Processing of silver halide color photographic material
    61.
    发明授权
    Processing of silver halide color photographic material 失效
    卤化银彩色照相材料的加工

    公开(公告)号:US5234801A

    公开(公告)日:1993-08-10

    申请号:US840585

    申请日:1992-02-26

    IPC分类号: G03C5/395 G03C7/44

    CPC分类号: G03C7/44 G03C5/3958

    摘要: A method for continuously processing an image-wise exposed silver halide color photographic material comprising the steps of color developing, bleach-fixing and at least one of washing with water and stabilizing. A replenisher is supplied to the bleach-fix bath to result in an overflow of from 30 to 500 ml/m.sup.2 of the photographic material processed. The bleach-fixing step further comprises collecting the bleach-fix overflow, regenerating the collected bleach-fix bath overflow by adding thereto a regenerant to produce a regenerated bleach-fix bath, and reusing the regenerated bleach-fix bath as a replenisher to the bleach-fix bath. The regeneration rate defined as the amount of bleach-fix overflow used for regeneration divided by the total amount of overflow multiplied by 100% is more than 80%. The photographic layers of the silver halide color photographic material have a degree of swelling of from about 2.5 to 4.0. The silver halide color photographic material further has a silver coverage of less than about 0.8 g/m.sup.2. The above described method solves problems of poor desilvering, inadequate color reproduction and undesirable cyan thermal discoloration which generally accompany reuse of the bleach-fixing bath.

    摘要翻译: 一种用于连续处理图像曝光的卤化银彩色照相材料的方法,包括彩色显影,漂白固定和至少一种用水洗涤和稳定化的步骤。 补充液被提供给漂白固定液,导致处理的照相材料溢出30至500ml / m 2。 漂白固定步骤还包括收集漂白剂固定溢流液,通过向其中加入再生剂再生所述收集的漂白固定液溢流,以产生再生漂白剂 - 固定浴,以及将再生漂白剂固定浴作为补充剂再次用于漂白剂 混合浴。 再生率定义为用于再生的漂白固定溢流量除以总溢出量乘以100%,超过80%。 卤化银彩色照相材料的照相层具有约2.5至4.0的溶胀度。 卤化银彩色照相材料还具有小于约0.8g / m 2的银覆盖。 上述方法解决了脱色不良,颜色再现不足和不期望的青色热变色的问题,通常伴随着漂白剂固定浴的再利用。

    Silicon substrate having porous oxidized silicon layers and its
production method
    62.
    发明授权
    Silicon substrate having porous oxidized silicon layers and its production method 失效
    具有多孔氧化硅层的硅衬底及其生产方法

    公开(公告)号:US5091061A

    公开(公告)日:1992-02-25

    申请号:US629857

    申请日:1990-12-18

    摘要: In the silicon substrate having porous oxidized silicon layers of this invention, which consists of a silicon substrate the one surface of which is dotted with porous oxidized silicon layers, the residual internal stress (compression stress) is dispersedly distributed in the porous oxidized silicon layers. Therefore, the entire silicon substrate having porous oxidized silicon layers of this invention is only minimally warped.Adopting a method for producing the silicon substrate of this invention which consists of covering with a mask the surface of a silicon substrate except its dotting areas to be treated, subjecting the silicon substrate to anodic formation in an aqueous hydrofluoric acid solution to form porous silicon layers in the areas to be treated and not covered with the mask and then oxidizing the formed porous silicon layers enables secured production of a silicon substrate dotted with porous oxidized silicon layers.

    摘要翻译: 在本发明的具有多孔氧化硅层的硅衬底中,其由一个表面以多孔氧化硅层为点的硅衬底组成,残留的内部应力(压缩应力)分散分布在多孔氧化硅层中。 因此,具有本发明的多孔氧化硅层的整个硅衬底仅被最小程度地翘曲。 采用本发明的硅基板的制造方法,该方法由掩模覆盖硅基板​​的除了其待处理区域之外的表面,使硅基板在氢氟酸水溶液中阳极形成以形成多孔硅层 在待处理的区域中并未被掩模覆盖,然后氧化所形成的多孔硅层,从而可以有效地生产以多孔氧化硅层为中心的硅衬底。

    Process for processing silver halide color photographic materials
    63.
    发明授权
    Process for processing silver halide color photographic materials 失效
    卤化银彩色照相材料加工工艺

    公开(公告)号:US5006438A

    公开(公告)日:1991-04-09

    申请号:US518266

    申请日:1990-05-03

    CPC分类号: G03C7/39208 G03C7/413

    摘要: A process for processing a silver halide color photographic material is disclosed which comprises processing a silver halide color photographic material containing at least one compound represented by formula (I) or (II): ##STR1## wherein R.sub.1 and R.sub.2 each represents an aliphatic group, an aromatic group, or a heterocyclic group; A represents a group forming a chemical bond by reaction with an aromatic primary amine color developing agent; n represents 0 or 1; X represents a group released on reaction with an aromatic primary amine color developing agent; B represents a hydrogen atom, an aliphatic group, an aromatic group, a heterocyclic group, an acyl group, or a sulfonyl group; and Y represents a group accelerating the addition of an aromatic primary amine color developing agent to the compound of formula (II), and said R.sub.1 and X or said Y and R.sub.2 or B may combine with each other to form a ring, with a color developer prepared by diluting a concentrated color developer composition containing from 90 ml/liter to 600 ml/liter of benzyl alcohol and from 0.07 mol/liter to 0.5 mol/liter of an aromatic primary amine color developing agent.

    Method for processing a silver halide photosensitive material for color
photography
    64.
    发明授权
    Method for processing a silver halide photosensitive material for color photography 失效
    用于处理用于彩色摄影的卤化银感光材料的方法

    公开(公告)号:US5004675A

    公开(公告)日:1991-04-02

    申请号:US416797

    申请日:1989-10-03

    摘要: A method for processing a silver halide color photosensitive material is disclosed.The process step comprises developing a color photographic light-sensitive material composed of a support having thereon at least one light-sensitive silver halide emulsion layer containing a silver halide containing at least 80 mol % silver chloride; at least one emulsion layer thereof containing a dispersion of a mixture of (i) at least one oil-soluble non-diffusible cyan coupler capable of forming a substantially non-diffusible cyan dye by coupling with the oxidized form of a developing agent, and (ii) a water-insoluble polymer;in a color developer solution comprising a primary amine color developing agent, and having a chloride ion concentration of from 3.5.times.10.sup.-2 to 1.5.times.10.sup.-1 mol/l, and a bromide ion concentration of from 3.0.times.10.sup.-5 to 1.0.times.10.sup.-3 mol/l.When used in rapid processing methods, the method according to the invention prevents pressure-sensitization fogging, and provides high maximum density and low minimum density images.

    摘要翻译: 公开了一种处理卤化银色感光材料的方法。 工艺步骤包括显影由其上具有至少一种含有至少80mol%氯化银的卤化银的感光卤化银乳剂层的载体组成的彩色照相感光材料; 其至少一个乳剂层含有(i)至少一种能够通过与显影剂的氧化形式偶联形成基本上不可扩散的青色染料的油溶性非扩散性青色成色剂的混合物的分散体,和 ii)水不溶性聚合物; 在包含伯胺显色剂的显色剂溶液中,并且氯离子浓度为3.5×10 -2至1.5×10 -1 mol / l,溴离子浓度为3.0×10-5至1.0×10-3 mol / l。 当用于快速加工方法时,根据本发明的方法防止增压雾化,并提供高的最大密度和低的最小密度的图像。

    Method for processing silver halide color photographic material
    65.
    发明授权
    Method for processing silver halide color photographic material 失效
    卤化银彩色照相材料的处理方法

    公开(公告)号:US4963474A

    公开(公告)日:1990-10-16

    申请号:US309588

    申请日:1989-02-13

    IPC分类号: G03C7/42

    CPC分类号: G03C7/42

    摘要: A method of processing a silver halide color photographic material in which the material is, after color-developed, processed in a bath having bleaching ability and then in a bath having fixing ability, wherein a bleaching agent in the bath having bleaching ability is at least one iron(III) complex of an aminopolycarboxylic acid of the following formula (I) and the bath having fixing ability contains at least one organic phosphonic acid: ##STR1## wherein n represents 3, 4 or 5, and is preferable 3. Especially, the bleaching agent in the bath having bleaching ability comprises at least one iron(III) complex of a compound selected from the following group (A) and a (1,3-diaminopropanetetraacetato)iron(III) complex in a molar proportion of the former to the latter of being 3 or less, and ammonium ion accounts for 90 mol % or more of the sum of the alkali metal ions and ammonium ion in the bath having fixing ability; Group (A): A-1: Ethylenediaminetetraacetic Acid A-2: Diethylenetriaminepentaacetic Acid A-3: 1,2-Cyclohexanediaminetetraacetic Acid A-4: 1,2-Propylenediaminetetraacetic Acid. According to the method, rapid desilvering is effected, the stability of the fixing agent is improved, bleaching fog is inhibited, the fixing speed is elevated, and the storage stability of the images formed in the material processed is improved.

    Method for forming a direct positive color image
    66.
    发明授权
    Method for forming a direct positive color image 失效
    用于形成直接正彩色图像的方法

    公开(公告)号:US4956267A

    公开(公告)日:1990-09-11

    申请号:US200268

    申请日:1988-05-31

    IPC分类号: G03C1/485 G03C7/413

    CPC分类号: G03C7/413 G03C1/48538

    摘要: A method for forming a direct positive color image by image-wise exposing to light a light-sensitive material having at least one internal latent image type silver halide emulsion layer which is unfogged and color image-forming couplers on a support; either (1) subjecting the resulting material to fogging exposure to light and/or processing it with a nucleating agent before development, and then developing the resulting material with a surface developing solution containing an aromatic primary amine type color developing agent, or (2) developing the material after the image-wise exposure with a surface developing solution containing an aromatic primary amine type color developing agent under fogging exposure and/or in the presence of a nucleating agent; and bleach-fixing the resulting material, wherein the color developing solution contains at least one compound selected from the group consisting of compounds represented by the following general formulae (I), (II), (III) and (IV): ##STR1## wherein X represents --CO--, --SO.sub.2 -- or ##STR2## and R.sup.1 and R.sup.2 represents various familiar group; ##STR3## wherein R.sup.3, R.sup.4, R.sup.5 and R.sup.6 represent various familiar groups; ##STR4## wherein R.sup.7 and R.sup.8 represent various familiar groups; ##STR5## wherein Y represents a trivalent atomic group necessary for completing a condensed ring, m represents an integer of 0 to 4, and n represents an integer of 1 to 5.Stability of the color developing solutions with time lapse is excellent, which makes stable continuous process of color photographic light-sensitive materials possible over a long period.

    Printing head assembly
    67.
    发明授权
    Printing head assembly 失效
    打印头组件

    公开(公告)号:US4929968A

    公开(公告)日:1990-05-29

    申请号:US399657

    申请日:1989-08-28

    IPC分类号: B41J2/045 B41J2/06

    摘要: An ink-jet printing head assembly having a substrate and a cover plate which are juxtaposed with a space provided therebetween, for a nozzle at one edge of said substrate, an air chamber behind said nozzle, and an ink chamber with an outlet into the air chamber beyond the air chamber. A first electrode is located along an edge of the inner surface of the substrate and on one side of the nozzle. A second electrode is located on the inner surface of said substrate in the outlet opening between the ink chamber and the air chamber and separated from the first electrode by a space. The printing head ink used is conductive. The surface tension of the ink prevents it from flowing out of the small outlet from the ink chamber into to the air chamber when air is flowing into said air chamber and out of the nozzle. When a voltage is applied across two electrodes the electric field between the electrodes creates an attractive force the overcomes the surface tension of the ink in the outlet and ink flows into the air chamber where droplets are formed and the air transports the to an object to be printed. A printing head assembly according to the invention having electrodes and nozzles with a high concentration per unit area can be realized by means of a film formation technique. Such a compact and lightweight designed printing head assembly with a high concentration of nozzles can be manufactured using mass production techniques.

    摘要翻译: 一种喷墨打印头组件,其具有基板和盖板,该基板和盖板与其间设置的空间并置,用于在所述基板的一个边缘处的喷嘴,在所述喷嘴之后的空气室,以及具有出口到空气中的墨室 室外空气室。 第一电极沿着衬底的内表面的边缘并且在喷嘴的一侧上定位。 第二电极位于墨室和空气室之间的出口开口中的所述基板的内表面上,并与第一电极隔开一空间。 使用的打印头墨水是导电的。 当空气流入所述空气室并从喷嘴出来时,油墨的表面张力防止其从墨水室流出小室,进入空气室。 当在两个电极之间施加电压时,电极之间的电场产生吸引力,克服出口中的墨水的表面张力,并且墨水流入空气室,在其中形成液滴并且空气传输到物体 印刷。 根据本发明的具有电极和每单位面积浓度高的喷嘴的印刷头组件可以通过成膜技术实现。 可以使用大规模生产技术制造具有高浓度喷嘴的这种紧凑且轻便的设计的打印头组件。

    Method for processing a silver halide color photographic material using
a developer substantially free of benzyl alcohol and sulfite
    68.
    发明授权
    Method for processing a silver halide color photographic material using a developer substantially free of benzyl alcohol and sulfite 失效
    使用基本上不含苄醇和亚硫酸盐的显影剂处理卤化银彩色照相材料的方法

    公开(公告)号:US4920041A

    公开(公告)日:1990-04-24

    申请号:US298238

    申请日:1989-01-12

    CPC分类号: G03C7/413

    摘要: A method for processing a silver halide color photographic material comprising a reflective support having thereon at least one light-sensitive silver halide emulsion layer containing a color coupler or color couplers, which comprises the step of, after imagewise exposing, developing said silver halide color photographic material with a color developing solution which does not substantially contain benzyl alcohol and which contains an aromatic primary amine color developing agent represented by formula (A): ##STR1## wherein X represents a compound capable of forming a salt with a primary amine; and a compound represented by formula (I): ##STR2## wherein R.sup.1 represents a hydrogen atom or a substituted or unsubstituted alkyl, aryl, alkoxy, aryloxy or amino group; and R.sup.2 represents a hydrogen atom or a substituted or unsubstituted alkyl or aryl group; or R.sup.1 and R.sup.2 may be bonded to each other to form a carbon ring or a hetero-ring.The color developing solution used in the present method has improved stability and color forming properties.

    摘要翻译: 一种用于处理卤化银彩色照相材料的方法,包括其上具有至少一个含有着色成色剂的感光卤化银乳剂层的反射性载体,其包括在成像曝光后显影所述卤化银彩色照相 具有基本上不含苄醇的显色溶液的材料,其含有由式(A)表示的芳族伯胺显色剂:其中X表示与伯胺形成盐的化合物 ; 和由式(I)表示的化合物:其中R 1表示氢原子或取代或未取代的烷基,芳基,烷氧基,芳氧基或氨基; 并且R 2表示氢原子或取代或未取代的烷基或芳基; 或者R 1和R 2可以彼此键合形成碳环或杂环。 本方法中使用的显色溶液具有改进的稳定性和成色性能。

    Method for processing a silver halide color photographic material and a
color developing composition comprising hydroxylamines and stabilizing
agents
    69.
    发明授权
    Method for processing a silver halide color photographic material and a color developing composition comprising hydroxylamines and stabilizing agents 失效
    用于处理卤化银彩色照相材料的方法和包含羟胺和稳定剂的彩色显影组合物

    公开(公告)号:US4897339A

    公开(公告)日:1990-01-30

    申请号:US333816

    申请日:1989-04-06

    IPC分类号: G03C7/413

    CPC分类号: G03C7/413

    摘要: A method for processing a silver halide color photographic material including a step of developing the material with a developer containing an aromatic primary amine color developing agent and at least one compounds represented by the following general formulae (Ia) and (Ib): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4, which may be the same or different, each represents a hydrogen atom or an unsubstituted alkyl group; R.sup.5, R.sup.6 and R.sup.7, which may be the same or different, each represents an unsubstituted alkylene group; X.sup.1 and X.sup.2, which may be the same or different, each represents ##STR2## --O--, --S--, --CO--, --SO.sub.2 or --SO--, or a combination thereof, and R.sup.8 represents a hydrogen atom or an unsubstituted alkyl group; and m and n, which may be the same or different, each is 0, 1, 2 or 3; and ##STR3## wherein R.sup.13 represents a substituted alkylene group; and R.sup.9, R.sup.10, R.sup.11 and R.sup.12, which may be the same or different, each represents a hydrogen atom, a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group. The developer has superior stability and reduces fogging in continuous processing.

    摘要翻译: 一种用于处理卤化银彩色照相材料的方法,包括用包含芳族伯胺显色剂的显影剂和至少一种由以下通式(Ia)和(Ib)表示的化合物显影材料的步骤: (Ia)其中可以相同或不同的R 1,R 2,R 3和R 4各自表示氢原子或未取代的烷基; R5,R6和R7可以相同或不同,表示未取代的亚烷基; X 1和X 2可以相同或不同,各自表示-O - , - S - , - CO - , - SO 2或-SO-或其组合,R 8表示氢原子或未取代的 烷基; 和m和n可以相同或不同,各自为0,1,2或3; (Ib)其中R 13表示取代的亚烷基; 和R 9,R 10,R 11和R 12可以相同或不同,表示氢原子,取代或未取代的烷基或取代或未取代的芳基。 开发者具有优异的稳定性,并减少连续加工中的起雾。