利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

85 条记录 (耗时 0.026 秒)

    Electrolytic cation exchange membrane
    61.
    发明授权
    Electrolytic cation exchange membrane 失效
    电解阳离子交换膜

    公开(公告)号：US4486277A

    公开(公告)日：1984-12-04

    申请号：US493574

    申请日：1983-05-11

    申请人： Haruhisa Miyake ,  Manabu Suhara ,  Hiroshi Mori ,  Yoshihiko Saito

    发明人： Haruhisa Miyake ,  Manabu Suhara ,  Hiroshi Mori ,  Yoshihiko Saito

    IPC分类号： C25B13/08 ,  C08J5/22 ,  C25B1/14 ,  C25B13/00

    CPC分类号： C08J5/2281 ,  C08J2327/18

    摘要： An electrolytic cation exchange membrane comprises a first film made of a fluorinated polymer having cation exchange groups and a second film laminated thereon, made of a fluorinated polymer having carboxylic acid groups as its ion exchange groups and containing the following repeating units (A), (B) and (C) and having a smaller thickness and greater specific electric resistance than the first film; ##STR1## where each of X and X' is --F, --Cl or --CF.sub.3, R.sub.f is a perfluoroalkyl group having from 1 to 10 carbon atoms, M is hydrogen or an alkali metal and Y is selected from the group consisting of --CF.sub.2).sub.x, --O--CF.sub.2).sub.x, ##STR2## where each of x and y is an integer of from 0 to 10 and Z is --F or R.sub.f as defined above, provided that B/A+B+C (molar ratio) and C/A+B+C (molar ratio) are from 0.01 to 0.3 and from 0.05 to 0.5, respectively.

    摘要翻译： 电解阳离子交换膜包括由具有阳离子交换基团的氟化聚合物制成的第一膜和层压在其上的第二膜，由具有羧酸基的氟化聚合物作为其离子交换基团并含有以下重复单元（A），（ B）和（C），并且具有比第一膜更小的厚度和更大的比电阻; （C）其中X和X'各自为-F，-Cl或-CF 3，R f为具有1至10个碳原子的全氟烷基，M（C 1 -C 6） 是氢或碱金属，Y选自-CF 2）x，-O-CF 2）x，其中x和y各自为0至10的整数，Z为-F或 只要B / A + B + C（摩尔比）和C / A + B + C（摩尔比）分别为0.01至0.3和0.05至0.5，则定义如上。

    Process for producing alkali metal hydroxide
    62.
    发明授权
    Process for producing alkali metal hydroxide 失效
    碱金属氢氧化物的制备方法

    公开(公告)号：US4065366A

    公开(公告)日：1977-12-27

    申请号：US728017

    申请日：1976-09-29

    申请人： Yoshio Oda ,  Manabu Suhara ,  Eiji Endo

    发明人： Yoshio Oda ,  Manabu Suhara ,  Eiji Endo

    IPC分类号： C25B13/08 ,  C08J5/22 ,  C25B1/46 ,  C25B1/16 ,  C25B1/26

    CPC分类号： C25B1/46 ,  C08J5/2237 ,  C08J2327/12

    摘要： In a process for producing an alkali metal hydroxide which comprises electrolysis of an aqueous solution of an alkali metal chloride in an electrolytic cell having an anode compartment and a cathode compartment which are partitioned by a fluorinated cation exchange membrane, the improvement which comprises a fluorinated cation exchange membrane made of a fluorinated copolymer having carboxylic acid groups as the ion exchange group and having an ion exchange capacity of 0.5 to 2.0 meq/g dry polymer and a concentration of carboxylic acid groups of 8 to 30 meq/g water absorbed by the membrane when contacted with an aqueous solution of the alkali metal hydroxide having about the same concentration of alkali metal hydroxide as that of catholyte during said electrolysis.

    摘要翻译： 在制造碱金属氢氧化物的方法中，其包括在具有由氟化阳离子交换膜分隔的阳极室和阴极室的电解池中电解碱金属氯化物水溶液，其改进包括氟化阳离子 由具有羧酸基的氟化共聚物作为离子交换基团并具有0.5-2.0meq / g干燥聚合物的离子交换容量和由膜吸收的8至30meq / g水的羧酸基团的浓度的交换膜 当与所述电解期间具有与阴极电解液相同浓度的碱金属氢氧化物的碱金属氢氧化物的水溶液接触时。

    Cathode active material powder for lithium secondary battery
    65.
    发明授权
    Cathode active material powder for lithium secondary battery 有权
    锂二次电池用正极活性物质粉末

    公开(公告)号：US07429434B2

    公开(公告)日：2008-09-30

    申请号：US11610529

    申请日：2006-12-14

    申请人： Takuya Mihara ,  Yukimitsu Wakasugi ,  Naoshi Saito ,  Manabu Suhara

    发明人： Takuya Mihara ,  Yukimitsu Wakasugi ,  Naoshi Saito ,  Manabu Suhara

    IPC分类号： H01M4/50 ,  H01M4/52 ,  H01M4/58

    CPC分类号： C01G51/006 ,  C01B25/45 ,  C01G45/1228 ,  C01G45/1235 ,  C01G45/1242 ,  C01G51/42 ,  C01G51/50 ,  C01G53/006 ,  C01G53/50 ,  C01P2002/72 ,  C01P2004/61 ,  C01P2006/40 ,  H01M4/02 ,  H01M4/131 ,  H01M4/1315 ,  H01M4/364 ,  H01M4/505 ,  H01M4/525 ,  H01M4/582 ,  H01M4/587 ,  H01M10/052 ,  H01M10/0565 ,  H01M2004/028

    摘要： It is to provide a cathode active material powder for a positive electrode for a lithium secondary battery, which has a large volume capacity density, high safety and excellent durability for charge and discharge cycles. A cathode active material powder for a lithium secondary battery characterized by comprising a first composite oxide powder represented by the formula (1) LipQxMyOzFa (wherein Q is Co or Mn, M is aluminum or an alkaline earth metal element or a transition metal element other than Q, provided that when Q is Co, 0.9≦p≦1.1, 0.980≦x≦1.000, 0≦y≦0.02, 1.9≦z≦2.1, x+y=1, and 0≦a≦0.02, and when Q is Mn, 1≦p≦1.3, x=2−y, 0≦y≦0.05, z=4, and a=0), having an average particle size D50 of from 5 to 30 μm, and having a compression breaking strength of at least 40 MPa; and a second composite oxide powder represented by the formula (2) LipNixCoyMnzNqOrFa (wherein N is aluminum or an alkaline earth metal element or a transition metal element other than Ni, Co and Mn, 0.9≦p≦1.1, 0.2≦x≦0.8, 0≦y≦0.4, 0≦z≦0.5, 0≦q≦0.05, 1.9≦r≦2.1, x+y+z+q=1, and 0≦a≦0.02), having an average particle size D50 of from 2 to 30 μm, and having a compression breaking strength less than 40 MPa; in a ratio (weight ratio) of the first composite oxide powder/the second composite oxide powder being from 95/5 to 30/70.

    摘要翻译： 本发明提供一种锂二次电池用正极用正极活性物质粉末，其具有容量密度大，安全性高，充放电循环优异的耐久性。 一种锂二次电池用正极活性物质粉末，其特征在于，含有式（1）表示的第一复合氧化物粉末， （其中Q是Co或Mn，M是铝或碱土金属元素或Q以外的过渡金属元素，条件是当Q 是Co，0.9 <= p <= 1.1,0.980 <= x <= 1.000,0 <= y <= 0.02,1.9 <= z <= 2.1，x + y = 1，0 <= a <= 0.02， 当Q为Mn时，平均粒度D50为5〜30μm，1≤p≤3.3，x = 2-y，0≤y≤0.05，z = 4，a = 0） 并且具有至少40MPa的压缩断裂强度; 和由式（2）表示的第二复合氧化物粉末LiNi x N x Mn x N （其中N为铝或碱土金属元素或Ni之外的过渡金属元素，Co和Mn， 0.9 <= p <= 1.1,0.2 <= x <= 0.8,0 <= y <= 0.4,0 <= z <= 0.5,0 <= q <= 0.05,1.9 <= r = 2.1，x + y + z + q = 1，0 <= a <= 0.02），平均粒径D50为2〜30μm，压缩断裂强度小于40MPa; 第一复合氧化物粉末/第二复合氧化物粉末的比例（重量比）为95/5〜30/70。

    CATHODE ACTIVE MATERIAL POWDER FOR LITHIUM SECONDARY BATTERY
    66.
    发明申请
    CATHODE ACTIVE MATERIAL POWDER FOR LITHIUM SECONDARY BATTERY 有权
    用于锂二次电池的阴极活性材料粉末

    公开(公告)号：US20070099087A1

    公开(公告)日：2007-05-03

    申请号：US11610529

    申请日：2006-12-14

    申请人： Takuya MIHARA ,  Yukimitsu Wakasugi ,  Naoshi Saito ,  Manabu Suhara

    发明人： Takuya MIHARA ,  Yukimitsu Wakasugi ,  Naoshi Saito ,  Manabu Suhara

    IPC分类号： H01M4/58 ,  H01M4/50 ,  H01M4/52

    CPC分类号： C01G51/006 ,  C01B25/45 ,  C01G45/1228 ,  C01G45/1235 ,  C01G45/1242 ,  C01G51/42 ,  C01G51/50 ,  C01G53/006 ,  C01G53/50 ,  C01P2002/72 ,  C01P2004/61 ,  C01P2006/40 ,  H01M4/02 ,  H01M4/131 ,  H01M4/1315 ,  H01M4/364 ,  H01M4/505 ,  H01M4/525 ,  H01M4/582 ,  H01M4/587 ,  H01M10/052 ,  H01M10/0565 ,  H01M2004/028

    摘要： It is to provide a cathode active material powder for a positive electrode for a lithium secondary battery, which has a large volume capacity density, high safety and excellent durability for charge and discharge cycles. A cathode active material powder for a lithium secondary battery characterized by comprising a first composite oxide powder represented by the formula (1) LipQxMyOzFa (wherein Q is Co or Mn, M is aluminum or an alkaline earth metal element or a transition metal element other than Q, provided that when Q is Co, 0.9≦p≦1.1, 0.980≦x≦1.000, 0≦y≦0.02, 1.9≦z≦2.1, x+y=1, and 0≦a≦0.02, and when Q is Mn, 1≦p≦1.3, x=2−y, 0≦y≦0.05, z=4, and a=0), having an average particle size D50 of from 5 to 30 μm, and having a compression breaking strength of at least 40 MPa; and a second composite oxide powder represented by the formula (2) LipNixCoyMnzNqOrFa (wherein N is aluminum or an alkaline earth metal element or a transition metal element other than Ni, Co and Mn, 0.9≦p≦1.1, 0.2≦x≦0.8, 0≦y≦0.4, 0≦z≦0.5, 0≦q≦0.05, 1.9≦r≦2.1, x+y+z+q=1, and 0≦a≦0.02), having an average particle size D50 of from 2 to 30 μm, and having a compression breaking strength less than 40 MPa; in a ratio (weight ratio) of the first composite oxide powder/the second composite oxide powder being from 95/5 to 30/70.

    摘要翻译： 本发明提供一种锂二次电池用正极用正极活性物质粉末，其具有容量密度大，安全性高，充放电循环优异的耐久性。 一种锂二次电池用正极活性物质粉末，其特征在于，含有式（1）表示的第一复合氧化物粉末， （其中Q是Co或Mn，M是铝或碱土金属元素或Q以外的过渡金属元素，条件是当Q 是Co，0.9 <= p <= 1.1,0.980 <= x <= 1.000,0 <= y <= 0.02,1.9 <= z <= 2.1，x + y = 1，0 <= a <= 0.02， 当Q为Mn时，平均粒度D50为5〜30μm，1≤p≤3.3，x = 2-y，0≤y≤0.05，z = 4，a = 0） 并且具有至少40MPa的压缩断裂强度; 和由式（2）表示的第二复合氧化物粉末LiNi x N x Mn x N （其中N为铝或碱土金属元素或Ni之外的过渡金属元素，Co和Mn， 0.9 <= p <= 1.1,0.2 <= x <= 0.8,0 <= y <= 0.4,0 <= z <= 0.5,0 <= q <= 0.05,1.9 <= r = 2.1，x + y + z + q = 1，0 <= a <= 0.02），平均粒径D50为2〜30μm，压缩断裂强度小于40MPa; 第一复合氧化物粉末/第二复合氧化物粉末的比例（重量比）为95/5〜30/70。

    Process for producing positive electrode active material for lithium secondary battery
    67.
    发明授权
    Process for producing positive electrode active material for lithium secondary battery 有权
    锂二次电池用正极活性物质的制造方法

    公开(公告)号：US07192672B2

    公开(公告)日：2007-03-20

    申请号：US11136493

    申请日：2005-05-25

    申请人： Kazushige Horichi ,  Manabu Suhara ,  Naoshi Saito ,  Megumi Uchida

    发明人： Kazushige Horichi ,  Manabu Suhara ,  Naoshi Saito ,  Megumi Uchida

    IPC分类号： H01M4/00

    CPC分类号： H01M10/0525 ,  C01G51/42 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/1315 ,  H01M4/485 ,  H01M4/525 ,  H01M2004/021

    摘要： To provide a process for producing a lithium-cobalt composite oxide for a positive electrode of a lithium secondary battery, which has a large volume capacity density, high safety, high charge and discharge cycle durability, high press density and high productivity.A process for producing a lithium-cobalt composite oxide represented by the formula LipCoxMyOzFa (wherein M is a transition metal element other than Co, or an alkaline earth metal element, 0.9≦p≦1.1, 0.980≦x≦1.000, 0≦y≦0.02, 1.9≦z≦2.1, x+y=1, and 0≦a≦0.02), characterized in that as a cobalt source, a mixture is used which comprises cobalt hydroxide in the form of substantially spherical secondary particles with an average particle size of from 8 to 20 μm formed by agglomeration of primary particles and tricobalt tetroxide in the form of secondary particles with an average particle size of from 2 to 10 μm formed by agglomeration of primary particles, in a cobalt atomic ratio of from 5:1 to 1:5, and firing is carried out at from 700 to 1,050° C.

    摘要翻译： 为了提供具有大容量密度，高安全性，高充放电循环耐久性，高压力密度和高生产率的锂二次电池正极用锂钴复合氧化物的制造方法。 一种由下式表示的锂 - 钴复合氧化物的制备方法：其中R 1，R 2，R 2， （其中M是除Co以外的过渡金属元素或碱土金属元素，0.9 <= p <= 1.1,0.980 <= x <= 1.000,0 <= y < 0.02，1.9 <= z <= 2.1，x + y = 1，0 <= a <= 0.02），其特征在于，作为钴源，使用包含基本上球形二次粒子形式的氢氧化钴的混合物 平均粒度为8〜20μm的原子粒子的原子比通过一次粒子的聚集而形成的平均粒径为2〜10μm的二次粒子的一次粒子和四氧化四铁的凝聚而形成的平均粒径为8〜 从5:1至1:5，并且在700至1050℃进行烧制。

    Particulate positive electrode active material for a lithium secondary cell
    70.
    发明授权
    Particulate positive electrode active material for a lithium secondary cell 有权
    用于锂二次电池的微粒正极活性材料

    公开(公告)号：US07018741B2

    公开(公告)日：2006-03-28

    申请号：US10916391

    申请日：2004-08-12

    申请人： Manabu Suhara ,  Naoshi Saito ,  Tsutomu Kato ,  Megumi Yukawa

    发明人： Manabu Suhara ,  Naoshi Saito ,  Tsutomu Kato ,  Megumi Yukawa

    IPC分类号： H01M4/58

    CPC分类号： H01M4/505 ,  C01G51/42 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2004/32 ,  C01P2004/61 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/485 ,  H01M4/525 ,  H01M4/582 ,  H01M10/052 ,  H01M2004/021 ,  H01M2004/028

    摘要： A particulate positive electrode active material for a lithium secondary cell which satisfies high charge and discharge cyclic durability, high safety, high temperature storage properties, a high discharge average voltage, large current discharge properties, a high weight capacity density, a high volume capacity density, etc. in a well-balanced manner is provided. A particulate positive electrode active material for a lithium secondary cell, which is represented by the formula LipCoxMyOzFa (wherein M is at least one element selected from Groups 2 to 8, 13 and 14 of the Periodic Table, 0.9≦p≦1.1, 0.980≦x≦0.9999, 0.0001≦y≦0.02, 1.9≦z≦2.1, 0.9≦x+y≦1 and 0.0001≦a≦0.02), wherein fluorine atoms and element M are unevenly distributed on the particle surface, the atomic ratio of fluorine atoms to cobalt atoms (a/x) is from 0.0001 to 0.02, and in powder X-ray diffraction using CuKα-ray, the half value width of the angle of diffraction on (110) plane is from 0.06 to 0.13°, and the half value width of the angle of diffraction on (003) plane is from 0.05 to 0.12°.

    摘要翻译： 一种满足高充放电循环耐久性，高安全性，高温保存性，高放电平均电压，大电流放电特性，高重量容量密度，高体积容量密度的锂二次电池用微粒正极活性物质 等等。 一种用于锂二次电池的颗粒状正极活性物质，其由下式表示：其中R 1，R 2，R 2， （其中M是选自周期表第2至8,13和14族中的至少一种元素，0.9 <= p <= 1.1,0.980 <= x <= 0.9999,0.0001 <= y <= 0.02,1.9 <= z <= 2.1,0.9 <= x + y <= 1和0.0001 <= a <= 0.02），其中氟原子和元素M不均匀地分布在颗粒表面 ，氟原子与钴原子的原子比（a / x）为0.0001〜0.02，在使用CuKα射线的粉末X射线衍射中，（110）面的衍射角的半值宽度为0.06 至0.13°，（003）面上的衍射角的半值宽度为0.05〜0.12°。