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73 条记录 (耗时 0.046 秒)

    One pot synthesis of 5,10-dihydrophenazine compounds and 5,10-substituted dihydrophenazines
    64.
    发明授权
    One pot synthesis of 5,10-dihydrophenazine compounds and 5,10-substituted dihydrophenazines 有权
    一锅合成5,10-二氢吩嗪化合物和5,10-取代二氢吩嗪

    公开(公告)号：US06242602B1

    公开(公告)日：2001-06-05

    申请号：US09280396

    申请日：1999-03-29

    申请人： Punam Giri ,  Harlan J. Byker ,  Kelvin L. Baumann

    发明人： Punam Giri ,  Harlan J. Byker ,  Kelvin L. Baumann

    IPC分类号： C07D24146

    CPC分类号： C07D241/48 ,  C07D241/46

    摘要： Dihydrophenazines and bis(dihydrophenazines) are prepared in high yield under commercially viable reaction conditions by reacting a catechol with a 1,2-diaminoaryl compound, wherein either the catechol or the 1,2-diaminoaryl compound is provided in at least 50% molar stoichiometric excess. The product may be oxidized to the corresponding phenazine, but is preferably derivatized at one or both of the 5,10-positions to form a monosubstituted or disubstituted dihydrophenazine or bis(dihydrophenazine). Most preferably, 5,10-dialkyl-5,10-dihydrophenazines are prepared starting from catechol and 1,2-diaminoaryl compound in a one pot synthesis. The products are useful as dyes, and in particular as chromophores in electrochromic systems.

    摘要翻译： 在商业上可行的反应条件下，通过使邻苯二酚与1,2-二氨基芳基化合物反应，以高产率制备二氢苯并嗪和双（二氢苯并嗪），其中儿茶酚或1,2-二氨基芳基化合物以至少50％的摩尔化学计量 过量。 产物可以被氧化成相应的吩嗪，但优选在5,10-位的一个或两个上衍生化，以形成单取代或二取代的二氢吩嗪或双（二氢吩嗪）。 最优选地，在一锅合成中从儿茶酚和1,2-二氨基芳基化合物开始制备5,10-二烷基-5,10-二氢吩嗪。 该产品可用作染料，特别是作为电致变色系统中的发色团。

    Variable transmittance electrochromic devices
    65.
    发明授权
    Variable transmittance electrochromic devices 失效
    可变透射电色变装置

    公开(公告)号：US06211994B1

    公开(公告)日：2001-04-03

    申请号：US09477470

    申请日：2000-01-04

    申请人： Harlan J. Byker

    发明人： Harlan J. Byker

    IPC分类号： G02F1153

    CPC分类号： C07D498/04 ,  B60R1/088 ,  C09K9/02 ,  G01R13/40 ,  G02F1/1521 ,  G02F1/1533 ,  G02F1/157 ,  G02F2001/1502 ,  G02F2001/1512

    摘要： Single-compartment, self-erasing, solution-phase electrochromic devices, solutions of electrochromic compounds for use as media of variable transmittance in such devices, and electrochromic compounds for such solutions are provided. The devices of the invention are surprisingly stable to cycling between light and dark states, have continuously variable transmittance to light as a function of electrical potential applied across the solution in a device, and have transmittance that can be varied over more than a factor of 10, from clear to dark or from dark to clear, in several seconds. Thus, the devices are especially suitable as variable transmittance components of variable transmission light filters, including windows, and variable reflectance mirrors, including anti-glare rearview mirrors in automobiles. Also provided are improved variable reflectance mirrors, wherein transmittance of reflected light is varied by thermochromic, photochromic or electro-optic means and wherein the reduction in transmittance which is required to eliminate perceptible reflection of an object to the eyes of an observer is reduced by disposing the plane of the highly reflective surface of the mirror at an angle with respect to the plane of the surface through which light from the object enters the mirror.

    摘要翻译： 提供单室，自擦除，溶液相电致变色装置，用作这种装置中透射率可变的介质的电致变色化合物的溶液以及用于这种溶液的电致变色化合物。 本发明的装置对于光和暗状态之间的循环是令人惊奇的稳定的，具有连续可变的透射率，作为穿过装置中的溶液施加的电势的函数，并且透射率可以超过10倍 ，从清澈到黑暗或从黑暗到清澈，几秒钟。 因此，这些装置特别适用于包括窗口的可变透光滤光器的可变透射分量，以及包括汽车中的防眩后视镜的可变反射镜。 还提供了改进的可变反射镜，其中反射光的透射率由热致变色，光致变色或电光装置改变，并且其中通过处置以减少物体对观察者的眼睛的可察觉反射所需的透射率的降低 反射镜的高度反射表面的平面相对于表面的平面成角度，通过该平面，来自物体的光进入反射镜。

    Near infrared-absorbing electrochromic compounds and devices comprising same
    66.
    发明授权
    Near infrared-absorbing electrochromic compounds and devices comprising same 失效
    近红外吸收电致变色化合物及包含其的装置

    公开(公告)号：US06193912B1

    公开(公告)日：2001-02-27

    申请号：US09034531

    申请日：1998-03-03

    申请人： Dave Thieste ,  Harlan J. Byker ,  Kelvin Baumann ,  Ramanujan Srinivasa

    发明人： Dave Thieste ,  Harlan J. Byker ,  Kelvin Baumann ,  Ramanujan Srinivasa

    IPC分类号： G02F100

    CPC分类号： C09K9/02 ,  G02F1/1521

    摘要： Electrochromic compounds capable of reversibly attenuating the transmittance of the near infrared portion of the electromagnetic spectrum are provided. These compounds exhibit an energy difference between the singly occupied molecular orbital (SOMO) energy and the highest doubly occupied molecular orbital (HDOMO) energy (ESOMO−EHDOMO) of less than about 3.6 eV. In addition, these compounds have a transition moment of the configuration made up of the HDOMO and SOMO that is “long axis polarized”.

    摘要翻译： 提供能够可逆地衰减电磁光谱的近红外部分的透射率的电致变色化合物。 这些化合物在单独占据的分子轨道（SOMO）能量和低于约3.6eV的最高双重占据的分子轨道（HDOMO）能量（ESOMO-EHDOMO）之间表现出能量差。 此外，这些化合物具有由“长轴极化”的HDOMO和SOMO构成的结构的转变时刻。

    Prismatic variable reflectance mirrors
    68.
    发明授权
    Prismatic variable reflectance mirrors 失效
    棱镜可变反射镜

    公开(公告)号：US5481395A

    公开(公告)日：1996-01-02

    申请号：US174209

    申请日：1993-12-28

    申请人： Harlan J. Byker

    发明人： Harlan J. Byker

    IPC分类号： B60R1/08 ,  C07D498/04 ,  C09K9/02 ,  G01R13/40 ,  G02F1/15 ,  G02F1/153 ,  G02F1/157

    CPC分类号： B60R1/088 ,  C07D498/04 ,  C09K9/02 ,  G01R13/40 ,  G02F1/1521 ,  G02F1/1533 ,  G02F1/157 ,  G02F2001/1502 ,  G02F2001/1512

    摘要： Prismatic variable reflectance mirrors are provided. In the mirrors of the invention, transmittance of reflected light is varied by thermochromic, electrochromic, photochromic or electro-optic means and the reduction in transmittance, which is required to eliminate perceptible reflection of an object to the eyes of an observer, is reduced by disposing the plane of the highly reflective surface of the mirror at an angle with respect to the plane of the surface through which light from the object enters the mirror.

    摘要翻译： 提供棱镜式可变反射镜。 在本发明的反射镜中，通过热变色，电致变色，光致变色或电光装置改变反射光的透射率，并且减少了将物体对观察者的眼睛的可察觉反射消除所需的透射率的降低， 将反射镜的高度反射表面的平面设置成相对于表面的平面成角度，通过该平面，来自物体的光进入反射镜。

    Bipyridinium salt solutions
    69.
    发明授权
    Bipyridinium salt solutions 失效
    双吡啶鎓盐溶液

    公开(公告)号：US5294376A

    公开(公告)日：1994-03-15

    申请号：US720170

    申请日：1991-06-25

    申请人： Harlan J. Byker

    发明人： Harlan J. Byker

    IPC分类号： C07D213/22 ,  C09K9/02 ,  G02F1/15 ,  C07D401/04 ,  C09K9/00 ,  G02B5/30 ,  G02F1/01 ,  G02F1/137

    CPC分类号： C07D213/22 ,  C09K9/02 ,  G02F1/1521 ,  G02F2001/1502 ,  G02F2001/1512

    摘要： The present invention provides solutions of certain 4,4'-bipyridinium salts, such as salts of 1,1'- dibenzyl-2,2',6,6'-tetraalkyl-4,4'-bipyridinium cations. The solutions of the invention are employed as solutions of variable transmittance in solution-phase electrochromic devices, including such devices that are single-compartment and self-erasing. In the solutions of the invention in such devices, the bipyridinium salts are cathodic electrochromic compounds, as reduction of a cation of such a salt causes its molar extinction coefficient at at least one wavelength in the visible range to increase markedly. Electrochromic devices, in which solutions of the invention provide variable transmittance, are, in turn, components of variable transmittance in display devices, windows and other types of light filters, and variable reflectance mirrors, such as those that can be used as dimmable rearview mirrors in motor vehicles.

    摘要翻译： 本发明提供某些4,4'-联吡啶鎓盐，例如1,1'-二苄基-2,2'，6,6'-四烷基-4,4'-联吡啶阳离子的盐的溶液。 本发明的解决方案用作溶液相电致变色装置中可变透射率的解决方案，包括单室和自擦除装置。 在本发明的这种装置的溶液中，联吡啶鎓盐是阴极电致变色化合物，因为这种盐的阳离子的还原使其在可见光范围内的至少一个波长的摩尔消光系数显着增加。 本发明的解决方案提供可变透射率的电致变色装置又是显示装置，窗口和其他类型的滤光器中的可变透射率的组分，以及可用作可调光后视镜的可变反射镜 在机动车辆。