Removal of acid gas from a feed gas stream using small pore zeolites containing double-six rings and cages

    公开(公告)号:US10569213B2

    公开(公告)日:2020-02-25

    申请号:US15883406

    申请日:2018-01-30

    Abstract: A method for removing acid gas from feed gas, comprising:alternating input of feed gas between beds of adsorbent particles that comprise zeolite SSZ-98 or SSZ-105; wherein gas contacts one of the beds during an adsorption and tail gas is vented from another bed by desorption; wherein a product gas containing no greater than about 2 Mol % carbon dioxide is produced, and methane and ethane are recovered. A method for removing acid gas, wherein the product gas contains 1 wppm H2S or less. A process for removing acid gas from feed gas, comprising adjusting selectivity of an adsorbent by changing a substitution of ERI phase with LEV phase in an intergrown molecular sieve. A process for removing acid gas from a feed gas, comprising: contacting a feed gas with adsorbent comprising a molecular sieve having a defined intergrowth of an ERI phase and a LEV phase.

    Synthesis of molecular sieve SSZ-35

    公开(公告)号:US10384950B1

    公开(公告)日:2019-08-20

    申请号:US15956963

    申请日:2018-04-19

    Inventor: Dan Xie

    Abstract: A molecular sieve having the framework structure of SSZ-35 is produced using 3,3′-(butane-1,4-diyl)bis(1-methyl-2-propyl-1H-imidazol-3-ium) dications as a structure directing agent.

    Synthesis of molecular sieve SSZ-43

    公开(公告)号:US10384949B1

    公开(公告)日:2019-08-20

    申请号:US15950232

    申请日:2018-04-11

    Inventor: Dan Xie

    Abstract: A molecular sieve having the framework structure of SSZ-43 is produced using one or more of 3,3′-(butane-1,4-diyl)bis(1-methyl-2-propyl-1H-imidazol-3-ium) dications and N,N′-(1,4-phenylenebis(methylene))bis(N,N-diethylethaniminium) dications as a structure directing agent.

    Removal of contaminants from gas using zeolite SSZ-36, zeolite SSZ-39, or zeolite SSZ-45

    公开(公告)号:US10092875B2

    公开(公告)日:2018-10-09

    申请号:US15408533

    申请日:2017-01-18

    Abstract: We provide a method for removing contaminants from a gas, comprising: alternating input of the gas between two or more beds of adsorbent particles that comprise zeolite SSZ-36, zeolite SSZ-39, or zeolite SSZ-45; wherein the gas contacts one of the beds during an adsorption and a tail gas is simultaneously vented from another of the beds by desorption; wherein a contacting pressure is from about 345 kPa to about 6895 kPa and produces a product gas containing no greater than about 2 mol % carbon dioxide, at least about 10 wppm water, at least about 65 mol % of methane recovered from the feed gas, and at least about 25 mol % of ethane recovered from the feed gas; and wherein the tail gas is vented from the feed end of the beds. We also provide a method for removing a contaminant from a gas, wherein the gas contains hydrogen sulfide.

    REMOVAL OF ACID GAS FROM A FEED GAS STREAM USING SMALL PORE ZEOLITES CONTAINING DOUBLE-SIX RINGS AND CAGES

    公开(公告)号:US20180257019A1

    公开(公告)日:2018-09-13

    申请号:US15883406

    申请日:2018-01-30

    Abstract: A method for removing acid gas from feed gas, comprising: alternating input of feed gas between beds of adsorbent particles that comprise zeolite SSZ-98 or SSZ-105; wherein gas contacts one of the beds during an adsorption and tail gas is vented from another bed by desorption; wherein a product gas containing no greater than about 2 Mol % carbon dioxide is produced, and methane and ethane are recovered. A method for removing acid gas, wherein the product gas contains 1 wppm H2S or less. A process for removing acid gas from feed gas, comprising adjusting selectivity of an adsorbent by changing a substitution of ERI phase with LEV phase in an intergrown molecular sieve. A process for removing acid gas from a feed gas, comprising: contacting a feed gas with adsorbent comprising a molecular sieve having a defined intergrowth of an ERI phase and a LEV phase.

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