摘要:
Disclosed herein is an improved method for regenerating materials from a desulfurization/demetallation reaction. The desulfurization/demetallation reaction preferably has products including one or more of an alkali sulfide, polysulfide or hydrosulfide, or alkali earth sulfide, polysulfide, or hydrosulfide. The method includes the steps of reacting the desulfurization/demetallation products with a halogen, liberating and removing sulfur from the product, and then electrolyzing the halogenated products to separate the halogen from the alkali metal or alkali earth metal.
摘要:
A high-temperature, steam-selective membrane for adding steam to or removing steam from various types of chemical reactions is disclosed herein. In one embodiment, such a membrane includes a polymer layer (a Nafion or sulfonated PEEK polymer layer, for example) exhibiting high selectivity to the transport of steam relative to other gas species. The polymer layer is sandwiched between substantially rigid porous layers that are steam permeable. The rigid porous layers substantially immobilize the polymer layer and reduce the tendency of the polymer layer to shrink and/or expand in response to changes in temperature or humidity. The rigid porous layers may also retain water to keep the polymer layer moist. The physical support and moisture retention provided by the rigid porous layers enable the polymer layer to operate in a temperature range of about 100° C. to 500° C.
摘要:
An apparatus for administering a therapeutic is provided. In various embodiments, the apparatus includes a syringe having a barrel and a plunger and having an ozone generator associated therewith. The generator is initiated and a therapeutic gas is accumulated within the barrel, at which point it can be delivered from the barrel into a target site via a needle, thereby delivering therapeutic effects to that target site.
摘要:
A device and method for atomizing a liquid for delivery to a target zone are presented. The liquid atomization device may include a liquid reservoir to contain a liquid, and a liquid pathway to receive at least a portion of the liquid from the liquid reservoir. The liquid pathway may include one end communicating with the liquid reservoir, and another end communicating with a target zone. Two electrodes may be placed in the liquid pathway to accommodate the liquid therebetween. An AC power source may be connected to each of the electrodes to generate an alternating current through the liquid, thereby atomizing at least a portion of the liquid for delivery to the target zone.
摘要:
A selective catalytic reduction (SCR) system includes an on-board ammonia generation system that produces nitrogen from air and hydrogen from a source of a hydrogen-containing compound, and generates an ammonia product from the nitrogen and hydrogen to provide the ammonia product into an exhaust from a NOx generator to reduce the NOx in the exhaust. Oxygen from one or both of the nitrogen generator and the hydrogen generation cell can be supplied to the NOx generator for cleaner combustion or to a particulate filter for cleaning the filter. H2O from the NOx generator can at least partially provide a water source for the hydrogen generation cell.
摘要:
A process for treating flue gas containing fly ash and carbon dioxide is disclosed. In the process, carbon dioxide and fly ash are contacted with an aqueous metal hydroxide solution to convert carbon dioxide into a metal carbonate, and wherein the metal carbonate and the metal hydroxide cause the fly ash to undergo a geopolymerization reaction and form a geopolymerized fly ash. The geopolymerized fly ash is recovered for disposal or for further use, such as a concrete additive.
摘要:
Methods and apparatus for synthesizing biodiesel using an alkali ion donating material are disclosed. Generally, the methods include placing an alcohol and a triglyceride in a container having the alkali ion donating material. A biodiesel reaction driving force is applied to the contents of the container. This force may cause the ion donating material to release alkali ions that react with the alcohol to form an alkali alcoholate. In turn, the alkali alcoholate reacts with triglycerides to form biodiesel and an alkali salt of glycerine. When the driving force is removed and where the alkali ion donating material comprises a catalyst with a high affinity for alkali ions, the alkali ion in the alkali salt of glycerine returns to the alkali ion donating material. Accordingly, the apparatus and methods may produce substantially pure biodiesel and glycerine.
摘要:
Alkali alcoholates, also called alkali alkoxides, are produced from alkali metal salt solutions and alcohol using a three-compartment electrolytic cell. The electrolytic cell includes an anolyte compartment configured with an anode, a buffer compartment, and a catholyte compartment configured with a cathode. First and second separators are positioned between the anolyte compartment and the catholyte compartment to define a buffer compartment. The first and second separators are permeable to alkali ions. They may be fabricated of the same or different materials including, but not limited to, an alkali ion conducting solid electrolyte configured to selectively transport alkali ions, a porous ceramic, or a porous polymer separator material. The catholyte solution may include an alkali alcoholate and alcohol. The anolyte solution may include at least one alkali salt. The buffer compartment solution may include a soluble alkali salt and an alkali alcoholate in alcohol.
摘要:
Alkali alcoholates, also called alkali alkoxides, are produced from alkali metal salt solutions and alcohol using a three-compartment electrolytic cell. The electrolytic cell includes an anolyte compartment configured with an anode, a buffer compartment, and a catholyte compartment configured with a cathode. First and second separators are positioned between the anolyte compartment and the catholyte compartment to define a buffer compartment. The first and second separators are permeable to alkali ions. They may be fabricated of the same or different materials including, but not limited to, an alkali ion conducting solid electrolyte configured to selectively transport alkali ions, a porous ceramic, or a porous polymer separator material. The catholyte solution may include an alkali alcoholate and alcohol. The anolyte solution may include at least one alkali salt. The buffer compartment solution may include a soluble alkali salt and an alkali alcoholate in alcohol.
摘要:
An apparatus for providing beneficial agents to the body is disclosed in one aspect of the invention as including an implant and a device integrated with the implant to generate a beneficial agent, such as iodine, chlorine, or other halogens. The device includes electrodes to conduct an electrical current and a substantially solid layer between the electrodes. An electrical current passes between the electrodes to electrochemically generate the beneficial agent. The implant may include a variety of devices to produce the beneficial agent, including for example an electrochemical cell, a capacitor, an electrochemical capacitor, a galvanic cell, or the like. Similarly, because of the solid state construction of the device, the device may, in certain embodiments, be incorporated into a load-bearing implant. This may be useful for use with certain types of implants, such as orthopedic implants.