公开(公告)号：US12157674B2

公开(公告)日：2024-12-03

申请号：US17480364

申请日：2021-09-21

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Ulrich Müller ,  Stefan Maurer ,  Yu Dai ,  Feng-Shou Xiao ,  Xiangju Meng ,  Yeqing Wang

IPC: C01B37/00 ,  B01J20/10 ,  B01J20/30 ,  B01J29/70 ,  B01J29/86 ,  B01J37/00 ,  B01J37/02 ,  B01J37/03 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/30 ,  C01B39/12

Abstract: The present invention relates to a process for the production of a zeolitic material having an MWW framework structure comprising YO2 and B2O3, wherein Y stands for a tetravalent element, said process comprising (i) preparing a mixture comprising one or more sources for YO2, one or more sources for B2O3, one or more organotemplates, and seed crystals, (ii) crystallizing the mixture obtained in (i) for obtaining a layered precursor of the MWW framework structure, (iii) calcining the layered precursor obtained in (ii) for obtaining the zeolitic material having an MWW framework structure, wherein the one or more organotemplates have the formula (I) R1R2R3N  (I) wherein R1 is (C5-C8)cycloalkyl, and wherein R2 and R3 are independently from each other H or alkyl, and wherein the mixture prepared in (i) and crystallized in (ii) contains 35 wt.-% or less of H2O based on 100 wt.-% of YO2 contained in the mixture prepared in (i) and crystallized in (ii), as well as to a synthetic boron-containing zeolite which is obtainable and/or obtained according to the inventive process and to its use.

公开(公告)号：US11529620B2

公开(公告)日：2022-12-20

申请号：US17057970

申请日：2019-06-18

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Robert McGuire ,  Ulrich Mueller ,  Xiangju Meng ,  Feng-Shou Xiao ,  Toshiyuki Yokoi ,  Dirk De Vos ,  Bernd Marler ,  Hermann Gies ,  Ute Kolb ,  Weiping Zhang

IPC: C01B39/02 ,  B01J29/76 ,  B01D53/94 ,  B01J35/10 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/30 ,  C01B39/48

Abstract: The present invention relates to a process for the preparation of a zeolitic material SiO2 and X2O3 in its framework structure, wherein X stands for a trivalent element, wherein said process comprises interzeolitic conversion of a first zeolitic material comprising SiO2 and X2O3 in its framework structure, wherein the first zeolitic material has an FER-, TON-, MTT-, BEA-, MEL-, MWW-, MFS-, and/or MFI-type framework structure to a second zeolitic material comprising SiO2 and X2O3 in its framework structure, wherein the second zeolitic material obtained in (2) has a different type of framework structure than the first zeolitic material. Furthermore, the present invention relates to a zeolitic material per se as obtainable and/or obtained according to the inventive process and to its use, in particular as a molecular sieve, as an adsorbent, for ion-exchange, or as a catalyst and/or as a catalyst support.

公开(公告)号：US20230150827A1

公开(公告)日：2023-05-18

申请号：US17917331

申请日：2021-03-23

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Tress Maria De Baerdemaeker ,  Ute Kolb ,  Bernd Marler ,  Feng-Shou Xiao ,  Toshiyuki Yokoi ,  Weiping Zhang ,  Dirk De Vos ,  Xiangju Meng

IPC: C01B39/12 ,  C01B39/04

CPC classification number: C01B39/12 ,  C01B39/04 ,  C01P2002/77 ,  C01P2002/76 ,  C01P2002/72

Abstract: The present invention relates to a crystalline material having a framework structure comprising O and one or more tetravalent elements Y, and optionally comprising one or more trivalent elements X, wherein the crystalline material displays a crystallographic unit cell of the monoclinic space group C2, wherein the unit cell parameter a is in the range of from 14.5 to 20.5 Å, the M unit cell parameter b is in the range of from 14.5 to 20.5 Å, the unit cell parameter c in the range of from 11.5 to 17.5 Å and the unit cell parameter β is in the range of from 109 to 118°, wherein the framework density is in the range of from 11 to 23 T-atoms/1000 Å3 wherein the framework structure comprises 12 membered rings, and wherein the framework structure displays a 2-dimensional channel e dimensionality of 12 membered ring channels. The present invention further relates to a process for the production of said material, as N well as to its use, in particular as a catalyst or catalyst component.

公开(公告)号：US11072535B2

公开(公告)日：2021-07-27

申请号：US16631911

申请日：2018-08-03

Applicant: BASF SE

Inventor： Mathias Feyen ,  Ulrich Mueller ,  Xinhe Bao ,  Weiping Zhang ,  Dirk De Vos ,  Hermann Gies ,  Feng-Shou Xiao ,  Toshiyuki Yokoi ,  Ute Kolb ,  Bernd Marler ,  Yong Wang ,  Trees De Baerdemaeker ,  Chuan Shi ,  Xiulian Pan ,  Xiangju Meng

IPC: C01B39/46 ,  B01J29/76 ,  C01B39/02

Abstract: A zeolitic material having framework type CHA, comprising a transition metal M and an alkali metal A, and having a framework structure comprising a tetravalent element Y, a trivalent element X and O, wherein the transition metal M is a transition I metal of groups 7 to 12 of the periodic table, A is one or more of K and Cs, Y is one or more of Si, Ge, Ti, Sn and Zr, and X is one or more of Al, B, Ga and In. A process for preparing such a zeolitic material. Use of such a zeolitic material.

公开(公告)号：US10793443B2

公开(公告)日：2020-10-06

申请号：US16202918

申请日：2018-11-28

Applicant: BASF SE

Inventor： Stefan Maurer ,  Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Xiangju Meng ,  Feng-Shou Xiao ,  Yeqing Wang

IPC: C01B39/12 ,  C01B39/48 ,  B01J29/86 ,  B01J20/18 ,  B01D15/36 ,  B01D53/86

Abstract: The present invention relates to a process for the production of a boron-containing zeolitic material having an MWW framework structure comprising YO2 and B2O3, wherein Y stands for a tetravalent element, wherein said process comprises(a) providing a mixture comprising one or more sources for YO2, one or more sources for B2O3, one or more organotemplates, and seed crystals,(b) crystallizing the mixture obtained in (a) for obtaining a layered precursor of the boron-containing MWW-type zeolitic material,(c) calcining the layered precursor obtained in (b) for obtaining the boron-containing zeolitic material having an MWW framework structure,wherein the one or more organotemplates have the formula (I) R1R2R3N  (I) wherein R1 is (C5-C8)cycloalkyl, and wherein R2 and R3 are independently from each other H or alkyl, as well as to a synthetic boron-containing zeolite which is obtainable and/or obtained according to the inventive process as well as to its use.

公开(公告)号：US10301185B2

公开(公告)日：2019-05-28

申请号：US15518945

申请日：2015-10-15

Applicant: BASF SE

Inventor： Stefan Maurer ,  Ulrich Müller ,  Feng-Shou Xiao ,  Xiangju Meng ,  Qinming Wu

IPC: B01J29/70 ,  C01B39/48 ,  B01J29/18 ,  C01B39/20 ,  C01B39/26 ,  C01B39/04 ,  B01J29/08 ,  B01J29/40 ,  B01J29/65 ,  C01B37/02 ,  C01B39/08 ,  C01B39/40

Abstract: The present invention relates to a process for the preparation of a zeolitic material comprising YO2 in its framework structure, wherein Y stands for a tetravalent element, wherein said process comprises the steps of: (1) providing a mixture comprising one or more sources for YO2, one or more fluoride containing compounds, and one or more structure directing agents; (2) crystallizing the mixture obtained in step (1) for obtaining a zeolitic material comprising YO2 in its framework structure; wherein the mixture provided in step (1) and crystallized in step (2) contains 35 wt.-% or less of H2O based on 100 wt.-% of YO2 contained in the mixture provided in step (1) and crystallized in step (2), as well as to a zeolitic material comprising YO2 in its framework structure obtainable and/or obtained according to said process, and to a zeolitic material per se comprising SiO2 in its framework structure, wherein in the 29Si MAS NMR spectrum of the as-synthesized zeolitic material the ratio of the total integration value of the peaks associated to Q3 signals to the total integration value of the peaks associated to Q4 signals is in the range of from 0:100 to 20:80, including the use of the aforementioned zeolitic materials.

公开(公告)号：US20220106192A1

公开(公告)日：2022-04-07

申请号：US17423590

申请日：2020-01-21

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Feng-Shou Xiao ,  Xiangju Meng ,  Qinming Wu ,  Yu Dai ,  Stefan Maurer ,  Ulrich Mueller ,  Hao XU

IPC: C01B39/48

Abstract: A process for preparing an oxidic material comprising a zeolitic material having framework type AEI and a framework structure comprising a tetravalent element Y, a trivalent element X, and O, the process comprising preparing a synthesis mixture comprising water, a source of Y, a source of X comprising sodium, an AEI framework structure directing agent, and a source of sodium other than the source of X; and heating the synthesis mixture obtained from (i) to a temperature in the range of from 100 to 180° C. and keeping the synthesis mixture under autogenous pres-sure at a temperature in this range for a time in the range of at least 6 h, obtaining the oxidic material comprising a zeolitic material having framework type AEI and a framework structure comprising a tetravalent element Y, a trivalent element X, and O, comprised in its mother liquor; wherein the AEI framework structure directing agent according to (i) comprises a N, N-diethyl-2,6-dimethylpiperidinium cation.

公开(公告)号：US11219886B2

公开(公告)日：2022-01-11

申请号：US17047239

申请日：2019-05-23

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Robert McGuire ,  Ulrich Mueller ,  Weiping Zhang ,  Xiangju Meng ,  Feng-Shou Xiao ,  Toshiyuki Yokoi ,  Hermann Gies ,  Bernd Marler ,  Ute Kolb ,  Dirk De Vos

IPC: B01D53/94 ,  B01J29/70 ,  B01J29/72 ,  B01J29/76 ,  B01J37/00 ,  B01J37/06 ,  B01J37/08 ,  B01J37/30 ,  B01J29/80 ,  B01J29/06

Abstract: The present invention relates to a rare earth element containing zeolitic material having a framework structure selected from the group consisting of AEI, AFT, AFV, AFX, AVL, CHA, EMT, GME, KFI, LEV, LTN, and SFW, including mixtures of two or more thereof, the framework structure of the zeolitic material comprising SiO2 and X2O3, wherein X stands for a trivalent element, wherein the zeolitic material displays an SiO2:X2O molar ratio in the range of from 2 to 20, and wherein the zeolitic material contains one or more rare earth elements as counter-ions at the ion exchange sites of the framework structure. Furthermore, the present invention relates to a process for the production of the inventive rare earth element containing zeolitic material as well as to the use of the inventive rare earth element containing zeolitic material.

公开(公告)号：US11155467B2

公开(公告)日：2021-10-26

申请号：US16330592

申请日：2017-09-05

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Stefan Maurer ,  Yu Dai ,  Feng-Shou Xiao ,  Xiangju Meng ,  Yeqing Wang

IPC: C01B37/00 ,  B01J20/10 ,  B01J29/70 ,  B01J29/86 ,  B01J37/08 ,  B01J37/30 ,  C01B39/12 ,  B01J20/30 ,  B01J37/00 ,  B01J37/02 ,  B01J37/03 ,  B01J37/04 ,  B01J37/06

Abstract: Described herein is a process for producing a zeolitic material having an MWW framework structure containing YO2 and B2O3, in which Y stands for a tetravalent element. The process includes the steps of (i) preparing a mixture containing one or more sources for YO2, one or more sources for B2O3, one or more organotemplates, and seed crystals, (ii) crystallizing the mixture obtained in (i) for obtaining a layered precursor of the MWW framework structure, and (iii) calcining the layered precursor obtained in (ii) for obtaining the zeolitic material having an MWW framework structure. Also disclosed herein are synthetic boron-containing zeolites obtain by the process and uses thereof.

公开(公告)号：US20220339611A1

公开(公告)日：2022-10-27

申请号：US17761674

申请日：2020-09-18

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Trees Maria De Baerdemaeker ,  Ulrich Mueller ,  Feng-Shou Xiao ,  Xiangju Meng ,  Qinming Wu

IPC: B01J29/70 ,  C01B33/26 ,  B01J37/04 ,  B01J37/00 ,  B01J37/03 ,  B01J37/06 ,  B01J37/02 ,  B01J37/08 ,  B01J37/30 ,  B01J20/18 ,  B01J20/30 ,  C07C1/24

Abstract: A zeolitic material having the ITH framework structure type.A process for the preparation of a zeolitic material having the ITH framework structure type, the process comprising: (1) preparing a mixture comprising one or more specific organotemplates as structure direct-ing agents, one or more sources of YO2, optionally one or more sources of X2O3, seed crystals, and a solvent system, wherein Y is tetravalent element and X is a trivalent ele-ment,(2) heating the mixture obtained in (1) for crystallizing a zeolitic material having the ITH framework structure type comprising YO2 and optionally X2O3 in its framework structure; wherein the one or more organotemplates comprise a specific polymeric cation.