公开(公告)号：US09859553B2

公开(公告)日：2018-01-02

申请号：US14496074

申请日：2014-09-25

Applicant: KABUSHIKI KAISHA TOSHIBA

Inventor： Tomokazu Morita ,  Takashi Kuboki ,  Takayuki Fukasawa ,  Yasuyuki Hotta ,  Yasuhiro Goto ,  Toshiro Hiraoka

IPC: H01M4/48 ,  H01M4/36 ,  H01M4/38 ,  H01M4/485 ,  H01M4/587 ,  H01M4/133 ,  H01M4/583 ,  H01M10/052 ,  H01M4/02

CPC classification number: H01M4/364 ,  H01M4/133 ,  H01M4/386 ,  H01M4/48 ,  H01M4/485 ,  H01M4/583 ,  H01M4/587 ,  H01M10/052 ,  H01M2004/027

Abstract: A negative electrode active material for a nonaqueous electrolyte secondary battery of an embodiment includes a carbonaceous material, a silicon oxide phase in the carbonaceous material, and a silicon phase in the silicon oxide phase. The negative electrode active material has a crack in the carbonaceous material, and the longest side of the crack has a length equal to or greater than ⅕ of the diameter of the negative electrode active material.

公开(公告)号：US09537145B2

公开(公告)日：2017-01-03

申请号：US14855604

申请日：2015-09-16

Applicant: Kabushiki Kaisha Toshiba

Inventor： Norikazu Osada ,  Takashi Kuboki ,  Shinsuke Matsuno

IPC: H01M4/131 ,  H01M4/133 ,  H01M4/134 ,  H01M4/36 ,  H01M4/38 ,  H01M4/485 ,  H01M4/587 ,  H01M4/13 ,  H01M4/48 ,  H01M4/62 ,  H01M10/0525 ,  H01M4/02

CPC classification number: H01M4/364 ,  H01M4/13 ,  H01M4/386 ,  H01M4/483 ,  H01M4/587 ,  H01M4/625 ,  H01M10/0525 ,  H01M2004/021

Abstract: A negative electrode for a nonaqueous electrolyte secondary battery of the embodiment includes a current collector; and an electrode mixture layer that is formed on the current collector and contains a first particle, a second particle and a binder. The first particle is comprised of silicon, a silicon oxide and a carbonaceous material. The second particle has electron conductivity and an oxygen content of 1% or lower. The electrode mixture layer is characterized in that silicon concentrations in the vicinity of the surface having contact with the current collector and the vicinity of the opposite surface to the surface having contact with the current collector are higher than a silicon concentration at the central part in the thickness direction.

Abstract translation: 本实施方式的非水电解质二次电池用负极包括集电体， 以及形成在集电体上并含有第一颗粒，第二颗粒和粘合剂的电极混合物层。 第一颗粒由硅，氧化硅和碳质材料构成。 第二颗粒具有电子传导性，氧含量为1％以下。 电极混合层的特征在于，与集电体接触的表面附近的硅浓度与与集电体接触的表面的相反表面附近的硅浓度高于在集电体的中心部分的硅浓度 厚度方向。

公开(公告)号：US09318737B2

公开(公告)日：2016-04-19

申请号：US13774169

申请日：2013-02-22

Applicant: KABUSHIKI KAISHA TOSHIBA

Inventor： Kenji Essaki ,  Takayuki Fukasawa ,  Tomokazu Morita ,  Noikazu Osada ,  Yasuyuki Hotta ,  Takashi Kuboki ,  Toshiro Hiraoka

IPC: H01M4/58 ,  H01M4/134 ,  H01M4/133 ,  H01M4/36 ,  H01M4/62 ,  H01M4/04 ,  H01M4/02

CPC classification number: H01M4/134 ,  H01M4/0471 ,  H01M4/133 ,  H01M4/366 ,  H01M4/625 ,  H01M2004/021 ,  Y02E60/122

Abstract: There is provided a negative electrode material for non-aqueous electrolyte secondary batteries, the negative electrode material being a silicon oxide represented by the composition formula, SiOx, containing silicon and silicon oxide, in which x satisfies the relation of 0.1≦x≦0.8; the silicon oxide contains crystalline silicon; among the particles of crystalline silicon having a diameter of 1 nm or greater, the proportion by number of particles having a diameter of 100 nm or less is 90% or greater; and the BET specific surface area of the silicon oxide is larger than 100 m2/g.

Abstract translation: 提供了一种用于非水电解质二次电池的负极材料，所述负极材料是由组成式表示的氧化硅，SiO x，含有硅和氧化硅，其中x满足0.1＆nlE; x＆nlE; 0.8的关系 ; 氧化硅含有结晶硅; 在直径为1nm以上的结晶性硅颗粒之中，直径为100nm以下的粒子数为90％以上， 并且氧化硅的BET比表面积大于100m 2 / g。

公开(公告)号：US08974958B2

公开(公告)日：2015-03-10

申请号：US13785455

申请日：2013-03-05

Applicant: Kabushiki Kaisha Toshiba

Inventor： Miho Muramatsu ,  Tomokazu Morita ,  Takashi Kuboki ,  Norio Takami

IPC: H01M4/62 ,  H01M4/13

CPC classification number: H01M4/622 ,  H01M4/13

Abstract: An electrode for a nonaqueous electrolyte secondary battery of an embodiment includes: a current collector; and an active material layer including an active material and a binder, formed on the current collector, wherein the binder includes at least an olefin based polymer and a fatty acid, and the fatty acid has a melting point of 25° C. or less and a boiling point of 100° C. or more.

Abstract translation: 一种实施方式的非水电解质二次电池用电极包括：集电体; 以及形成在集电体上的包含活性物质和粘合剂的活性物质层，其中，所述粘合剂至少含有烯烃类聚合物和脂肪酸，所述脂肪酸的熔点为25℃以下， 沸点为100℃以上。

公开(公告)号：US20140024127A1

公开(公告)日：2014-01-23

申请号：US13942954

申请日：2013-07-16

Applicant: KABUSHIKI KAISHA TOSHIBA

Inventor： Hiroko WATANDO ,  Takashi Kuboki

IPC: G01N30/96 ,  C07C213/10 ,  C07C241/00

CPC classification number: G01N30/96 ,  B01D15/00 ,  B01D53/1418 ,  B01D53/1475 ,  B01J39/17 ,  B01J49/06 ,  B01J49/53 ,  B01J49/60 ,  C07C213/10 ,  C07C241/00 ,  Y02C10/06 ,  Y02C10/08 ,  Y10T436/147777 ,  Y10T436/170769 ,  Y10T436/173845

Abstract: The objects of embodiments in the present disclosure are to provide a method capable of recovering two or more amine compounds at the same time from a gas or solution, and also to provide a method capable of analyzing the recovered amines.The amine-recovering method comprises the steps (A) and (B). In the step (A), the gas or solution is brought into contact with a solid adsorbent so that the adsorbent may retain the amines. In the step (B), the amines retained by the adsorbent in the step (A) are eluted out by use of a basic compound-containing organic solvent. The solid adsorbent has a substituent group represented by —SO3M (M is H or an alkali metal).

Abstract translation: 本公开内容的实施方案的目的是提供能够从气体或溶液中同时回收两种或更多种胺化合物的方法，并且还提供能够分析回收的胺的方法。 胺回收方法包括步骤（A）和（B）。 在步骤（A）中，使气体或溶液与固体吸附剂接触，使得吸附剂可以保留胺。 在步骤（B）中，通过使用含碱性化合物的有机溶剂洗脱由步骤（A）中的吸附剂保留的胺。 固体吸附剂具有由-SO 3 M（M为H或碱金属）表示的取代基。

公开(公告)号：US20130337314A1

公开(公告)日：2013-12-19

申请号：US13774169

申请日：2013-02-22

Applicant: KABUSHIKI KAISHA TOSHIBA

Inventor： Kenji Essaki ,  Takayuki Fukasawa ,  Tomokazu Morita ,  Noikazu Osada ,  Yasuyuki Hotta ,  Takashi Kuboki ,  Toshiro Hiraoka

IPC: H01M4/134 ,  H01M4/133

CPC classification number: H01M4/134 ,  H01M4/0471 ,  H01M4/133 ,  H01M4/366 ,  H01M4/625 ,  H01M2004/021 ,  Y02E60/122

Abstract: There is provided a negative electrode material for non-aqueous electrolyte secondary batteries, the negative electrode material being a silicon oxide represented by the composition formula, SiOx, containing silicon and silicon oxide, in which x satisfies the relation of 0.1≦x≦0.8; the silicon oxide contains crystalline silicon; among the particles of crystalline silicon having a diameter of 1 nm or greater, the proportion by number of particles having a diameter of 100 nm or less is 90% or greater; and the BET specific surface area of the silicon oxide is larger than 100 m2/g.

Abstract translation: 提供一种用于非水电解质二次电池的负极材料，该负极材料是由组成式表示的氧化硅，SiO x含有硅和氧化硅，其中x满足0.1 @ x @ 0.8的关系; 氧化硅含有结晶硅; 在直径为1nm以上的结晶性硅颗粒之中，直径为100nm以下的粒子数为90％以上， 并且氧化硅的BET比表面积大于100m 2 / g。

公开(公告)号：US20130330627A1

公开(公告)日：2013-12-12

申请号：US13969104

申请日：2013-08-16

Applicant: KABUSHIKI KAISHA TOSHIBA

Inventor： Shinsuke Matsuno ,  Hiromichi Kuriyama ,  Hideki Satake ,  Takashi Kuboki

IPC: H01M4/485 ,  H01M4/505 ,  H01M4/525

CPC classification number: H01M10/05 ,  H01M4/13 ,  H01M4/131 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5825 ,  H01M10/0525 ,  H01M2004/027 ,  H01M2004/028 ,  Y02E60/122

Abstract: According to one embodiment, there is provided a non-aqueous electrolyte secondary battery including a positive electrode including a positive electrode active material layer, a negative electrode including a negative electrode active material layer, and a non-aqueous electrolyte. At least one of the positive electrode active material layer and the negative electrode active material layer contains carbon dioxide and releases the carbon dioxide in the range of 0.1 ml to 10 ml per 1 g when heated at 350° C. for 1 minute.