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61.发明申请PROCESS FOR PREPARING POLYETHER CARBONATE POLYOLS WITH DOUBLE METAL CYANIDE CATALYSTS AND IN THE PRESENCE OF METAL SALTS 有权用双金属氰化物催化剂制备聚碳酸酯多元醇的方法和金属盐的存在公开(公告)号：US20130190462A1
公开(公告)日：2013-07-25
申请号：US13579222
申请日：2011-02-17
申请人： Aurel Wolf , Stefan Grasser , Christoph Gürtler , Jörg Hofmann
发明人： Aurel Wolf , Stefan Grasser , Christoph Gürtler , Jörg Hofmann
CPC分类号： C08G64/34 , C08G18/32 , C08G18/44 , C08G64/205 , C08G65/2603 , C08G65/2663 , C08G65/2696
摘要： The present invention relates to a process for the preparation of polyether carbonate polyols by catalytic copolymerisation of carbon dioxide (CO2) with alkylene oxides in the presence of one or more H-functional starter substances with the aid of double metal cyanide (DMC) catalysts and in the presence of metal salts.
摘要翻译： 本发明涉及通过在双金属氰化物（DMC）催化剂的帮助下，在一种或多种H官能起始物质的存在下，二氧化碳（CO 2）与环氧烷的催化共聚制备聚醚碳酸酯多元醇的方法， 在金属盐的存在下。
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公开(公告)号：US09382417B2
公开(公告)日：2016-07-05
申请号：US13636509
申请日：2011-03-24
申请人： Christoph Gürtler , Jörg Hofmann , Thomas Ernst Müller , Aurel Wolf , Stefan Grasser , Burkhard Köhler
发明人： Christoph Gürtler , Jörg Hofmann , Thomas Ernst Müller , Aurel Wolf , Stefan Grasser , Burkhard Köhler
CPC分类号： C08L69/00 , C08G65/2603 , C08G65/2663 , C08K5/13 , C08K5/32 , C08K5/3435 , C08K5/357 , C08K5/46 , C08K5/47
摘要： The present invention relates to a process for the preparation of polyether carbonate polyols by catalytic copolymerization of carbon dioxide (CO2) with alkylene oxides in the presence of one or more H-functional starter substances with the aid of double metal cyanide (DMC) catalysts and in the presence of additives A) chosen from the group consisting of sterically non-hindered phenols, catechols, pyrocatechols, thiazines, phenothiazines, thiazoles, benzothiazoles, oxazines, phenoxazines, 2,2,6,6-tetramethylpiperidine 1-oxyl and nitrostyrenes and optionally in the presence of metal salts B).
摘要翻译： 本发明涉及一种通过在双金属氰化物（DMC）催化剂的帮助下，在一种或多种H官能起始物质存在下，通过二氧化碳（CO 2）与环氧烷的催化共聚制备聚醚碳酸酯多元醇的方法， 在添加剂A）的存在下，选自空间非受阻酚，儿茶酚，邻苯二酚，噻嗪，吩噻嗪，噻唑，苯并噻唑，吩嗪，吩恶嗪，2,2,6,6-四甲基哌啶1-氧基和硝基苯乙烯，以及 任选地在金属盐B）的存在下。
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公开(公告)号：US08946466B2
公开(公告)日：2015-02-03
申请号：US13698694
申请日：2011-05-13
申请人： Christoph Gürtler , Jörg Hofmann , Aurel Wolf , Stefan Grasser
发明人： Christoph Gürtler , Jörg Hofmann , Aurel Wolf , Stefan Grasser
CPC分类号： C07C68/04 , C08G64/34 , C08G65/2603 , C08G65/2663
摘要： The present invention relates to a process for the preparation of polyether carbonate polyols from one or more H-functional starter substances, one or more alkylene oxides and carbon dioxide in the presence of at least one double metal cyanide catalyst, wherein the cyanide-free metal salt, the metal cyanide salt or both the mentioned salts used for the preparation of the double metal cyanide catalyst contain(s) from 0.3 to 1.8 mol base equivalents (based on 1 mol of the metal cyanide salt used for the synthesis of the catalyst) of alkaline metal hydroxide, metal carbonate and/or metal oxide.
摘要翻译： 本发明涉及一种在至少一种双金属氰化物催化剂存在下从一种或多种H官能起始物质，一种或多种环氧烷和二氧化碳制备聚醚碳酸酯多元醇的方法，其中无氰化物金属 盐，金属氰化物盐或用于制备双金属氰化物催化剂的所述盐两者含有0.3至1.8摩尔碱当量（基于用于合成催化剂的金属氰化物盐的1摩尔） 的碱金属氢氧化物，金属碳酸盐和/或金属氧化物。
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64.发明授权Process for the activation of double metal cyanide catalysts for the preparation of polyether carbonate polyols 有权用于制备聚碳酸酯多元醇的双金属氰化物催化剂的活化方法公开(公告)号：US08933192B2
公开(公告)日：2015-01-13
申请号：US13574146
申请日：2011-01-18
申请人： Christoph Gürtler , Stefan Grasser , Jörg Hofmann , Aurel Wolf
发明人： Christoph Gürtler , Stefan Grasser , Jörg Hofmann , Aurel Wolf
CPC分类号： C08G64/34 , C08G64/0208 , C08G64/1608 , C08G64/183 , Y02P20/142
摘要： The present invention relates to a process for the activation of double metal cyanide (DMC) catalysts for the preparation of polyether carbonate polyols by catalytic copolymerisation of carbon dioxide (CO2) with alkylene oxides in the presence of one or more H-functional starter substances.
摘要翻译： 本发明涉及通过在一种或多种H功能性起始物质的存在下通过二氧化碳（CO 2）与烯化氧的催化共聚来活化用于制备聚醚碳酸酯多元醇的双金属氰化物（DMC）催化剂的方法。
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公开(公告)号：US20130123532A1
公开(公告)日：2013-05-16
申请号：US13698694
申请日：2011-05-13
申请人： Christoph Gürtler , Jörg Hofmann , Aurel Wolf , Stefan Grasser
发明人： Christoph Gürtler , Jörg Hofmann , Aurel Wolf , Stefan Grasser
IPC分类号： C07C68/04
CPC分类号： C07C68/04 , C08G64/34 , C08G65/2603 , C08G65/2663
摘要： The present invention relates to a process for the preparation of polyether carbonate polyols from one or more H-functional starter substances, one or more alkylene oxides and carbon dioxide in the presence of at least one double metal cyanide catalyst, wherein the cyanide-free metal salt, the metal cyanide salt or both the mentioned salts used for the preparation of the double metal cyanide catalyst contain(s) from 0.3 to 1.8 mol base equivalents (based on 1 mol of the metal cyanide salt used for the synthesis of the catalyst) of alkaline metal hydroxide, metal carbonate and/or metal oxide.
摘要翻译： 本发明涉及一种在至少一种双金属氰化物催化剂存在下从一种或多种H官能起始物质，一种或多种环氧烷和二氧化碳制备聚醚碳酸酯多元醇的方法，其中无氰化物金属 盐，金属氰化物盐或用于制备双金属氰化物催化剂的所述盐两者含有0.3至1.8摩尔碱当量（基于用于合成催化剂的金属氰化物盐的1摩尔） 的碱金属氢氧化物，金属碳酸盐和/或金属氧化物。
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公开(公告)号：US20130072602A1
公开(公告)日：2013-03-21
申请号：US13636509
申请日：2011-03-24
申请人： Christoph Gürtler , Jörg Hofmann , Thomas Ernst Müller , Aurel Wolf , Stefan Grasser , Burkhard Köhler
发明人： Christoph Gürtler , Jörg Hofmann , Thomas Ernst Müller , Aurel Wolf , Stefan Grasser , Burkhard Köhler
CPC分类号： C08L69/00 , C08G65/2603 , C08G65/2663 , C08K5/13 , C08K5/32 , C08K5/3435 , C08K5/357 , C08K5/46 , C08K5/47
摘要： The present invention relates to a process for the preparation of polyether carbonate polyols by catalytic copolymerization of carbon dioxide (CO2) with alkylene oxides in the presence of one or more H-functional starter substances with the aid of double metal cyanide (DMC) catalysts and in the presence of additives A) chosen from the group consisting of sterically non-hindered phenols, catechols, pyrocatechols, thiazines, phenothiazines, thiazoles, benzothiazoles, oxazines, phenoxazines, 2,2,6,6-tetramethylpiperidine 1-oxyl and nitrostyrenes and optionally in the presence of metal salts B).
摘要翻译： 本发明涉及一种通过在双金属氰化物（DMC）催化剂的帮助下，在一种或多种H官能起始物质存在下，通过二氧化碳（CO 2）与环氧烷的催化共聚制备聚醚碳酸酯多元醇的方法， 在添加剂A）的存在下，选自空间非受阻酚，儿茶酚，邻苯二酚，噻嗪，吩噻嗪，噻唑，苯并噻唑，吩嗪，吩恶嗪，2,2,6,6-四甲基哌啶1-氧基和硝基苯乙烯，以及 任选地在金属盐B）的存在下。
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67.发明申请公开(公告)号：US20130018186A1
公开(公告)日：2013-01-17
申请号：US13515710
申请日：2010-12-09
申请人： Christoph Gürtler , Thomas Ernst Müller , Pieter Ooms , Johann Rechner , Friedhelm Risse , Angelina Prokofieva , Franco Doro , Burkhard Köhler , Walter Leitner , Aurel Wolf
发明人： Christoph Gürtler , Thomas Ernst Müller , Pieter Ooms , Johann Rechner , Friedhelm Risse , Angelina Prokofieva , Franco Doro , Burkhard Köhler , Walter Leitner , Aurel Wolf
CPC分类号： C07F15/0066 , C07C68/005 , C07C69/96
摘要： The invention relates to bimetallic complexes in which the ligand contains a salophen unit which complexes copper, manganese or cobalt and a phenanthroline unit which complexes palladium and the two systems are linked by a continuous conjugated system. The invention further relates to the use of these bimetallic complexes as catalysts for the oxidative carbonylation of aromatic hydroxy compounds to form diaryl carbonates, a process for preparing diaryl carbonates using the bimetallic complex as catalyst and also diaryl carbonates prepared by oxidative carbonylation of aromatic hydroxy compounds using the bimetallic complexes of the invention as catalysts.
摘要翻译： 本发明涉及双金属络合物，其中配体包含络合铜，锰或钴的盐酸单体和络合钯并且两种体系通过连续共轭体系连接的菲咯啉单元。 本发明还涉及这些双金属络合物作为用于芳族羟基化合物的氧化羰基化以形成碳酸二芳基酯的催化剂的使用，使用双金属络合物作为催化剂制备碳酸二芳基酯的方法，以及通过芳族羟基化合物的氧化羰基化制备的碳酸二芳基酯 使用本发明的双金属络合物作为催化剂。
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68.发明申请PROCESS FOR THE ACTIVATION OF DOUBLE METAL CYANIDE CATALYSTS FOR THE PREPARATION OF POLYETHER CARBONATE POLYOLS 有权用于制备聚碳酸酯多元醇的双金属氰化物催化剂的活化方法公开(公告)号：US20120289732A1
公开(公告)日：2012-11-15
申请号：US13574146
申请日：2011-01-18
申请人： Christoph Gürtler , Stefan Grasser , Jörg Hofmann , Aurel Wolf
发明人： Christoph Gürtler , Stefan Grasser , Jörg Hofmann , Aurel Wolf
IPC分类号： C07C68/04
CPC分类号： C08G64/34 , C08G64/0208 , C08G64/1608 , C08G64/183 , Y02P20/142
摘要： The present invention relates to a process for the activation of double metal cyanide (DMC) catalysts for the preparation of polyether carbonate polyols by catalytic copolymerisation of carbon dioxide (CO2) with alkylene oxides in the presence of one or more H-functional starter substances.
摘要翻译： 本发明涉及通过在一种或多种H功能性起始物质的存在下通过二氧化碳（CO 2）与烯化氧的催化共聚来活化用于制备聚醚碳酸酯多元醇的双金属氰化物（DMC）催化剂的方法。
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69.发明申请PROCESS FOR HETEROGENEOUSLY CATALYZED ESTERIFICATION OF (METH)ACRYLIC ACID WITH OXYALKYLATED POLYOLS 审中-公开（甲基）丙烯酸与异氰酸酯多异构体异构催化酯化反应的方法公开(公告)号：US20110028754A1
公开(公告)日：2011-02-03
申请号：US12671989
申请日：2008-07-29
申请人： Michael Ludewig , Jan Weikard , Andre Düx , Benie Marotz , Georg Ronge , Aurel Wolf
发明人： Michael Ludewig , Jan Weikard , Andre Düx , Benie Marotz , Georg Ronge , Aurel Wolf
IPC分类号： C07C69/54
CPC分类号： C09D4/00 , C07C67/08 , C07C269/02 , C08G18/672 , C09D175/16 , C07C69/54 , C08G18/6795 , C07C271/06
摘要： The present invention relates to a process for heterogeneously catalyzed partial esterification of (meth)acrylic acid with oxyalkylated polyols, wherein the oxyalkylated polyols have at least 3 free hydroxyl groups, and wherein the catalyst is selected from the group comprising acidic ion exchange resins and/or acidic zeolites. The invention further relates to (meth)acrylic esters and urethane acrylates, obtained by a process according to the present invention, and to the use thereof as radiation-curable compounds.
摘要翻译： （甲基）丙烯酸与烷氧基化多元醇的非均相催化部分酯化反应的方法技术领域本发明涉及一种用烷氧基化多元醇异构催化部分酯化（甲基）丙烯酸的方法，其中烷氧基化多元醇具有至少3个游离羟基，其中该催化剂选自酸性离子交换树脂和/ 或酸性沸石。 本发明还涉及通过本发明的方法获得的（甲基）丙烯酸酯和氨基甲酸酯丙烯酸酯，以及作为可辐射固化的化合物的用途。
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70.发明申请PROCESSES FOR THE OXIDATION OF CARBON MONOXIDE IN A GAS STREAM CONTAINING HCL 审中-公开在含有HCL的气体流中一氧化碳氧化的方法公开(公告)号：US20080267849A1
公开(公告)日：2008-10-30
申请号：US12110468
申请日：2008-04-28
IPC分类号： B01D53/34
CPC分类号： C07C263/10 , B01J23/626 , C01B7/04 , C01B7/0706 , C01B32/50 , C07C265/14
摘要： Processes comprising: providing a gas stream comprising hydrogen chloride and carbon monoxide; and oxidizing at least a portion of the carbon monoxide in the gas stream in the presence of a catalyst to form a product gas comprising hydrogen chloride and carbon dioxide; wherein the catalyst comprises tin dioxide and a ruthenium compound comprising at least one element selected from the group consisting of oxygen and chlorine.
摘要翻译： 方法包括：提供包含氯化氢和一氧化碳的气流; 以及在催化剂存在下氧化气流中至少一部分一氧化碳以形成包含氯化氢和二氧化碳的产物气体; 其中所述催化剂包含二氧化锡和包含至少一种选自氧和氯的元素的钌化合物。
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