Thermal dye transfer system with receiver containing reactive carbonyl
group
    62.
    发明授权
    Thermal dye transfer system with receiver containing reactive carbonyl group 失效
    具有含有反应性羰基的受体的热染料转移体系

    公开(公告)号:US5510314A

    公开(公告)日:1996-04-23

    申请号:US410195

    申请日:1995-03-24

    摘要: A thermal dye transfer assemblage comprising:(a) a dye-donor element comprising a support having thereon a dye layer comprising a dye dispersed in a polymeric binder, the dye being substituted with a reactive primary or secondary aliphatic amino group, and(b) a dye-receiving element comprising a support having thereon a dye image-receiving layer, the dye-receiving element being in a superposed relationship with the dye-donor element so that the dye layer is in contact with the dye image-receiving layer, the dye image-receiving layer comprising a polymer containing a plurality of functional groups:R.sup.2 --CO--X--R.sup.3 wherein:R.sup.2 represents alkyl, aryl, alkoxy or aryloxy;X represents oxygen or sulfur; andR.sup.3 represents aryl or hetaryl; with the proviso that R.sup.2 or R.sup.2 and R.sup.3 are directly attached to the polymer chain.

    摘要翻译: 一种热染料转移组合物,包括:(a)染料供体元件,其包含其上具有染料层的载体,染料层包含分散在聚合物粘合剂中的染料,所述染料被反应性伯或仲脂族氨基取代,和(b) 染料接收元件,其包括其上具有染料影像接收层的支持体,所述染料接收元件与所述染料供体元件重叠关系,使得染料层与染料影像接收层接触, 包含含有多个官能团的聚合物的染料影像接受层:R2-CO-X-R3其中:R2代表烷基,芳基,烷氧基或芳氧基; X表示氧或硫; R3代表芳基或杂芳基; 条件是R2或R2和R3直接连接到聚合物链上。

    Yellow dye mixture for thermal color proofing

    公开(公告)号:US5045524A

    公开(公告)日:1991-09-03

    申请号:US628817

    申请日:1990-12-14

    摘要: A yellow dye-donor element for thermal dye transfer comprises a support having thereon a dye layer comprising a mixture of yellow dyes dispersed in a polymeric binder, at least one of the yellow dyes having the formula: ##STR1## wherein: each R.sup.1 independently represents a substituted or unsubstituted alkyl group of from 1 to about 10 carbon atoms, a cycloalkyl group of from about 5 to about 7 carbon atoms; a substituted or unsubstituted allyl group; an aryl group of from about 6 to about 10 carbon atoms; a hetaryl group of from 5 to 10 atoms; acyl; arylsulfonyl; aminocarbonyl; aminosulfonyl; fluorosulfonyl; halogen; nitro; alkylthio; or arylthio;or any two adjacent R.sup.1 's together represent the atoms necessary to form a 5- or 6-membered fused ring;n represents an integer from 0-4;R.sup.2 represents hydrogen; a substituted or unsubstituted alkyl, cycloalkyl, allyl, aryl or hetaryl group as described above for R.sup.1 ; cyano; acyl; alkylsulfonyl; arylsulfonyl; or alkoxycarbonyl;Z represents cyano; alkoxycarbonyl; acyl; nitro; arylsulfonyl or alkylsulfonyl;Y represents hydrogen; a substituted or unsubstituted alkyl, cycloalkyl, allyl, aryl or hetaryl group as described above for R.sup.1 ; amino; alkylamino; arylamino; acylamino; or sulfonylamino;and at least one of the other of the dyes having the formula: ##STR2## wherein: R.sup.3 and R.sup.4 each independently represents the same groups as R.sup.1 above;R.sup.5 represents H, a substituted or unsubstituted alkyl, allyl, aryl or hetaryl group as described above for R.sup.1 ; halogen; carbamoyl; cyano; or alkoxycarbonyl;each R.sup.6 independently represents substituted or unsubstituted alkyl, aryl, allyl or hetaryl groups such as those listed above for R.sup.1 ; hydroxy, alkoxy, aryloxy, acyloxy, aminocarbonyl, aminosulfonyl, carbamoyloxy, halogen, aryl, cyano, nitro, trifluoromethyl, fluorosulfonyl, acylamido, alkoxycarbonyl, alkylthio, arylthio, alkylsulfonyl, arylsulfonyl, alkylsulfonamido or arylsulfonamido; or two adjacent R.sup.6 's together represent the atoms necessary to complete a 5- or 6-membered fused saturated or aromatic ring;X represents CR.sup.7 or N;R.sup.7 represents the same groups as R.sup.5 ; andm is an integer from 0 to 5.

    Pyridoneindoaniline dye-donor element for thermal dye transfer
    67.
    发明授权
    Pyridoneindoaniline dye-donor element for thermal dye transfer 失效
    用于热染料转移的吡啶二酮苯胺染料供体元件

    公开(公告)号:US5026678A

    公开(公告)日:1991-06-25

    申请号:US606369

    申请日:1990-10-31

    摘要: A dye-donor element for thermal dye transfer comprises a support having thereon a dye dispersed in a polymeric binder, the dye comprising a pyridoneindoaniline dye having the formula: ##STR1## wherein: R.sup.1 and R.sup.2 each independently represents hydrogen; a substituted or unsubstituted alkyl group having from 1 to about 6 carbon atoms; a substituted or unsubstituted cycloalkyl group having from about 5 to about 7 carbon atoms; a substituted or unsubstituted allyl group; a substituted or unsubstituted aryl group having from about 6 to about 10 carbon atoms; or a substituted or unsubstituted hetaryl group; orR.sup.1 and R.sup.2 can be joined together to form, along with the nitrogen to which they are attached, a 5- to 7-membered heterocyclic ring; oreither or both of R.sup.1 and R.sup.2 can be combined with R.sup.3 to form a 5- to 7-membered heterocyclic ring;each R.sup.3 independently represents a substituted or unsubstituted alkyl group having from 1 to about 6 carbon atoms; a substituted or unsubstituted cycloalkyl group having from about 5 to about 7 carbon atoms; a substituted or unsubstituted allyl group; a substituted or unsubstituted aryl group having from about 6 to about 10 carbon atoms; a substituted or unsubstituted hetaryl group; alkoxy; aryloxy; halogen; nitro; cyano; thiocyano; hydroxy; acyloxy; acyl; alkoxycarbonyl; aminocarbonyl; alkoxycarbonyloxy; carbamoyloxy; acylamido; ureido; imido; alkylsulfonyl; arylsulfonyl; alkylsulfonamido; arylsulfonamido; alkylthio; arylthio or trifluoromethyl; orany two of R.sup.3 may be combined together to form a 5- or 6-membered carbocyclic or heterocyclic ring; orone or two of R.sup.3 may be combined with either or both of R.sup.1 and R.sup.2 to complete a 5- to 7-membered ring;m is an integer of from 0 to 4;R.sup.4 and R.sup.5 each independently represents hydrogen; a substituted or unsubstituted alkyl group having from 1 to about 6 carbon atoms; a substituted or unsubstituted aryl group having from about 6 to about 10 carbon atoms; a substituted or unsubstituted hetaryl group; or an electron withdrawing group;R.sup.6 represents hydrogen; a substituted or unsubstituted alkyl, aryl, or hetaryl group as described above for R.sup.1 and R.sup.2 ; NH.sub.2, NHR.sup.1, NR.sup.1 R.sup.2, NHCOR.sup.1, NHSO.sub.2 R.sup.1 or OR.sup.1.

    Infrared absorbing indene-bridged-polymethine dyes for dye-donor element
used in laser-induced thermal dye transfer
    68.
    发明授权
    Infrared absorbing indene-bridged-polymethine dyes for dye-donor element used in laser-induced thermal dye transfer 失效
    用于激光诱导热染料转移的染料供体元件的红外吸收茚 - 桥联聚甲炔染料

    公开(公告)号:US5019480A

    公开(公告)日:1991-05-28

    申请号:US367064

    申请日:1989-06-16

    摘要: A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer and an infrared-absorbing material which is different from the dye in the dye layer, and wherein the infrared-absorbing material is an indene-bridged-polymethine dye. In a preferred embodiment, the indene-bridged-polymethine dye has the following formula: ##STR1## wherein: R represents a substituted or unsubstituted alkyl or cycloalkyl group having from 1 to about 6 carbon atoms or an aryl or hetaryl group having from about 5 to about 10 atoms; R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, sulfonyl, carbamoyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryly group; or any two of said R, R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 groups may be joined together to form a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring;A represents --COR, --CO.sub.2 R, --CONHR, --CONR.sub.2, --SO.sub.2 R, --SO.sub.2 NHR, --SO.sub.2 NR.sub.2 or --CN;B represents A or hydrogen, --R, --SR, --OR or --NR; or A or B may be joined together to form a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring;Y represents a dialkyl-substituted carbon atom, a vinylene group, an oxygen atom, a sulfur atom, a selenium atom, a tellurium atom, NR, or a direct bond to the carbon at the R.sup.2 position;Z represents hydrogen or the atoms necessary to complete a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring; andn is 0 to 3.

    Thermally-transferred color filter array element and process for
preparing
    69.
    发明授权
    Thermally-transferred color filter array element and process for preparing 失效
    热转印滤色片阵列元件及其制备方法

    公开(公告)号:US4975410A

    公开(公告)日:1990-12-04

    申请号:US358976

    申请日:1989-05-26

    摘要: A thermally-transferred color filter array element comprising a transparent support having thereon a thermally-transparent image comprising a repeating mosaic pattern of colorants in a receiving layer, one of the colorants being a mixture of a yellow dye and a cyan dye to form a green hue, said yellow dye having the formula: ##STR1## wherein: R.sup.1 and R.sup.2 represents hydrogen, alkyl, cycloalkyl, aryl or hetaryl; or can be taken together to form a 5- or 6-membered ring; or either or both of R.sup.1 and R.sup.2 can be joined to a carbon atom of the aromatic ring to form a 5- or 6-membered ring;R.sup.3 represents hydrogen or halogen:Y represents hydrogen, halogen, cyano, alkyl, alkoxy, aryl, hetaryl, aryloxy, acylamido, alkylsulfonamido, or arylsulfonamido; andn is a positive integer from 1 to 5; andsaid cyan dye having the formula: ##STR2## wherein R.sup.4 R.sup.5 represents hydrogen, alkyl, cycloalkyl, aryl or hetaryl;R.sup.6 represents hydrogen, alkyl or alkoxy;R.sup.5 may be taken together with R.sup.4 to form a 5- or 6-membered ring;R.sup.4 or R.sup.5 may be combined with R.sup.6 or may be joined to the carbon atom of the benzene ring to form a 5- or 6-membered ring;R.sup.7 represents hydrogen, alkyl, alkoxy, halogen, sulfonamido or acylamido;R.sup.8 represents nitro, cyano, fluorosulfonyl, alkylsulfonyl, arylsulfonyl, acyl, alkoxycarbonyl, carbamoyl, sulfamoyl, trifluoromethyl or halogen;R.sup.9 represents nitro, cyano, acyl, trifluoroacetyl, dicyanovinyl or tricyanovinyl; andJ represents --S-- or --CH.dbd.CR.sup.8 --.

    Infrared absorbing bis(chalcogenopyrylo)polymethine dyes for dye-donor
element used in laser-induced thermal dye transfer
    70.
    发明授权
    Infrared absorbing bis(chalcogenopyrylo)polymethine dyes for dye-donor element used in laser-induced thermal dye transfer 失效
    用于激光诱导热染料转移的染料供体元件的红外吸收双(硫属元素复合)聚甲炔染料

    公开(公告)号:US4948777A

    公开(公告)日:1990-08-14

    申请号:US366970

    申请日:1989-06-16

    摘要: A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer and an infrared-absorbing material which is different from the dye in the dye layer, and wherein the infrared-absorbing material is a bis(chalcogenopyrylo)polymethine dye. In a preferred embodiment, the bis(chalcogenopyrylo)polymethine dye has the following formula: ##STR1## wherein: R.sup.1, R.sup.2 and R.sup.3 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, sulfonyl, carbamoyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryl group; or any two of said R.sup.1, R.sup.2 and R.sup.3 groups may be joined together to form a 5- to 7-membered substituted or unsubstituted carboxyclic or heterocyclic ring; or R.sup.1 may be joined to Z.sup.1 to form a fused 5- or 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring; or R.sup.3 may be joined to Z.sup.2 to form a fused 5- or 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring;Y.sup.1 and Y.sup.2 each independently represents sulfur, oxygen, tellurium, or selenium, with the methine chain being joined ortho or para to each of Y.sup.1 and Y.sup.2 ;Z.sup.1 and Z.sup.2 each independently represents hydrogen; a substituted or unsubstituted alkyl group having from 1 to about 6 carbon atoms; a substituted or unsubstituted aryl or hetaryl group having from about 5 to about 10 atoms; or the atoms necessary to complete a 5- to 7-membered carbocyclic or heterocyclic ring;each m independently is 1 to 4;n is 1 to 3; andX is a monovalent anion.