公开(公告)号：US20050089464A1

公开(公告)日：2005-04-28

申请号：US10605736

申请日：2003-10-22

申请人： Robin Wang ,  Peter Pappas ,  Amarendra Anumakonda ,  Mariola Proszowski ,  Jean Yamanis

发明人： Robin Wang ,  Peter Pappas ,  Amarendra Anumakonda ,  Mariola Proszowski ,  Jean Yamanis

IPC分类号： B01J12/00 ,  B01J19/24 ,  C01B3/38 ,  C01B32/40 ,  C01B6/24 ,  C01B31/18 ,  C01B31/24 ,  C01B3/02

CPC分类号： C01B3/386 ,  B01J12/007 ,  B01J19/2485 ,  B01J2208/025 ,  B01J2219/00087 ,  B01J2219/00155 ,  B01J2219/00157 ,  B01J2219/00159 ,  C01B32/40 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/066 ,  C01B2203/0844 ,  C01B2203/1023 ,  C01B2203/1247 ,  C01B2203/1258 ,  C01B2203/142 ,  C01B2203/82

摘要： Method and equipment for converting hydrocarbon fuel to a mixture of hydrogen and carbon monoxide through catalytic partial oxidation. The catalysts can include a combination of both an oxidation catalyst and a steam reforming catalyst, though no water is used in the process and catalyst contact time is short. Thermal management of the process in the pre-reaction and post reaction zones of the reactor enhance yields and reduce carbon deposition.

摘要翻译： 通过催化部分氧化将烃类燃料转化为氢气和一氧化碳的混合物的方法和设备。 催化剂可以包括氧化催化剂和蒸汽重整催化剂的组合，尽管在该方法中不使用水，催化剂接触时间短。 反应器和反应后反应区中的方法的热管理提高了产率并减少了碳沉积。

公开(公告)号：US5807642A

公开(公告)日：1998-09-15

申请号：US699753

申请日：1996-08-20

申请人： Liang An Xue ,  Jean Yamanis ,  Richard Donaldson

发明人： Liang An Xue ,  Jean Yamanis ,  Richard Donaldson

IPC分类号： C04B35/465 ,  H01M8/02 ,  H01M8/12 ,  H01M8/24 ,  H01M8/10

CPC分类号： C04B35/465 ,  H01M8/02 ,  H01M8/1213 ,  H01M8/2485 ,  H01M2008/1293 ,  H01M2300/0074

摘要： A ceramic body based on barium and strontium titanates has a composition defined essentially by the formula Ba.sub.1-x Sr.sub.x TiO.sub.3, where x ranges from 0 to 1. The ceramic body is chemically and dimensionally stable in solid oxide fuel cell (SOFC) operation environments, which encounter oxidizing and reducing atmospheres at temperatures as high as 1,000.degree. C. In addition, the ceramic of which the body is comprised can be tailored to yield a ceramic in which the thermal expansion coefficient (CTE) is adjusted between 11.3.times.10.sup.-6 /.degree.C. and 12.4.times.10.sup.-6 /.degree.C. to match the CTE of the other SOFC materials, thereby avoiding the adverse effects of thermal stress. These features make the ceramic body especially suited for use as manifolds in SOFC stacks, or other non-electrical structural components, such as the inflow and outflow gas manifold materials, the stack housing, or other support structure or spacers in the stack, and the like.

摘要翻译： 基于钡和钛酸锶的陶瓷体具有基本上由式Ba1-xSrxTiO3定义的组成，其中x的范围为0至1.陶瓷体在固体氧化物燃料电池（SOFC）操作环境中化学和尺寸稳定，其遇到 在高达1000℃的温度下氧化和还原气氛。此外，可以调整包含人体的陶瓷以产生陶瓷，其中热膨胀系数（CTE）在11.3×10 -6 /℃ 和12.4×10-6 /℃，以匹配其他SOFC材料的CTE，从而避免热应力的不利影响。 这些特征使得陶瓷体特别适合用作SOFC堆叠中的歧管或其它非电气结构部件，例如流入和流出气体歧管材料，堆叠壳体或堆叠中的其它支撑结构或间隔物，以及 喜欢。

公开(公告)号：US5292489A

公开(公告)日：1994-03-08

申请号：US720272

申请日：1991-06-24

申请人： Anthony J. Fanelli ,  Jeffrey P. Solar ,  Beili L. Wu ,  Jean Yamanis

发明人： Anthony J. Fanelli ,  Jeffrey P. Solar ,  Beili L. Wu ,  Jean Yamanis

IPC分类号： C04B35/515 ,  C04B35/584 ,  C04B35/593 ,  C04B35/58

CPC分类号： C04B35/5156 ,  C04B35/584 ,  C04B35/5935

摘要： This invention provides a compound having the formula LnSi.sub.3 N.sub.5 wherein Ln is selected from the group consisting of scandium, yttrium, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium. In addition, there is provided a method for making the compound Ln'Si.sub.3 N.sub.5 wherein Ln' is a radical selected from the group consisting of lanthanum, scandium, yttrium, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium and lutetium, comprising the step of reacting SiO.sub.z, Ln'.sub.x O.sub.y in a nitrogen atmosphere in the presence of carbon at a temperature of from 1200.degree. C. to about 2000.degree. C. for at least 2 hrs., x being an integer equal to or greater than 2, y being an integer equal to or greater than 3, and z being an integer selected from 1 and 2, with the proviso that x and y are selected to result in a stable compound of Ln'.sub.x O.sub.y.

摘要翻译： 本发明提供具有式LnSi 3 N 5的化合物，其中Ln选自钪，钇，铈，镨，钕，ium，钐，铕，钆，铽，镝，钬，铒，ium，镱和镥 。 此外，提供了一种制备化合物Ln'Si3N5的方法，其中Ln'是选自镧，钪，钇，铈，镨，钕，ium，钐，铕，钆，铽，镝的基团 钬，铒，ium，镱和镥，包括在碳存在下，在1200℃至约2000摄氏度的温度下，在氮气气氛中使SiO 2，L 1 O 10反应至少2小时的步骤 x是等于或大于2的整数，y是等于或大于3的整数，z是选自1和2的整数，条件是选择x和y以产生稳定的化合物 的Ln'xOy。

公开(公告)号：US5185301A

公开(公告)日：1993-02-09

申请号：US826194

申请日：1992-01-21

申请人： Beili Li ,  Stephen Haig ,  Jean Yamanis

发明人： Beili Li ,  Stephen Haig ,  Jean Yamanis

IPC分类号： C01G37/00 ,  C04B35/42 ,  H01M8/02 ,  H01M8/12

CPC分类号： C04B35/42 ,  C01G37/006 ,  H01M8/0215 ,  C01P2002/02 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2004/40 ,  C01P2004/61 ,  C01P2006/10 ,  C01P2006/12 ,  H01M2008/1293 ,  H01M2300/0074 ,  Y02P70/56

摘要： A sinter-reactive lanthanum chromite powder is prepared from the lanthanum chromite precursor LaCr.sub.1-x M.sub.x O.sub.3 (Adsorbate). The powder is crystalline, has the formula LaCr.sub.1-x M.sub.x O.sub.3, where M is magnesium or calcium and x ranges from about 0.03 to 0.3, and sinters to densities higher than about 95% of theoretical density at temperature as low as 1600.degree. C. in inert or reducing atmospheres. Sintering to such high density at temperatures in the vicinity of 1600.degree. C. makes the powder particularly suited for use as interconnect material for solid oxide fuel cells.

摘要翻译： 从铬酸镧原子LaCr1-xMxO3（Adsorbate）制备烧结反应性铬酸镧粉末。 该粉末是结​​晶的，具有式LaCr1-xMxO3，其中M为镁或钙，x为约0.03至0.3，在低至1600℃的温度下烧结至理论密度高于约95％的密度。 或减少气氛。 在1600℃附近的温度下烧结至如此高的密度，使粉末特别适用于固体氧化物燃料电池的互连材料。

公开(公告)号：US5100847A

公开(公告)日：1992-03-31

申请号：US759970

申请日：1991-09-17

申请人： Chien-Wei Li ,  Jean Yamanis ,  Gilbert Carrasquillo

发明人： Chien-Wei Li ,  Jean Yamanis ,  Gilbert Carrasquillo

IPC分类号： C04B35/593

CPC分类号： C04B35/5935

摘要： A monolithic silicon nitride ceramic is densified at temperatures lower than 2000.degree. C. and heat treated at temperatures greater than 2000.degree. C. in the presence of at least 6.5 w % of multi-component sintering aids. This monolithic silicon nitride has a highly acicular microstructure Chevron Notch fracture toughness greater than 9 MPa.multidot.m.sup.1/2, R-curve behavior, high Weibull modulus, excellent damage tolerance, high thermal conductivity, and other desirable properties.

摘要翻译： 整体式氮化硅陶瓷在低于2000℃的温度下致密化，并且在至少6.5w％的多组分烧结助剂的存在下，在高于2000℃的温度下进行热处理。 这种单片氮化硅具有高度针状微观结构，Chevron Notch断裂韧性大于9 MPaxm1 / 2，R-曲线行为，威布尔模量高，耐损伤性好，导热性好等优点。

公开(公告)号：US5061402A

公开(公告)日：1991-10-29

申请号：US515787

申请日：1990-04-25

申请人： William L. Olson ,  Beili Li ,  Jean Yamanis

发明人： William L. Olson ,  Beili Li ,  Jean Yamanis

IPC分类号： C01G37/00 ,  C04B35/42 ,  H01M8/02 ,  H01M8/12

CPC分类号： H01M8/0215 ,  C01G37/006 ,  C04B35/42 ,  C01P2002/54 ,  C01P2004/52 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2006/10 ,  C01P2006/14 ,  C01P2006/36 ,  C01P2006/60 ,  H01M2008/1293 ,  H01M2300/0074

摘要： This invention relates to a process for the preparation of a crystalline compound having an empirical formula LaCr.sub.x A.sub.1-x O.sub.4.yH.sub.2 O where A is a metal selected from the group consisting of Mg, Sr, Ca and Ba, x ranges from 0.99 to about 0.7 and y ranges from 0 to 0.15. The process comprises adding a solution of the appropriate metal salts to a solution of ammonium hydroxide thereby precipitating a hydroxide gel intermediate, which is dried and calcined in air to yield the resultant crystalline compound which has a huttonite structure. Additionally, this invention relates to a process for the preparation of a ceramic powder having the empirical formula LaCr.sub.x A.sub.1-x O.sub.3, where A is a metal selected from the group consisting of Mg, Sr, Ca and Ba, and x ranges from 0.99 to about 0.7. Finally, a ceramic composition having the empirical formula LaCr.sub.x A.sub.1-x O.sub.4.yH.sub.2 O having a huttonite structure is also disclosed.

摘要翻译： 本发明涉及制备具有经验式LaCrxAl-xO4.yH2O的结晶化合物的方法，其中A是选自Mg，Sr，Ca和Ba的金属，x为0.99至约0.7，y为 范围从0到0.15。 该方法包括将合适的金属盐溶液加入到氢氧化铵溶液中，由此使氢氧化凝胶中间体沉淀，将其在空气中干燥和煅烧，得到所得到的具有钙钛矿结构的结晶化合物。 另外本发明涉及制备具有经验式LaCrxAl-xO3的陶瓷粉末的方法，其中A是选自Mg，Sr，Ca和Ba的金属，x在0.99至0.7的范围内 。 最后，还公开了具有钙钛矿结构的经验式LaCrxAl-xO4.yH2O的陶瓷组合物。