公开(公告)号：US5034303A

公开(公告)日：1991-07-23

申请号：US367061

申请日：1989-06-16

申请人： Steven Evans ,  Charles D. DeBoer

发明人： Steven Evans ,  Charles D. DeBoer

IPC分类号： D06P5/00 ,  B41M5/382 ,  B41M5/385 ,  B41M5/388 ,  B41M5/39 ,  B41M5/392 ,  B41M5/46

CPC分类号： B41M5/465 ,  B41M5/392 ,  Y10S430/145

摘要： A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer and an infrared-absorbing material which is different from the dye in the dye layer, and wherein the infrared-absorbing material is a trinuclear cyanine dye. In a preferred embodiment, the trinuclear cyanine dye has the following formula: ##STR1## wherein: R.sup.1, R.sup.2 and R.sup.3 each independently represents a substituted or unsubstituted alkyl or cycloalkyl group having from 1 to about 6 carbon atoms or an aryl or hetaryl group having from about 5 to about 10 atoms;R.sup.4, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, sulfonyl, carbamoyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryl group;or any of said R.sup.4, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 groups may be combined with R.sup.1, R.sup.2 or R.sup.3 or with each other to form a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring;J is NR.sup.1 O, or S;Z.sup.1 and Z.sup.2 each independently represents hydrdogen, R.sup.1 or the atoms necessary to form a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring;Y.sup.1 and Y.sup.2 each independently represents a dialkyl-substituted carbon atom, a vinylene group, an oxygen atom, a sulfur atom, a selenium atom, a tellurium atom, NR.sup.1, or a direct bond to the carbon at the R.sup.5 or R.sup.7 position;m and n are each independently 0 to 3, with the proviso that n+m is at least 3; andX is a monovalent anionic group isolated or covalently attached to any of said R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8, Z.sup.1 or Z.sup.2 groups.

公开(公告)号：US4950639A

公开(公告)日：1990-08-21

申请号：US366968

申请日：1989-06-16

申请人： Charles D. DeBoer ,  Steven Evans

发明人： Charles D. DeBoer ,  Steven Evans

IPC分类号： B41M5/392 ,  B41M5/382 ,  B41M5/46

CPC分类号： B41M5/465 ,  B41M5/392 ,  Y10S428/913 ,  Y10S428/914 ,  Y10S430/146 ,  Y10T428/31786

摘要： A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer and an infrared-absorbing material which is different from the dye in the dye layer, and wherein the infrared-absorbing material is a bis(aminoaryl)polymethine dye. In a preferred embodiment, the bis(aminoaryl)polymethine dye has the following formula: ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, sulfonyl, carbamoyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryl group; or any two of said R.sup.1, R.sup.2 and R.sup.3 groups may be joined together or with an adjacent aromatic ring to complete a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring;R.sup.4, R.sup.5, R.sup.6 and R.sup.7 each independently represents hydrogen, a substituted or unsubstituted alkyl or cycloalkyl group having from 1 to about 6 carbon atoms or an aryl or hetaryl group having from about 5 to about 10 atoms;or R.sup.4 and R.sup.5 or R.sup.6 and R.sup.7 may be joined together to form a 5- to 7-membered heterocyclic ring;or R.sup.4, R.sup.5, R.sup.6 or R.sup.7 may be joined to the carbon atom of the adjacent aromatic ring at a position ortho to the position of attachment of the anilino nitrogen to form, along with the nitrogen to which they are attached, a 5-or 6-membered heterocyclic ring;n is 1 to 5;X is a monovalent anion;Z.sup.1 and Z.sup.2 each independently represents R.sup.1 or the atoms necessary to complete a 5- to 7-membered fused carbocyclic or heterocyclic ring; and m and p are each 4.

公开(公告)号：US4950640A

公开(公告)日：1990-08-21

申请号：US366967

申请日：1989-06-16

申请人： Steven Evans ,  Charles D. DeBoer

发明人： Steven Evans ,  Charles D. DeBoer

IPC分类号： B41M5/382 ,  B41M5/385 ,  B41M5/388 ,  B41M5/39 ,  B41M5/392 ,  B41M5/42 ,  B41M5/46 ,  D06P5/00

CPC分类号： B41M5/465 ,  B41M5/392 ,  Y10S428/913 ,  Y10S428/914 ,  Y10S430/146 ,  Y10T428/31786

摘要： A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer and an infrared-absorbing material which is different from the dye in the dye layer, and wherein the infrared-absorbing material is a merocyanine dye. In a preferred embodiment, the merocyanine dye has the following formula: ##STR1## wherein R represents a substituted or unsubstituted alkyl group having from 1 to about 6 carbon atoms or a substituted or unsubstituted aryl or hetaryl group having from about 5 to about 10 atoms;R.sup.1, R.sup.2, R.sup.3, and R.sup.4 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, sulfonyl, carbamoyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryl group; or any two of said R, R.sup.1,R.sup.2, R.sup.3 and R.sup.4 groups may be joined together to complete a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring;A represents hydrogen, --COR, --CO.sub.2 R, --CONHR, --CONR.sub.2, --SO.sub.2 R, --SO.sub.2 NHR, --SO.sub.2 NR.sub.2 --SR, or --CN;B represents --NHR, --NR.sub.2, --OR, --SR or --R;or A or B may be joined together or with R.sup.3 or R.sup.4 to complete a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring;Y represents a dialkyl-substituted carbon atom, a vinylene group, an oxygen atom, a sulphur atom, a selenium atom, a tellurium atom, NR, or a direct bond to the carbon at the R.sup.2 position;Z represents the atoms necessary to complete a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring; andn is 3 to 5.

公开(公告)号：US5035977A

公开(公告)日：1991-07-30

申请号：US367062

申请日：1989-06-16

申请人： Charles D. DeBoer ,  Steven Evans

发明人： Charles D. DeBoer ,  Steven Evans

IPC分类号： B41M5/382 ,  B41M5/385 ,  B41M5/388 ,  B41M5/39 ,  B41M5/392 ,  B41M5/42 ,  B41M5/46 ,  D06P5/00

CPC分类号： B41M5/465 ,  B41M5/392 ,  Y10S430/145

摘要： A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer and an infrared-absorbing material which is different from the dye in the dye layer, and wherein the infrared-absorbing material is an oxonol dye. In a preferred embodiment, the oxonol dye has the following formula: ##STR1## wherein: R.sup.1, R.sup.2 and R.sup.3 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, carbamoyl, sulfonyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryl group; or any two of said R.sup.1, R.sup.2 and R.sup.3 groups may be joined together to complete a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring; or either R.sup.1 or R.sup.2 may be joined to R.sup.4 or R.sup.6 to complete a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring; or R.sup.2 or R.sup.3 may be joined to R.sup.5 or R.sup.7 to complete a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring;each R.sup.4 and R.sup.5 independently represents hydrogen, halogen, cyano, alkoxy, aryloxycarbonyl, alkoxycarbonyl, carbamoyl, sulfamoyl, sulfonyl, acyl, nitro or a substituted or unsubstituted alkyl, aryl or hetaryl group;R.sup.6 and R.sup.7 each independently represents alkoxy, aryloxy, alkylamino, arylamino, or a substituted or unsubstituted alkyl, aryl or hetaryl group;Y.sup.1 and Y.sup.2 each independently represents sulfur, oxygen or NR, where R is a substituted or unsubstituted alkyl group having from 1 to about 6 carbon atoms, or a substituted or unsubstituted aryl or hetaryl group;n is 1 to 3;m is 3 to 5; andX is a monovalent cation.

公开(公告)号：US4948776A

公开(公告)日：1990-08-14

申请号：US366969

申请日：1989-06-16

申请人： Steven Evans ,  Charles D. DeBoer

发明人： Steven Evans ,  Charles D. DeBoer

IPC分类号： B41M5/392 ,  B41M5/382 ,  B41M5/385 ,  B41M5/388 ,  B41M5/39 ,  B41M5/46

CPC分类号： B41M5/465 ,  B41M5/392 ,  Y10S428/913 ,  Y10S428/914 ,  Y10S430/146 ,  Y10T428/31786

摘要： A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer and an infrared-absorbing material which is different from the dye in the dye layer, and wherein the infrared-absorbing material is a chalcogenopyrylo-arylidene dye. In a preferred embodiment, the chalcogenopyrylo-arylidene dye has the following formula: ##STR1## wherein: R.sup.1 and R.sup.2 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, sulfonyl, carbamoyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryl group; or any of R.sup.1 and R.sup.2 may be joined together or with an adjacent aromatic ring to complete a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring;R.sup.3 and R.sup.6 each independently represents R.sup.1 or the atoms necessary to complete a 5- to 7-membered fused substituted or unsubstituted carbocyclic or heterocyclic ring;R.sup.4 and R.sup.5 each independently represents a substituted or unsubstituted alkyl or cycloalkyl group having from 1 to about 6 carbon atoms or an aryl or hetaryl group having from about 5 to about 10 atoms;or R.sup.4 and R.sup.5 may be joined together or to the carbon atom of the adjacent aromatic ring at a position ortho to the position of attachment of the anilino nitrogen to form, along with the nitrogen to which they are attached, a 5- to 7-membered heterocyclic ring;Y is oxygen, sulfur, selenium or tellurium with the methine chain being joined ortho or para to Y;X is a monovalent anion;n and m are 4; andp is 1-3, with the proviso that when Y is oxygen, then p is 2 or 3.

公开(公告)号：US5019480A

公开(公告)日：1991-05-28

申请号：US367064

申请日：1989-06-16

申请人： Charles D. DeBoer ,  Steven Evans

发明人： Charles D. DeBoer ,  Steven Evans

IPC分类号： B41M5/382 ,  B41M5/385 ,  B41M5/388 ,  B41M5/39 ,  B41M5/392 ,  B41M5/42 ,  B41M5/46 ,  D06P5/00

CPC分类号： B41M5/465 ,  B41M5/392 ,  Y10S430/145 ,  Y10S430/146

摘要： A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer and an infrared-absorbing material which is different from the dye in the dye layer, and wherein the infrared-absorbing material is an indene-bridged-polymethine dye. In a preferred embodiment, the indene-bridged-polymethine dye has the following formula: ##STR1## wherein: R represents a substituted or unsubstituted alkyl or cycloalkyl group having from 1 to about 6 carbon atoms or an aryl or hetaryl group having from about 5 to about 10 atoms; R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, sulfonyl, carbamoyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryly group; or any two of said R, R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 groups may be joined together to form a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring;A represents --COR, --CO.sub.2 R, --CONHR, --CONR.sub.2, --SO.sub.2 R, --SO.sub.2 NHR, --SO.sub.2 NR.sub.2 or --CN;B represents A or hydrogen, --R, --SR, --OR or --NR; or A or B may be joined together to form a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring;Y represents a dialkyl-substituted carbon atom, a vinylene group, an oxygen atom, a sulfur atom, a selenium atom, a tellurium atom, NR, or a direct bond to the carbon at the R.sup.2 position;Z represents hydrogen or the atoms necessary to complete a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring; andn is 0 to 3.

公开(公告)号：US4948777A

公开(公告)日：1990-08-14

申请号：US366970

申请日：1989-06-16

申请人： Steven Evans ,  Charles D. DeBoer

发明人： Steven Evans ,  Charles D. DeBoer

IPC分类号： B41M5/392 ,  B41M5/385 ,  B41M5/388 ,  B41M5/39 ,  B41M5/46

CPC分类号： B41M5/465 ,  B41M5/392 ,  Y10S428/913 ,  Y10S428/914 ,  Y10S430/146 ,  Y10T428/31786

摘要： A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer and an infrared-absorbing material which is different from the dye in the dye layer, and wherein the infrared-absorbing material is a bis(chalcogenopyrylo)polymethine dye. In a preferred embodiment, the bis(chalcogenopyrylo)polymethine dye has the following formula: ##STR1## wherein: R.sup.1, R.sup.2 and R.sup.3 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, sulfonyl, carbamoyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryl group; or any two of said R.sup.1, R.sup.2 and R.sup.3 groups may be joined together to form a 5- to 7-membered substituted or unsubstituted carboxyclic or heterocyclic ring; or R.sup.1 may be joined to Z.sup.1 to form a fused 5- or 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring; or R.sup.3 may be joined to Z.sup.2 to form a fused 5- or 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring;Y.sup.1 and Y.sup.2 each independently represents sulfur, oxygen, tellurium, or selenium, with the methine chain being joined ortho or para to each of Y.sup.1 and Y.sup.2 ;Z.sup.1 and Z.sup.2 each independently represents hydrogen; a substituted or unsubstituted alkyl group having from 1 to about 6 carbon atoms; a substituted or unsubstituted aryl or hetaryl group having from about 5 to about 10 atoms; or the atoms necessary to complete a 5- to 7-membered carbocyclic or heterocyclic ring;each m independently is 1 to 4;n is 1 to 3; andX is a monovalent anion.

公开(公告)号：US4942141A

公开(公告)日：1990-07-17

申请号：US366952

申请日：1989-06-16

申请人： Charles D. DeBoer ,  Steven Evans

发明人： Charles D. DeBoer ,  Steven Evans

IPC分类号： B41M5/26 ,  B41M5/382 ,  B41M5/385 ,  B41M5/388 ,  B41M5/39 ,  B41M5/392 ,  B41M5/46 ,  G11B7/24 ,  G11B7/244

CPC分类号： B41M5/465 ,  B41M5/392 ,  Y10S428/913 ,  Y10S428/914 ,  Y10S430/145 ,  Y10S430/146 ,  Y10T428/31786

摘要： A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer and an infrared-absorbing material which is different from the dye in the dye layer, and wherein the infrared-absorbing material is a squarylium dye. In a preferred embodiment, the squarylium dye has the following formula: ##STR1## wherein: R.sup.1, R.sup.2, R.sup.3 and R.sup.4 each independently represents hydrogen, hydroxy, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, sulfonyl, carbamoyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryl group; or any of said R.sup.1, R.sup.2, R.sup.3 or R.sup.4 groups may be combined with R.sup.5, R.sup.6, R.sup.7 or R.sup.8 or with each other to form a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring;R.sup.5, R.sup.6, R.sup.7 and R.sup.8 each independently represents hydrogen, a substituted or unsubstituted alkyl or cycloalkyl group having from 1 to about 6 carbon atoms or an aryl or hetaryl group having from about 5 to about 10 atoms;or R.sup.5 and R.sup.6 or R.sup.7 and R.sup.8 may be joined together to form a 5- to 7-membered substituted or unsubstituted nitrogen-containing heterocyclic ring; and n and m are each independently 1 to 4.

公开(公告)号：US07645574B2

公开(公告)日：2010-01-12

申请号：US10763597

申请日：2004-01-23

申请人： Charles D. DeBoer ,  Roberta J. Greco ,  John M. Noonan ,  Richard S. Murante

发明人： Charles D. DeBoer ,  Roberta J. Greco ,  John M. Noonan ,  Richard S. Murante

IPC分类号： C12Q1/68

CPC分类号： B01J19/0046 ,  B01J2219/00529 ,  B01J2219/00596 ,  B01J2219/00608 ,  B01J2219/00612 ,  B01J2219/0063 ,  B01J2219/00637 ,  B01J2219/00653 ,  B01J2219/00659 ,  B01J2219/00722

摘要： The present invention relates to methods of metallizing nucleic acid molecules and to methods of attaching nucleic acid molecules to conductive surfaces. Methods of detecting target nucleic acid molecules based on these techniques are also disclosed.

摘要翻译： 本发明涉及金属化核酸分子的方法和将核酸分子连接到导电表面的方法。 还公开了基于这些技术检测靶核酸分子的方法。

公开(公告)号：US06486901B1

公开(公告)日：2002-11-26

申请号：US08919559

申请日：1997-08-29

申请人： Charles D. DeBoer ,  Werner Fassler ,  Xin Wen

发明人： Charles D. DeBoer ,  Werner Fassler ,  Xin Wen

IPC分类号： B41J221

CPC分类号： B41J2/211

摘要： A method for microfluidic printing comprising pumping and mixing colored inks which comprise a mixture of colorants, fluids, and gel-forming or gel-initiating ingredients to form ink pixels and to transfer such ink pixels to a receiver transferring position; and transferring the ink pixels to a reflective receiver which contains gel-forming or gel-initiating ingredients so that the ingredients in the transferred ink pixels and in the receiver react to form a gel and the viscosity of the transferred ink rapidly increases to limit the flow of ink pixels whereby such ink pixels are fixed to the receiver and overprinting of colors is minimized.

摘要翻译： 一种用于微流体印刷的方法，包括泵送和混合包含着色剂，流体和凝胶形成或凝胶起始成分的混合物的着色油墨以形成油墨像素并将这种油墨像素转移到接收器转印位置; 并将墨水像素转移到包含凝胶形成或凝胶引发成分的反射接收器中，使得转印的墨像素和接收器中的成分反应形成凝胶，并且转印的墨的粘度迅速增加以限制流动 的墨水像素，由此这样的墨像被固定到接收器并且颜色的套印被最小化。