摘要:
A method for continuously processing an image-wise exposed silver halide color photographic material comprising the steps of color developing, bleach-fixing and at least one of washing with water and stabilizing. A replenisher is supplied to the bleach-fix bath to result in an overflow of from 30 to 500 ml/m.sup.2 of the photographic material processed. The bleach-fixing step further comprises collecting the bleach-fix overflow, regenerating the collected bleach-fix bath overflow by adding thereto a regenerant to produce a regenerated bleach-fix bath, and reusing the regenerated bleach-fix bath as a replenisher to the bleach-fix bath. The regeneration rate defined as the amount of bleach-fix overflow used for regeneration divided by the total amount of overflow multiplied by 100% is more than 80%. The photographic layers of the silver halide color photographic material have a degree of swelling of from about 2.5 to 4.0. The silver halide color photographic material further has a silver coverage of less than about 0.8 g/m.sup.2. The above described method solves problems of poor desilvering, inadequate color reproduction and undesirable cyan thermal discoloration which generally accompany reuse of the bleach-fixing bath.
摘要翻译:一种用于连续处理图像曝光的卤化银彩色照相材料的方法,包括彩色显影,漂白固定和至少一种用水洗涤和稳定化的步骤。 补充液被提供给漂白固定液,导致处理的照相材料溢出30至500ml / m 2。 漂白固定步骤还包括收集漂白剂固定溢流液,通过向其中加入再生剂再生所述收集的漂白固定液溢流,以产生再生漂白剂 - 固定浴,以及将再生漂白剂固定浴作为补充剂再次用于漂白剂 混合浴。 再生率定义为用于再生的漂白固定溢流量除以总溢出量乘以100%,超过80%。 卤化银彩色照相材料的照相层具有约2.5至4.0的溶胀度。 卤化银彩色照相材料还具有小于约0.8g / m 2的银覆盖。 上述方法解决了脱色不良,颜色再现不足和不期望的青色热变色的问题,通常伴随着漂白剂固定浴的再利用。
摘要:
In the silicon substrate having porous oxidized silicon layers of this invention, which consists of a silicon substrate the one surface of which is dotted with porous oxidized silicon layers, the residual internal stress (compression stress) is dispersedly distributed in the porous oxidized silicon layers. Therefore, the entire silicon substrate having porous oxidized silicon layers of this invention is only minimally warped.Adopting a method for producing the silicon substrate of this invention which consists of covering with a mask the surface of a silicon substrate except its dotting areas to be treated, subjecting the silicon substrate to anodic formation in an aqueous hydrofluoric acid solution to form porous silicon layers in the areas to be treated and not covered with the mask and then oxidizing the formed porous silicon layers enables secured production of a silicon substrate dotted with porous oxidized silicon layers.
摘要:
A process for processing a silver halide color photographic material is disclosed which comprises processing a silver halide color photographic material containing at least one compound represented by formula (I) or (II): ##STR1## wherein R.sub.1 and R.sub.2 each represents an aliphatic group, an aromatic group, or a heterocyclic group; A represents a group forming a chemical bond by reaction with an aromatic primary amine color developing agent; n represents 0 or 1; X represents a group released on reaction with an aromatic primary amine color developing agent; B represents a hydrogen atom, an aliphatic group, an aromatic group, a heterocyclic group, an acyl group, or a sulfonyl group; and Y represents a group accelerating the addition of an aromatic primary amine color developing agent to the compound of formula (II), and said R.sub.1 and X or said Y and R.sub.2 or B may combine with each other to form a ring, with a color developer prepared by diluting a concentrated color developer composition containing from 90 ml/liter to 600 ml/liter of benzyl alcohol and from 0.07 mol/liter to 0.5 mol/liter of an aromatic primary amine color developing agent.
摘要:
A method for processing a silver halide color photosensitive material is disclosed.The process step comprises developing a color photographic light-sensitive material composed of a support having thereon at least one light-sensitive silver halide emulsion layer containing a silver halide containing at least 80 mol % silver chloride; at least one emulsion layer thereof containing a dispersion of a mixture of (i) at least one oil-soluble non-diffusible cyan coupler capable of forming a substantially non-diffusible cyan dye by coupling with the oxidized form of a developing agent, and (ii) a water-insoluble polymer;in a color developer solution comprising a primary amine color developing agent, and having a chloride ion concentration of from 3.5.times.10.sup.-2 to 1.5.times.10.sup.-1 mol/l, and a bromide ion concentration of from 3.0.times.10.sup.-5 to 1.0.times.10.sup.-3 mol/l.When used in rapid processing methods, the method according to the invention prevents pressure-sensitization fogging, and provides high maximum density and low minimum density images.
摘要:
A method of processing a silver halide color photographic material in which the material is, after color-developed, processed in a bath having bleaching ability and then in a bath having fixing ability, wherein a bleaching agent in the bath having bleaching ability is at least one iron(III) complex of an aminopolycarboxylic acid of the following formula (I) and the bath having fixing ability contains at least one organic phosphonic acid: ##STR1## wherein n represents 3, 4 or 5, and is preferable 3. Especially, the bleaching agent in the bath having bleaching ability comprises at least one iron(III) complex of a compound selected from the following group (A) and a (1,3-diaminopropanetetraacetato)iron(III) complex in a molar proportion of the former to the latter of being 3 or less, and ammonium ion accounts for 90 mol % or more of the sum of the alkali metal ions and ammonium ion in the bath having fixing ability; Group (A): A-1: Ethylenediaminetetraacetic Acid A-2: Diethylenetriaminepentaacetic Acid A-3: 1,2-Cyclohexanediaminetetraacetic Acid A-4: 1,2-Propylenediaminetetraacetic Acid. According to the method, rapid desilvering is effected, the stability of the fixing agent is improved, bleaching fog is inhibited, the fixing speed is elevated, and the storage stability of the images formed in the material processed is improved.
摘要:
A method for forming a direct positive color image by image-wise exposing to light a light-sensitive material having at least one internal latent image type silver halide emulsion layer which is unfogged and color image-forming couplers on a support; either (1) subjecting the resulting material to fogging exposure to light and/or processing it with a nucleating agent before development, and then developing the resulting material with a surface developing solution containing an aromatic primary amine type color developing agent, or (2) developing the material after the image-wise exposure with a surface developing solution containing an aromatic primary amine type color developing agent under fogging exposure and/or in the presence of a nucleating agent; and bleach-fixing the resulting material, wherein the color developing solution contains at least one compound selected from the group consisting of compounds represented by the following general formulae (I), (II), (III) and (IV): ##STR1## wherein X represents --CO--, --SO.sub.2 -- or ##STR2## and R.sup.1 and R.sup.2 represents various familiar group; ##STR3## wherein R.sup.3, R.sup.4, R.sup.5 and R.sup.6 represent various familiar groups; ##STR4## wherein R.sup.7 and R.sup.8 represent various familiar groups; ##STR5## wherein Y represents a trivalent atomic group necessary for completing a condensed ring, m represents an integer of 0 to 4, and n represents an integer of 1 to 5.Stability of the color developing solutions with time lapse is excellent, which makes stable continuous process of color photographic light-sensitive materials possible over a long period.
摘要:
An ink-jet printing head assembly having a substrate and a cover plate which are juxtaposed with a space provided therebetween, for a nozzle at one edge of said substrate, an air chamber behind said nozzle, and an ink chamber with an outlet into the air chamber beyond the air chamber. A first electrode is located along an edge of the inner surface of the substrate and on one side of the nozzle. A second electrode is located on the inner surface of said substrate in the outlet opening between the ink chamber and the air chamber and separated from the first electrode by a space. The printing head ink used is conductive. The surface tension of the ink prevents it from flowing out of the small outlet from the ink chamber into to the air chamber when air is flowing into said air chamber and out of the nozzle. When a voltage is applied across two electrodes the electric field between the electrodes creates an attractive force the overcomes the surface tension of the ink in the outlet and ink flows into the air chamber where droplets are formed and the air transports the to an object to be printed. A printing head assembly according to the invention having electrodes and nozzles with a high concentration per unit area can be realized by means of a film formation technique. Such a compact and lightweight designed printing head assembly with a high concentration of nozzles can be manufactured using mass production techniques.
摘要:
A method for processing a silver halide color photographic material comprising a reflective support having thereon at least one light-sensitive silver halide emulsion layer containing a color coupler or color couplers, which comprises the step of, after imagewise exposing, developing said silver halide color photographic material with a color developing solution which does not substantially contain benzyl alcohol and which contains an aromatic primary amine color developing agent represented by formula (A): ##STR1## wherein X represents a compound capable of forming a salt with a primary amine; and a compound represented by formula (I): ##STR2## wherein R.sup.1 represents a hydrogen atom or a substituted or unsubstituted alkyl, aryl, alkoxy, aryloxy or amino group; and R.sup.2 represents a hydrogen atom or a substituted or unsubstituted alkyl or aryl group; or R.sup.1 and R.sup.2 may be bonded to each other to form a carbon ring or a hetero-ring.The color developing solution used in the present method has improved stability and color forming properties.
摘要:
A method for processing a silver halide color photographic material including a step of developing the material with a developer containing an aromatic primary amine color developing agent and at least one compounds represented by the following general formulae (Ia) and (Ib): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4, which may be the same or different, each represents a hydrogen atom or an unsubstituted alkyl group; R.sup.5, R.sup.6 and R.sup.7, which may be the same or different, each represents an unsubstituted alkylene group; X.sup.1 and X.sup.2, which may be the same or different, each represents ##STR2## --O--, --S--, --CO--, --SO.sub.2 or --SO--, or a combination thereof, and R.sup.8 represents a hydrogen atom or an unsubstituted alkyl group; and m and n, which may be the same or different, each is 0, 1, 2 or 3; and ##STR3## wherein R.sup.13 represents a substituted alkylene group; and R.sup.9, R.sup.10, R.sup.11 and R.sup.12, which may be the same or different, each represents a hydrogen atom, a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group. The developer has superior stability and reduces fogging in continuous processing.
摘要翻译:一种用于处理卤化银彩色照相材料的方法,包括用包含芳族伯胺显色剂的显影剂和至少一种由以下通式(Ia)和(Ib)表示的化合物显影材料的步骤: (Ia)其中可以相同或不同的R 1,R 2,R 3和R 4各自表示氢原子或未取代的烷基; R5,R6和R7可以相同或不同,表示未取代的亚烷基; X 1和X 2可以相同或不同,各自表示-O - , - S - , - CO - , - SO 2或-SO-或其组合,R 8表示氢原子或未取代的 烷基; 和m和n可以相同或不同,各自为0,1,2或3; (Ib)其中R 13表示取代的亚烷基; 和R 9,R 10,R 11和R 12可以相同或不同,表示氢原子,取代或未取代的烷基或取代或未取代的芳基。 开发者具有优异的稳定性,并减少连续加工中的起雾。
摘要:
A process for processing color photographic papers using a color developer substantially free from benzyl alcohol and containing a compound represented by formula (I) ##STR1## wherein Z represents an atomic group forming an aromatic nucleus is disclosed. In the process, the formation of color stains is greatly reduced even in the case of shortening the processing times for the blix step and the wash and/or stabilization step after color development.