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公开(公告)号：US08575405B2
公开(公告)日：2013-11-05
申请号：US13197737
申请日：2011-08-03
申请人： David Lee , Adam Orosco , Lincoln Sarager , R. Jay Warner , Radmila Jevtic , Victor J. Johnston
发明人： David Lee , Adam Orosco , Lincoln Sarager , R. Jay Warner , Radmila Jevtic , Victor J. Johnston
IPC分类号： C07C29/149
CPC分类号： B01D3/40 , B01D3/148 , C07C29/149 , C07C29/80 , C07C29/88 , C07C51/12 , C07C31/08 , C07C53/08
摘要： To reduce acetal concentrations when separating ethanol from a crude product in one or more distillation column, at least one of the columns is operated at a higher pressure to increase the equilibrium constant that favors hydrolysis of the acetal. The crude product may comprise ethanol, acetaldehyde, water and one or more acetals, such as diethyl acetal. The acetal concentration may be reduced thus reducing the need to separate acetal from the crude product.
摘要翻译： 为了减少在一个或多个蒸馏塔中从粗产物中分离乙醇时的乙缩醛浓度，至少一个塔在较高的压力下运行以增加有利于缩醛水解的平衡常数。 粗产物可以包括乙醇，乙醛，水和一种或多种缩醛，例如二乙缩醛。 缩醛浓度可能会降低，从而减少了从粗产物分离乙缩醛的需要。
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公开(公告)号：US20130035523A1
公开(公告)日：2013-02-07
申请号：US13197737
申请日：2011-08-03
申请人： David Lee , Adam Orosco , Lincoln Sarager , R. Jay Warner , Radmila Jevtic , Victor J. Johnston
发明人： David Lee , Adam Orosco , Lincoln Sarager , R. Jay Warner , Radmila Jevtic , Victor J. Johnston
IPC分类号： C07C29/149 , B01D3/00
CPC分类号： B01D3/40 , B01D3/148 , C07C29/149 , C07C29/80 , C07C29/88 , C07C51/12 , C07C31/08 , C07C53/08
摘要： To reduce acetal concentrations when separating ethanol from a crude product in one or more distillation column, at least one of the columns is operated at a higher pressure to increase the equilibrium constant that favors hydrolysis of the acetal. The crude product may comprise ethanol, acetaldehyde, water and one or more acetals, such as diethyl acetal. The acetal concentration may be reduced thus reducing the need to separate acetal from the crude product.
摘要翻译： 为了减少在一个或多个蒸馏塔中从粗产物中分离乙醇时的乙缩醛浓度，至少一个塔在较高的压力下运行以增加有利于缩醛水解的平衡常数。 粗产物可以包括乙醇，乙醛，水和一种或多种缩醛，例如二乙缩醛。 缩醛浓度可能会降低，从而减少了从粗产物分离乙缩醛的需要。
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公开(公告)号：US20130035517A1
公开(公告)日：2013-02-07
申请号：US13273054
申请日：2011-10-13
IPC分类号： C07C29/143 , C07C31/08
CPC分类号： C07C29/149 , C07C29/145 , C07C45/48 , C07C31/10 , C07C31/08 , C07C49/08
摘要： A process is described for producing an alcohol product, in which (a) a first feed composition comprising acetic acid is converted to a product comprising acetone; and (b) a second feed composition comprising at least part of the acetone produced in (a) is hydrogenated in the presence of a catalyst to produce a hydrogenation effluent comprising isopropanol.
摘要翻译： 描述了用于生产醇产物的方法，其中（a）包含乙酸的第一进料组合物转化为包含丙酮的产物; 和（b）包含（a）中生产的至少一部分丙酮的第二进料组合物在催化剂存在下氢化以产生包含异丙醇的氢化流出液。
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公开(公告)号：US20120010448A1
公开(公告)日：2012-01-12
申请号：US13178861
申请日：2011-07-08
IPC分类号： C07C29/147
CPC分类号： C07C29/141 , C07C29/149 , C07C29/78 , C07C29/80 , C07C29/86 , C07C29/88 , C07C29/90 , C07C67/08 , C07C31/08 , C07C69/14
摘要： A process for purifying ethanol by using a finishing reactor to remove impurities, such as ethyl acetate, acetaldehyde, acetic acid, and diethyl acetal, present in ethanol after distilling a crude product from a hydrogenation reactor. The finishing reactor may reduce the impurities in the presence of hydrogen and a catalyst or may hydrolyze the impurities.
摘要翻译： 在从氢化反应器中蒸馏出粗产物后，使用精整反应器来净化乙醇的方法，以除去乙醇中的杂质，如乙酸乙酯，乙醛，乙酸和二乙基缩醛。 精加工反应器可以在氢和催化剂存在下减少杂质，或者可能水解杂质。
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65.发明申请公开(公告)号：US20110190552A1
公开(公告)日：2011-08-04
申请号：US12986008
申请日：2011-01-06
申请人： Nathan Kirk Powell , Samuel Roundy , Lincoln Sarager , Murray Viard , R. Jay Warner , Gerald Gruesendorf , Radmila Jevtic , Victor J. Johnston , Fred Ronald Olsson
发明人： Nathan Kirk Powell , Samuel Roundy , Lincoln Sarager , Murray Viard , R. Jay Warner , Gerald Gruesendorf , Radmila Jevtic , Victor J. Johnston , Fred Ronald Olsson
IPC分类号： C07C29/149
CPC分类号： C07C29/149 , B01D3/007 , B01D3/143 , B01J8/0457 , B01J2219/00006 , C07C29/80 , Y02P20/125 , Y02P70/34 , C07C31/08
摘要： Ethanol production from the hydrogenation of acetic acid requires energy to drive the hydrogenation reaction and the purification of the crude ethanol product. Heat integration process to recover heat from one part of the production process to be used within the process improves efficiencies and reduces costs.
摘要翻译： 从乙酸氢化生产乙醇需要能量来驱动氢化反应和纯化粗乙醇产物。 从整个生产流程的一部分回收热量的热量整合过程可以提高效率并降低成本。
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公开(公告)号：US08927782B2
公开(公告)日：2015-01-06
申请号：US13197740
申请日：2011-08-03
IPC分类号： C07C29/149 , B01D3/06
CPC分类号： B01D3/06 , C07C29/149
摘要： Two or more vapor-liquid separators are used in a process for removing at least one non-condensable gas from a crude alcohol mixture prepared by hydrogenating alkanoic acid and/or esters thereof. The vapor-liquid separators may comprise flashers or knock-out pots and are suitable for removing non-condensable gas, including those gases that are dissolved in the liquid. The multiple vapor-liquid separators may be in series prior to any separation of organic components. In addition, there may be a vapor-liquid separator before and after a distillation column for treating the feed to the column.
摘要翻译： 在从通过氢化链烷酸和/或其酯制备的粗醇混合物中除去至少一种不可冷凝气体的方法中，使用两种或更多种气液分离器。 气液分离器可以包括闪蒸器或分离罐，并且适用于去除不可冷凝的气体，包括溶解在液体中的那些气体。 在任何分离有机组分之前，多个气液分离器可以是串联的。 此外，在用于处理塔的进料的蒸馏塔之前和之后可以有气 - 液分离器。
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公开(公告)号：US20120010440A1
公开(公告)日：2012-01-12
申请号：US13094688
申请日：2011-04-26
申请人： Lincoln Sarager , R. Jay Warner , Trinity Horton , David Lee , Victor J. Johnston , Manuel Salado
发明人： Lincoln Sarager , R. Jay Warner , Trinity Horton , David Lee , Victor J. Johnston , Manuel Salado
摘要： A crude ethanol product obtained from the hydrogenation of acetic acid comprises ethanol and ethyl acetate. Using a distillation column operated at a pressure of from 0.1 to 100 kPa, the ethyl acetate and ethanol may be effectively separated. In addition, maintaining the amount of water that is fed to the distillation column to an amount less than 10 wt. %, based on the weight of all components fed to the distillation column, provides an energy benefit.
摘要翻译： 从乙酸氢化得到的粗乙醇产物包括乙醇和乙酸乙酯。 使用在0.1至100kPa压力下操作的蒸馏塔，可以有效地分离乙酸乙酯和乙醇。 此外，将进料到蒸馏塔中的水的量保持在小于10wt。 基于进料到蒸馏塔的所有组分的重量，提供了能量效益。
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公开(公告)号：US08877986B2
公开(公告)日：2014-11-04
申请号：US13197738
申请日：2011-08-03
申请人： Adam Orosco , Manuel Salado , Lincoln Sarager , R. Jay Warner , Trinity Horton , Victor J. Johnston , David Lee
发明人： Adam Orosco , Manuel Salado , Lincoln Sarager , R. Jay Warner , Trinity Horton , Victor J. Johnston , David Lee
IPC分类号： C07C27/04 , C07C29/149 , C07C51/12 , C07C29/88 , C07C29/80
摘要： Recovery of an alcohol such as ethanol from a crude alcohol product, preferably obtained from the hydrogenation of acetic acid using a low energy process. The crude ethanol product is separated in a column to produce a distillate stream comprising ethyl acetate and a residue stream comprising ethanol, acetic acid, and water. The ethanol product is recovered in a second column as an ethanol side stream.
摘要翻译： 从粗醇产物中回收醇如乙醇，优选使用低能量方法从乙酸氢化获得。 将粗乙醇产物在柱中分离以产生包含乙酸乙酯和包含乙醇，乙酸和水的残余物流的馏出物流。 将乙醇产物作为乙醇侧流在第二塔中回收。
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公开(公告)号：US08440866B2
公开(公告)日：2013-05-14
申请号：US13197714
申请日：2011-08-03
申请人： Adam Orosco , Manuel Salado , Lincoln Sarager , R. Jay Warner , Trinity Horton , Victor J. Johnston , David Lee
发明人： Adam Orosco , Manuel Salado , Lincoln Sarager , R. Jay Warner , Trinity Horton , Victor J. Johnston , David Lee
IPC分类号： C07C29/149
CPC分类号： C07C29/149 , C07C29/80 , C07C51/12 , C07C53/08 , C07C31/08
摘要： A process for operating a distillation column to separate an ethanol mixture comprising ethanol and acetic acid where the recovered ethanol comprises less than 700 wppm acetic acid. The operating conditions for the column may vary depending on the fed composition. In particular the process provides energy efficient recovery of ethanol with low concentration acetic acid.
摘要翻译： 一种用于操作蒸馏塔以分离包含乙醇和乙酸的乙醇混合物的方法，其中回收的乙醇包含小于700wppm的乙酸。 柱的操作条件可以根据进料组成而变化。 特别地，该方法提供了用低浓度乙酸对乙醇进行能量回收。
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公开(公告)号：US08704011B2
公开(公告)日：2014-04-22
申请号：US13094688
申请日：2011-04-26
申请人： Lincoln Sarager , R. Jay Warner , Trinity Horton , David Lee , Victor J. Johnston , Manuel Salado
发明人： Lincoln Sarager , R. Jay Warner , Trinity Horton , David Lee , Victor J. Johnston , Manuel Salado
IPC分类号： C07C27/04
摘要： A crude ethanol product obtained from the hydrogenation of acetic acid comprises ethanol and ethyl acetate. Using a distillation column operated at a pressure of from 0.1 to 100 kPa, the ethyl acetate and ethanol may be effectively separated. In addition, maintaining the amount of water that is fed to the distillation column to an amount less than 10 wt. %, based on the weight of all components fed to the distillation column, provides an energy benefit.
摘要翻译： 从乙酸氢化得到的粗乙醇产物包括乙醇和乙酸乙酯。 使用在0.1至100kPa压力下操作的蒸馏塔，可以有效地分离乙酸乙酯和乙醇。 此外，将进料到蒸馏塔中的水的量保持在小于10wt。 基于进料到蒸馏塔的所有组分的重量，提供了能量效益。
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