公开(公告)号：US4981833A

公开(公告)日：1991-01-01

申请号：US452650

申请日：1989-12-19

申请人： Kozo Sato

发明人： Kozo Sato

IPC分类号： B41M5/28 ,  B41M5/36 ,  C09B11/00 ,  C09K9/02

CPC分类号： B41M5/286 ,  Y10S428/913 ,  Y10S428/914

摘要： A recording material comprising at least one thermodecoloring type dye represented by formula (I) or formula (II) ##STR1## wherein Ar.sup.1 and AR.sup.2 each represents an aryl group or heteroaryl group; R.sup.1 represents an alkyl group, alkenyl group, aralkyl group, aryl group, or heteroaryl group; A represents an atomic group forming a 5 to 6 member ring; and X.crclbar. represents a residue with an electric charge value of -1; or Ar.sup.1 and Ar.sup.2 bond together to form a ring.

摘要翻译： 包含至少一种由式（I）或式（II）表示的热分解型染料的记录材料其中Ar 1和AR 2各自表示芳基或杂芳基; R1表示烷基，烯基，芳烷基，芳基或杂芳基; A表示形成5至6元环的原子团; X（ - ）表示电荷值为-1的残基; 或Ar 1和Ar 2键合在一起形成环。

公开(公告)号：US4975361A

公开(公告)日：1990-12-04

申请号：US287303

申请日：1988-12-21

申请人： Kozo Sato ,  Hiroshi Hara

发明人： Kozo Sato ,  Hiroshi Hara

IPC分类号： G03C7/00 ,  G03C7/305 ,  G03C8/10

CPC分类号： G03C8/10 ,  G03C7/30547

摘要： A color photographic light-sensitive material comprising a support having thereon at least one layer containing light-sensitive silver salt, wherein the color photographic a light-sensitive material contains at least one image forming compound represented by the following general formula (I):(Dye-X).sub.q -Y (I)wherein Dye, X, q and Y are described in detail below.

摘要翻译： 一种彩色照相感光材料，包括其上具有至少一层含有感光性银盐的载体的载体，其中所述彩色照相感光材料含有至少一种由以下通式（I）表示的成像化合物：（ 染料-X）qY（I）其中染料，X，q和Y在下面详细描述。

公开(公告)号：US4880730A

公开(公告)日：1989-11-14

申请号：US280412

申请日：1988-12-06

申请人： Kozo Sato ,  Yoshisada Nakamura

发明人： Kozo Sato ,  Yoshisada Nakamura

IPC分类号： G03C7/20 ,  G03C1/825 ,  G03C1/83 ,  G03C7/00

CPC分类号： G03C1/83

摘要： A silver halide photographic light-sensitive material comprising a support having thereon at least one colored layer, and the layer can be decolored or lightened upon photographic processing of the photographic light-sensitive material,wherein the colored layer is formed by a process comprising the step of:color developing at least one colorless or light-colored leuco-dyestuff utilizing at least one metal salt of an organic acid.

摘要翻译： 一种卤化银照相感光材料，其包括其上具有至少一个着色层的支撑体，并且该层可以在照相感光材料的照相处理时被脱色或减轻，其中该着色层通过包括步骤 使用至少一种有机酸的金属盐显色至少一种无色或浅色的无色染料。

公开(公告)号：US4864024A

公开(公告)日：1989-09-05

申请号：US154548

申请日：1988-02-10

申请人： Kozo Sato ,  Toru Harada

发明人： Kozo Sato ,  Toru Harada

IPC分类号： B41M5/136 ,  B41M5/145 ,  B41M5/323 ,  B41M5/327 ,  C07D491/048 ,  C09B11/26

CPC分类号： C09B11/26 ,  B41M5/145 ,  B41M5/327

摘要： A new leuco dye is capable of developing into a colored dye which has an absorption band in the near infrared region. The new leuco dye has the following formula (I): ##STR1## wherein each of R.sup.1, R.sup.2 and R.sup.3 independently is hydrogen, an alkyl group, an aralkyl group, a cycloalkyl group or an aryl group; each of X.sup.1 and X.sup.2 independently is oxygen, sulfur or --NR.sup.4 -- (R.sup.4 has the same meaning as for R.sup.1, R.sup.2 and R.sup.3); each of the rings A to E independently is benzene ring or naphthalene ring and may have one or more substituent groups; and each of R.sup.1 to R.sup.4 may have one or more substituent groups. A recording material containing the leuco dye is also disclosed.

摘要翻译： 新的无色染料能够发展成在近红外区域具有吸收带的着色染料。 新的无色染料具有下式（I）：其中R 1，R 2和R 3各自独立地为氢，烷基，芳烷基，环烷基或芳基; X 1和X 2各自独立地为氧，硫或-NR 4 - （R 4具有与R 1，R 2和R 3相同的含义）。 环A至E各自独立地为苯环或萘环，并且可具有一个或多个取代基; 并且R 1至R 4中的每一个可以具有一个或多个取代基。 还公开了含有无色染料的记录材料。

公开(公告)号：US4837142A

公开(公告)日：1989-06-06

申请号：US867121

申请日：1986-05-27

申请人： Kozo Sato ,  Masashi Takeuchi ,  Takeshi Shibata

发明人： Kozo Sato ,  Masashi Takeuchi ,  Takeshi Shibata

IPC分类号： G03C7/00 ,  C09B29/33 ,  G03C8/10 ,  G03C8/12

CPC分类号： G03C8/10 ,  C09B29/337

摘要： A color light-sensitive material is disclosed. The material is comprised of a support having provided thereon at least one image-forming compound represented by formula (I) ##STR1## wherein X, Y, q, and Dye are as defined herein. The light-sensitive material shows excellent yellow dye-transferring properties and provides a yellow dye having excellent light fastness.

公开(公告)号：US4789623A

公开(公告)日：1988-12-06

申请号：US937289

申请日：1986-12-03

申请人： Kozo Sato ,  Hideki Naito

发明人： Kozo Sato ,  Hideki Naito

IPC分类号： G03C7/00 ,  G03C1/42 ,  G03C8/40 ,  G03C5/24

CPC分类号： G03C1/42 ,  Y10S430/156

摘要： A method for forming an image comprising heating in the presence of at least one of a base and a base generating agent, a heat-developable color light-sensitive material which comprises a support having thereon at least: (1) a light-sensitive silver halide, (2) a coupler capable of coupling with an oxidation product of a developing agent, (3) a hydrophilic binder, and (4) at least one compound represented by formula (Z) ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 each represents a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, a cycloalkyl group, an aralkyl group, a hydroxy group, an amino group, a substituted amino group, an alkoxy group, an acylamino group, an alkylsulfonylamino group, an arylsulfonylamino group, an aryl group, a carbamoyl group, a substituted carbamoyl group, a sulfamoyl group, a substituted sulfamoyl group, an acyl group, an acyloxy group, or an alkoxycarbonyl group, or R.sub.1 and R.sub.2, or R.sub.3 and R.sub.4 are connected together to form a ring structure; A represents a hydroxy group, a group capable of providing a hydroxy group upon reaction with a nucleophilic reagent, or the group ##STR2## wherein R.sub.6 and R.sub.7 each represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted cycloalkyl group, or a substituted or unsubstituted aralkyl group, or R.sub.6 and R.sub.7 are connected together to form a heterocyclic group, or when A represents the group ##STR3## at least one combination of R.sub.1 and R.sub.6, and R.sub.3 and R.sub.7 is connected together to form a heterocyclic group; and R.sub.5 represents a substituted or unsubstituted aryl group or a substituted or unsubstituted heterocyclic group.

摘要翻译： 一种用于形成图像的方法，包括在基底和基底发生剂中的至少一种的存在下加热，可热显影的彩色感光材料，其至少包括其上具有的支持体：（1）感光银 卤化物，（2）能够与显影剂的氧化产物偶联的成色剂，（3）亲水性粘合剂，和（4）至少一种由式（Z）表示的化合物，其中R1，R2 ，R 3和R 4各自表示氢原子，卤素原子，烷基，烯基，环烷基，芳烷基，羟基，氨基，取代氨基，烷氧基，酰氨基 基团，烷基磺酰基氨基，芳基磺酰基氨基，芳基，氨基甲酰基，取代的氨基甲酰基，氨磺酰基，取代的氨磺酰基，酰基，酰氧基或烷氧基羰基，或R 1和R 2， 或R3和R4连接在一起形成环结构; A表示羟基，能够与亲核试剂反应而提供羟基的基团，或者其中R6和R7各自表示氢原子，取代或未取代的烷基，取代或未取代的烯基 ，取代或未取代的环烷基或取代或未取代的芳烷基，或者R 6和R 7连接在一起形成杂环基，或者当A代表基团时，R 1和R 6的至少一个组合，以及R 3和 R7连接在一起形成杂环基; R 5表示取代或未取代的芳基或取代或未取代的杂环基。

公开(公告)号：US4775610A

公开(公告)日：1988-10-04

申请号：US866843

申请日：1986-05-27

申请人： Hiroshi Kitaguchi ,  Kozo Sato ,  Masatoshi Kato

发明人： Hiroshi Kitaguchi ,  Kozo Sato ,  Masatoshi Kato

IPC分类号： G03C5/00 ,  G03C1/06 ,  G03C1/43 ,  G03C1/498 ,  G03C5/58 ,  G03C7/00 ,  G03C7/305 ,  G03C8/40 ,  G03C1/62 ,  G03C5/54 ,  G03C7/26

CPC分类号： G03C7/30511 ,  G03C1/43 ,  G03C1/49845 ,  Y10S430/156 ,  Y10S430/158 ,  Y10S430/16 ,  Y10S430/161

摘要： A method for the formation of a photographic image including a heating step, comprising heating a photographic material in the presence of at least one compound selected from those represented by formulae (I) and(II) ##STR1## wherein A represents a non-metallic atomic group forming a carbocyclic aromatic ring or a heterocyclic aromatic ring;X represents a nucleophilic group or a precursor thereof;Q represnts a hydrogen atom or a substituted or unsubstituted alkyl, cycloalkyl, or aryl group; andPUG represents a photographically useful group.

摘要翻译： 一种用于形成包括加热步骤的照相图像的方法，包括在至少一种选自由式（I）和（II）表示的化合物的化合物存在下加热照相材料。 II）其中A表示形成碳环芳环或杂环芳环的非金属原子团; X表示亲核基团或其前体; Q表示氢原子或取代或未取代的烷基，环烷基或芳基; PUG代表摄影有用的组。

公开(公告)号：US4772531A

公开(公告)日：1988-09-20

申请号：US23361

申请日：1987-03-09

申请人： Jiro Tsukahara ,  Kozo Sato

发明人： Jiro Tsukahara ,  Kozo Sato

IPC分类号： G03F7/004 ,  G03C1/498 ,  G03F7/028 ,  G03F7/06 ,  G03C1/68 ,  G03F7/26

CPC分类号： G03F7/0285 ,  Y10S430/114 ,  Y10S430/116 ,  Y10S430/12

摘要： A light-sensitive material comprising a light-sensitive layer which contains silver halide, a reducing agent and a polymerizable compound provided on a support, characterized in that the reducing agent is a hydrazine derivative having the following formula (I) or (II): ##STR1## in which R.sup.1 is a monovalent group selected from the group consisting of hydrogen, an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl group and a heterocyclic group, each of which may have one or more substituent groups; each of R.sup.2 and R.sup.3 independently is an aryl group which may have one or more substituent groups, or R.sup.2 and R.sup.3 form, together with the neighboring carbon, a condensed aromatic ring; R.sup.4 is a monovalent group selected from the group consisting of an alkyl group, an aryl group, an alkoxycarbonyl group and carbamoyl, each of which may have one or more substituent groups; (DEV) is a monovalent group having a function of reducing silver halide; and (LINK) is a divalent linkage group.

摘要翻译： 一种感光材料，其包含含有卤化银的光敏层，还原剂和提供在载体上的可聚合化合物，其特征在于还原剂是具有下式（I）或（II）的肼衍生物： （I）其中R 1是选自氢，烷基，环烷基，烯基，炔基，芳烷基，芳基的一价基团 和杂环基，其各自可以具有一个或多个取代基; R 2和R 3各自独立地为可以具有一个或多个取代基的芳基，或者R 2和R 3与相邻的碳一起形成稠合芳香环; R4是选自烷基，芳基，烷氧基羰基和氨基甲酰基的一价基团，各自可以具有一个或多个取代基; （DEV）是具有还原卤化银功能的一价基团; 和（LINK）是二价连接基团。

公开(公告)号：US4721667A

公开(公告)日：1988-01-26

申请号：US864061

申请日：1986-05-16

申请人： Kozo Sato ,  Tadahisa Sato ,  Takeshi Shibata

发明人： Kozo Sato ,  Tadahisa Sato ,  Takeshi Shibata

IPC分类号： C07D487/04 ,  G03C7/00 ,  G03C8/10 ,  G03C8/12 ,  G03C8/40 ,  G03C1/40 ,  G03C5/54 ,  G03C7/26

CPC分类号： C07D487/04 ,  G03C8/10 ,  G03C8/4033

摘要： A color light-sensitive material is provided, having at least one image forming compound of the following formula (I) on support.(Dye-X).sub.q -Y (I)wherein Dye represents a yellow dye residue represented by the following formula (II) or a dye precursor residue; X represents a bond or a binding group; Y represents a group capable of yielding a difference of diffusibility of a dye component before and after the reaction with a photographic silver salt imagewise having a latent image, corresponding to or reversely corresponding to said photographic silver salt; q is 1 or 2, and when q is 2, Dye-X may be the same or different; ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 may be the same or different and each represents a group selected from a hydrogen atom, a halogen atom, a hydroxyl group, a cyano group, a carboxyl group, or a substituted or unsubstituted alkyl, aralkyl, cycloalkyl, aryl, heterocyclic, alkoxy, aryloxy, amino, acylamino, sulfonylamino, acyl, sulfonyl, carbamoyl, sulfamoyl, ureido, alkylthio or arylthio group; n is an integer of 2 to 4, R.sup.3 may be the same or different; Dye and X are bound to each other via any of said R.sup.1, R.sup.2 and R.sup.3 in the formula (II).

摘要翻译： 提供了一种彩色感光材料，其在载体上具有至少一种下式（I）的成像化合物。 （Dye-X）q-Y（I）其中染料表示由下式（II）表示的黄色染料残基或染料前体残基; X表示键或结合基团; Y表示能够产生与具有潜像的照相银盐反应前后的染料组分的扩散性差异的基团，对应于或相反地对应于所述照相银盐; q为1或2，当q为2时，染料-X可以相同或不同; （II）其中R1，R2和R3可以相同或不同，并且各自表示选自氢原子，卤素原子，羟基，氰基，羧基或取代或未取代的基团 烷基，芳烷基，环烷基，芳基，杂环，烷氧基，芳氧基，氨基，酰氨基，磺酰氨基，酰基，磺酰基，氨基甲酰基，氨磺酰基，脲基，烷硫基或芳硫基; n为2〜4的整数，R3可以相同或不同; 染料和X通过式（II）中的所述R 1，R 2和R 3中的任何一个彼此结合。

公开(公告)号：US4696887A

公开(公告)日：1987-09-29

申请号：US829032

申请日：1986-02-13

申请人： Kozo Sato ,  Hiroshi Kitaguchi ,  Masashi Takeuchi ,  Masaaki Tsukase ,  Masatoshi Kato

发明人： Kozo Sato ,  Hiroshi Kitaguchi ,  Masashi Takeuchi ,  Masaaki Tsukase ,  Masatoshi Kato

IPC分类号： G03C5/00 ,  G03C5/58 ,  G03C7/00 ,  G03C7/305 ,  G03C8/40 ,  G03C5/54 ,  G03C1/06 ,  G03C1/34 ,  G03C5/26

CPC分类号： G03C8/408 ,  G03C7/305 ,  G03C8/4033 ,  Y10S430/158 ,  Y10S430/161

摘要： A novel method for formation of an image comprising a heating step, comprising the heating carried out in the presence of a compound of general formula (I):X--SO.sub.2 (DI) (I)wherein X represents a reducing group capable of reducing a silver salt and capable of being oxidized by heating and in its oxidized state capable of releasing a compound represented by (DI)--SO.sub.2 NH.sub.2 by reaction with a nucleophilic agent; and (DI) represents a development inhibiting group capable of inhibiting the oxidation reduction reaction of the silver salt and a reducing aent.The compound of the formula (I) functions to inhibit development after a certain period of time from the beginning of heat development.The present method provides a stable image with reduced fog and image mottle.

摘要翻译： 一种用于形成图像的新方法，包括加热步骤，其包括在通式（I）的化合物：X-SO 2（DI）（I）的存在下进行的加热，其中X表示可以还原的还原基团 银盐，能够通过与亲核剂反应而通过加热氧化并能够释放由（DI）-SO 2 NH 2表示的化合物的氧化态; 和（DI）表示能够抑制银盐的氧化还原反应和还原的显影抑制基团。 式（I）化合物起到抑制发育开始一段时间后的发育作用。 本方法提供了一种具有降低雾度和图像斑点的稳定图像。