ,  C01B39/06 ,  C01B39/12 ,  C07D301/12

Abstract: A process for preparing a molding comprising zinc and a titanium-containing zeolitic material having framework type MWW, comprising (i) providing a molding comprising a titanium-containing zeolitic material having framework type MWW; (ii) preparing an aqueous suspension comprising a zinc source and the molding comprising a titanium-containing zeolitic material having framework type MWW prepared in (i); (iii) heating the aqueous suspension prepared in (ii) under autogenous pressure to a temperature of the liquid phase of the aqueous suspension in the range of from 100 to 200° C., obtaining an aqueous suspension comprising a molding comprising zinc and a titanium-containing zeolitic material having framework type MWW; (iv) separating the molding comprising zinc and a titanium-containing zeolitic material having framework type MWW from the liquid phase of the suspension obtained in (iii).

公开(公告)号：US10442697B2

公开(公告)日：2019-10-15

申请号：US16007724

申请日：2018-06-13

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Hans-Juergen Luetzel ,  Georg Uhl ,  Robert Bayer ,  Regina Vogelsang ,  Robert Schlosser ,  Franky Ruslim ,  Pawel Czajka

IPC: C01B39/12 ,  B01J29/89 ,  B01J29/86 ,  C01B39/48 ,  B01J29/70 ,  C01B39/08 ,  C01B37/00 ,  B01J37/00 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/10 ,  C01B39/46

Abstract: A process for preparing an aluminum-free boron containing zeolitic material comprising the framework structure MWW (BMWW), comprising (a) hydrothermally synthesizing the BMWW from a synthesis mixture containing water, a silicon source, a boron source, and an MWW template compound obtaining the BMWW in its mother liquor, the mother liquor having a pH above 9; (b) adjusting the pH of the mother liquor, obtained in (a) and containing the BMWW, to a value in the range of from 6 to 9; (c) separating the BMWW from the pH-adjusted mother liquor obtained in (b) by filtration in a filtration device.

公开(公告)号：US10434503B2

公开(公告)日：2019-10-08

申请号：US15030754

申请日：2014-10-22

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Hans-Juergen Luetzel ,  Joaquim Henrique Teles ,  Dominic Riedel ,  Bianca Seelig ,  Daniel Urbanczyk ,  Ulrike Wegerle ,  Michael Hesse ,  Andreas Walch ,  Volker Bendig ,  Veit Stegmann ,  Henning Althoefer ,  Boris Gaspar ,  Frank Stallmach ,  Anne Kristin Pusch

IPC: B01J20/18 ,  B01J29/89 ,  C01B39/40 ,  B01J29/40 ,  B01J39/14 ,  B01J29/035 ,  B01J35/10 ,  B01J37/00 ,  C01B39/08 ,  C01B39/02 ,  B01J20/28 ,  B01J20/30 ,  B01J35/00 ,  B01J37/10 ,  B01J35/02

Abstract: The present invention relates to A process for the production of a molding, comprising (I) providing a zeolitic material; (II) mixing the zeolitic material provided in step (I) with one or more binders; (III) kneading of the mixture obtained in step (II); (IV) molding of the kneaded mixture obtained in step (III) to obtain one or more moldings; (V) drying of the one or more moldings obtained in step (IV); and (VI) calcining of the dried molding obtained in step (V); wherein the zeolitic material provided in step (I) displays a water adsorption ranging from 1 to 15 wt.-% when exposed to a relative humidity of 85%, as well as to a molding obtainable or obtained according to the inventive process in addition to a molding per se and to their respective use.

公开(公告)号：US10316007B2

公开(公告)日：2019-06-11

申请号：US15521924

申请日：2015-10-27

Applicant: BASF SE ,  Dow Global Technologies LLC

Inventor： Joaquim Henrique Teles ,  Dominic Riedel ,  Bianca Seelig ,  Philip Kampe ,  Markus Weber ,  Alexander Schroeder ,  Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Daniel Urbanczyk ,  Meinolf Weidenbach ,  Werner J. Witzl ,  Holger Baer

IPC: C07D301/12 ,  B01D3/14 ,  C07D301/32 ,  C07D303/04

Abstract: A continuous process for preparing propylene oxide proceeds by (a) reacting propene with hydrogen peroxide in a reaction apparatus in the presence acetonitrile as solvent, obtaining a stream S0 containing propylene oxide, acetonitrile, water, at least one further component B; (b) separating propylene oxide from S0, obtaining stream S1 containing acetonitrile, water and B; (c) dividing S1 into streams S2 and S3; (d) subjects S3 to vapor-liquid fractionation in a first fractionation unit, obtaining vapor fraction stream S4a being depleted, relative to S3, of at least one of B and obtaining liquid bottoms stream S4b, and subjecting at least part of vapor fraction stream S4a to vapor-liquid fractionation in a second fractionation unit, obtaining vapor fraction stream S4c and liquid bottoms stream S4 being depleted, relative to S4a, of at least one of B; (e) recycling at least a portion of S4 to (a).

公开(公告)号：US10196276B2

公开(公告)日：2019-02-05

申请号：US15316220

申请日：2015-06-03

Applicant: BASF SE

Inventor： Stefan Maurer ,  Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Xiangju Meng ,  Feng-Shou Xiao ,  Yeqing Wang

IPC: C01B39/48 ,  C01B39/12 ,  B01D15/36 ,  B01D53/86 ,  B01J20/18 ,  B01J29/86

Abstract: The present invention relates to a process for the production of a boron-containing zeolitic material having an MWW framework structure comprising YO2 and B2O3, wherein Y stands for a tetravalent element, wherein said process comprises (a) providing a mixture comprising one or more sources for YO2, one or more sources for B2O3, one or more organotemplates, and seed crystals, (b) crystallizing the mixture obtained in (a) for obtaining a layered precursor of the boron-containing MWW-type zeolitic material, (c) calcining the layered precursor obtained in (b) for obtaining the boron-containing zeolitic material having an MWW framework structure, wherein the one or more organotemplates have the formula (I): R1R2R3N, wherein R1 is (C5-C8)cycloalkyl, and wherein R2 and R3 are independently from each other H or alkyl, as well as to a synthetic boron-containing zeolite which is obtainable and/or obtained according to the inventive process as well as to its use.

公开(公告)号：US10195598B2

公开(公告)日：2019-02-05

申请号：US15550581

申请日：2016-02-12

Applicant: BASF SE ,  Dow Global Technologies LLC

Inventor： Dominic Riedel ,  Joaquim Henrique Teles ,  Daniel Urbanczyk ,  Ulrike Wegerle ,  Luise Spiske ,  Andrei-Nicolae Parvulescu ,  Alexander Schroeder ,  Ulrich Mueller ,  Meinolf Weidenbach ,  Werner J. Witzl

IPC: B01J29/89 ,  B01J38/12 ,  B01J38/48 ,  B01J29/90 ,  B01J35/02 ,  B01J35/10 ,  C07D301/12 ,  C01B39/08

Abstract: The invention relates to process for the regeneration of a catalyst comprising a titanium containing zeolite as catalytically active material comprising a stage comprising introducing a feed stream comprising propene, hydrogen peroxide or a hydrogen peroxide source, and an organic solvent into a reactor containing a catalyst comprising the titanium containing zeolite, subjecting the feed stream in the reactor to epoxidation conditions in the presence of the catalyst, removing a product steam comprising propylene oxide and the organic solvent from the reactor, stopping introducing the feed stream, washing the catalyst with a liquid aqueous system and calcining the washed catalyst.