摘要:
The present invention provides an imaging element comprising contiguous to a hydrophilic surface of a support a hydrophobic photosensitive composition comprising a photosensitive acid precursor, an acid-sensitive composition which is capable of undergoing polymerization or cross-linking and a hydrophobic binder characterized in that said imaging element comprises one or more protective layers, at least one of the protective layers being contiguous to the hydrophobic photosensitive composition and being a transfer layer which is capable of adhering to a receptor element.
摘要:
A method for making a heat-sensitive negative-working lithographic printing plate precursor including the steps of providing a support having a hydrophilic surface or which is provided with a hydrophilic layer, and applying onto the support a coating solution including an infrared absorbing agent, hydrophobic thermoplastic polymer particles, a hydrophilic binder, and a polymer including siloxane and/or perfluoroalkyl monomeric units.
摘要:
A heat-sensitive lithographic printing plate precursor is disclosed comprising a polymer which is soluble in an aqueous alkaline solution and which comprises at least one chromophoric moiety having a light absorption maximum in the wavelength range between 400 and 780 nm. Such materials show no dye stain after processing in areas where the coating has been removed by an alkaline developer.
摘要:
A negative-working lithographic printing plate precursor is disclosed comprising on a support having a hydrophilic surface or which is provided with a hydrophilic layer, a coating comprising an infrared absorbing agent, a first layer comprising an aqueous dispersion comprising hydrophobic thermoplastic polymer particles and a first hydrophobic binder, and a second layer located between said first layer and said support which comprises a second hydrophobic binder, characterized in that said first hydrophobic binder is a phenolic resin and said second hydrophobic binder is a polymer comprising at least one sulphonamide group.
摘要:
A positive-working printing plate precursor for wet lithographic printing is disclosed which comprises a support having a hydrophilic surface and a coating comprising a first layer closest to the support, said first layer containing an oleophilic phenolic resin soluble in an aqueous alkaline developer, and a second layer containing an amphyphilic polymer, wherein (c) the second layer is capable of preventing the aqueous alkaline developer from penetrating into the first layer to an extent that substantially no dissolution of unexposed coating occurs upon immersion in the aqueous alkaline developer during a time period t2; (d) and wherein said capability of the second layer of preventing the aqueous alkaline developer from penetrating into the first layer is reduced upon exposure to heat or light to an extent that substantially complete dissolution of exposed coating occurs upon immersion in the aqueous alkaline developer during a time period t1; wherein t2>t1 and t2−t1 is at least 10 seconds; and wherein the amphyphilic polymer is a block- or graft-copolymer comprising (i) a poly(alkylene oxide) block and (ii) a block comprising siloxane and/or perfluorohydrocarbon units.
摘要翻译:公开了用于湿平版印刷的正性印刷版前体,其包含具有亲水表面的载体和包含最靠近载体的第一层的涂层,所述第一层含有可溶于碱性显影液的亲油酚醛树脂,和 第二层含有两亲性聚合物,其中(c)第二层能够防止水性碱性显影剂渗透到第一层中,使得在一段时间内浸入含水碱性显影剂中基本上不会溶解未曝光的涂层 t 2 2; (d),并且其中防止水性碱性显影剂渗透到第一层中的第二层的所述能力在暴露于热或光时减少到在浸入含水碱性显影剂中时基本上完全溶解暴露涂层的程度 时间段t 1< 1>; 其中t 2 2和t 2 -T 1 H 1至少为10秒; 并且其中所述无亲性聚合物是包含(i)聚(环氧烷)嵌段和(ii)包含硅氧烷和/或全氟烃单元的嵌段的嵌段或接枝共聚物。
摘要:
A positive-working printing plate precursor for wet lithographic printing is disclosed which comprises a support having a hydrophilic surface and a coating comprising a first layer closest to the support, said first layer containing an oleophilic phenolic resin soluble in an aqueous alkaline developer, and a second layer containing an amphyphilic polymer, wherein(a) the second layer is capable of preventing the aqueous alkaline developer from penetrating into the first layer to an extent that substantially no dissolution of unexposed coating occurs upon immersion in the aqueous alkaline developer during a time period t2;(b) and wherein said capability of the second layer of preventing the aqueous alkaline developer from penetrating into the first layer is reduced upon exposure to heat or light to an extent that substantially complete dissolution of exposed coating occurs upon immersion in the aqueous alkaline developer during a time period t1;wherein t2>t1 and t2−t1 is at least 10 seconds; and wherein the amphyphilic polymer is a block- or graft-copolymer comprising (i) a poly(alkylene oxide) block and (ii) a block comprising siloxane and/or perfluorohydrocarbon units.
摘要:
A lithographic printing method is disclosed which comprising the steps of providing an imaging material which comprises a support and an image-recording layer that is not removable with a single-fluid ink which comprises an ink phase and a polar phase; image-wise exposure of the image-recording layer to heat or light without substantially ablating said image-recording layer, thereby switching the affinity of the image-recording towards ink or an ink-abhesive fluid and thereby creating a printing master comprising a lithographic image which consists of unexposed areas that have affinity for one phase of said ink phase and polar phase and of exposed areas that have affinity for the other phase of said ink phase and polar phase; printing, wherein the single-fluid ink is supplied to the printing master. The exposed image-recording layer, which normally exhibits a poor differentiation of hydrophilicity or oleophilicity between exposed and non-exposed areas, provides high quality printed copies in combination with the single-fluid ink.
摘要:
According to the present invention there is provided a heat-sensitive material for making lithographic plates comprising in the order given on a support an IR-sensitive oleophilic layer and an ablatable cross-linked hydrophilic layer comprising an inorganic pigment and a hardener, characterized in that the ratio of said inorganic pigment over the hardener is comprised between 95/5 and 75/25 by weight.
摘要:
According to the present invention there is provided a heat mode imaging element for providing a lithographic printing plate consisting of a lithographic base with a hydrophilic surface and a top layer that is sensitive to IR-radiation, comprises a polymer soluble in an aqueous alkaline solution, and is unpenetrable for an aqueous alkaline developer, characterized in that said top layer comprises a polysiloxane surfactant.
摘要:
According to the present invention there is provided a heat-sensitive material for making lithographic plates comprising in the order given on a support an IR-sensitive oleophilic layer and a cross-linked hydrophilic layer comprising an inorganic pigment and a hardener, characterized in that the ratio of said inorganic pigment over the hardener is comprised between 75/25 and 25/75 by weight.